vent: exposure limits which may be listed in ients ing 14: for recommended practice - american conference of msds toxicity property">
toluene (sara 313) (cercla) vp: 22 @ 20c; lel: 1.7%; uel: lacolene; (aliphatic hydrocarbon) vp: 12 @ 20c volatile organic content (calculated): 7.24 lb/gal less first aid proc: notes to md: any treatment that might be ing 5: control of symptoms and the clinical conditions. spill proc: absorb. use only non-sparking tools. place ing 7: prevent contamination of sewers, streams, and resp prot: in restricted vent areas a niosh/msha apprvd ing 9: cndtns, such as spraying, a niosh/msha mech ing 10: niosh/msha apprvd air-supp resp. if tlv's listed in ing 11: niosh/msha apprvd resp w/approp prot factor. refer ing 12: and "respiratory protection a manual and guideline, vent: exposure limits which may be listed in ients ing 14: for recommended practice - american conference of msds toxicity property">
MSDS
:
BARGE S.S. THINNER, P5687A1
CAS
:
141-78-6 108-88-3 64742-89-8
NAME
:
acetic acid, ethyl ester; (ethyl acetate) (cercla) vp: 73 @ toluene (sara 313) (cercla) vp: 22 @ 20c; lel: 1.7%; uel: lacolene; (aliphatic hydrocarbon) vp: 12 @ 20c volatile organic content (calculated): 7.24 lb/gal less first aid proc: notes to md: any treatment that might be ing 5: control of symptoms and the clinical conditions. spill proc: absorb. use only non-sparking tools. place ing 7: prevent contamination of sewers, streams, and resp prot: in restricted vent areas a niosh/msha apprvd ing 9: cndtns, such as spraying, a niosh/msha mech ing 10: niosh/msha apprvd air-supp resp. if tlv's listed in ing 11: niosh/msha apprvd resp w/approp prot factor. refer ing 12: and "respiratory protection a manual and guideline, vent: exposure limits which may be listed in ients ing 14: for recommended practice - american conference of
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: INGEST: CAN CAUSE GI IRRIT,
NAUS, & VOMIT. ASPIR OF MATL INTO LUNGS MAY CAUSE CHEM PNEUMIT
WHICH CAN BE FATAL. INHAL: MAY CAUSE NOSE/THROAT IRRIT. HIGH CONCS
MAY CAUSE ACUTE CNS DEPRESS CHARACT BY HDCH, DIZZ, NAUS &
CONFUSION. EYES:MAY CAUSE IRRIT. SKIN: MAY CAUSE DEFAT & IRRIT.
CHRONIC: RPTD (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: OVEREXP TO TOLUENE MAY CAUSE LIVER
DMG. REPORTS HAVE ASSOC PRLNG/RPTD OCCUP OVEREXP TO SOLV W/PERM
BRAIN & CNS DMG. INTENTIONAL MISUSE BY DELIBERATELY CONC & INHALING
CONTENTS MAY BE HARMFUL /FATAL. TOLUENE HAS BEEN FOUND TO
CAUSEKIDNEY, LUNG & SPLEEN DMG IN LAB ANIMALS. TOLUENE APPEARS ON
NAVY LIST (SUP DAT)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INGEST: DO NOT INDUCE VOMIT. CALL POIS CTL CTR, HOSPITAL EMER
ROOM/MD IMMED. INHAL: REMOVE TO FRESH AIR IMMED. IF BRTHG HAS
STOPPED GIVE ARTF RESP. KEEP WARM & QUIET.GET MD ATTN IMMED. EYES:
FLUSH W/L GE AMTS OF WATER, LIFTING UPPER & LOWERLIDS OCCASNLY.
