===================== Product Identification =====================
MSDS NAME:PR-1167 URETHANE PRIMER
NIIN:00N003817
MSDS Number: BYHFJ
=== Responsible Party ===
Company:CONAP INC
Address:1405 BUFFALO ST
City:OLEAN
State:NY
ZIP:14760
Country:US
Info Phone Num:716-372-9650
Emergency Phone Num:800-424-9300 (