CONTINUE FOR AT LEAST 15 MIN. GET MD ATTN. SKIN: REMOVE CONTAM
CLTHG. WASH AFFECTED AREA W/SOAP & WATER. OBTAIN MD ATTN IF IRRIT
PERSISTS (ING 5)
===================== Fire Fighting Measures =====================
Flash Point Method:SCC
Flash Point:21.0F,-6.1C
Extinguishing Media:USE NFPA CLASS B FIRE EXTING (CARBON DIOXIDE, ALL
PURPOSE DRY CHEM/ALCOHOL FOAM) DESIGNED TO EXTING FLAM LIQ (SUP
DAT)
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP
. WATER MAY BE INEFFECTIVE, BUT MAY BE USED TO COOL EXPOSED CONTRS
TO PREVENT PRESS BUILD-UP & (SUP DAT)
Unusual Fire/Explosion Hazard:DURING EMER CNDTNS, OVEREXP TO DECOMP
PROD MAY CAUSE HLTH HAZ. SYMP MAY NOT BE IMMED APPARENT. OBTAIN MED
ATTN. WARNING! FLAMMABLE.
Spill Release Procedures:KEEP SPECTATORS AWAY. ELIMINATE ALL IGNIT
SOURCES (FLAMES, HOT SURF, & SOURCES OF ELEC, STATIC/FRICTIONAL
SPARKS). DIKE & CONTAIN SPILL W/INERT MATL (E.G. SAND, EARTH).
TRANSFER LIQ TO COVERED METAL C ONTRS FOR RECOVERY/DISP/REMOVE
W/INERT (ING 7)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:DO NOT STORE ABOVE 115F (46C). STORE
LARGE QUANTITIES IN COMPLIANCE WITH OSHA 29 CFR 1910.106. DO NOT
TAKE INTERNALLY.
Other Precautions:CLOSE CONTR AFTER EACH USE. EMPTY CONTRS MUST NOT BE
WASHED & REUSED FOR ANY PURPOSE. CONTRS SHOULD BE GROUNDED & BONDED
TO RECEIVING CONTR. DO NOT WELD, BRAZE/CUT ON EMPTY CONTR. NEVER
USE PRESS TO E MPTY. DRUM IS NOT A PRESS VESSEL.
Respiratory Protection:PROPER SELECTION OF RESP PROT DEPENDS UPON MANY
FACTORS INCL DURATION/LEVEL OF EXPOS & CNDTNS OF USE. IN GEN EXPOS
TO ORG CHEM SUCH AS THOSE CONTAINED IN THIS PROD MAY NOT REQUIRE
USE OF RESP PROT IF USED IN WELL-VENT AREAS. (ING 9)
Ventilation:PROVIDE LOC EXHAUST VENT IN SUFFICIENT VOL & PATTERN SO AS
TO MAINTAIN EXPOS < NUISANCE DUST LIM & PERMISSIBLE (ING 14)
Protective Gloves:SOLVENT IMPERMEABLE GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS .
Other Protective Equipment:EMERGENCY EYEWASH & DELUGE SHOWER MEETING
ANSI DESIGN CRITERIA .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EXTING MEDIA:FIRES. POLYMER FOAM PREFERRED FOR LGE FIRES. FIRE FIGHT
PROC:POSS AUTO-IGNIT/EXPLO WHEN EXPOSED TO EXTREME HEAT. IF WATER
IS USED, FOG NOZZ PREFERABLE. EFTS OF OVEREXP:OF OCCUP CHEM REPRO
HAZ. SEEK CONSULTATION FROM APPROP HLTH PROFESSIONALS CONCERNING
LATEST HAZ LIST INFO & SAFE HNDLG & EXPO INFO .
Boiling Pt:B.P. Text:>168F,>76C
Vapor Pres:SEE INGS
Vapor Density:HVR/AIR
Spec Gravity:0.9
Evaporation Rate & Reference:SLOWER THAN DIETHYL ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
Percent Volatiles by Volume:100
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS OR ALKALINE MATERIALS.
Stability Condition to Avoid:AVOID EXCESSIVE HEAT (>115F/46C) AND
SOURCES OF IGNITION.
Hazardous Decomposition Products:BURNING, INCLUDING WHEN HEATED BY
WELDING OR CUTTING, WILL PRODUCE SMOKE, CARBON MONOXIDE AND CARBON
DIOXIDE.
Waste Disposal Methods:DISPOSE OF I/A/W LOC, STATE & FED REGS. THIS
PROD, IF DISCARDED DIRECTLY, WOULD BE CLASSIFIED AS HAZ WASTE BASED
ON ITS IGNITABILITY CHARACT, I.E. HAS A FL PT OF 140F (60C)/LESS.
THE PROPER RCRA CLASS IFICATION WOULD BE D001.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.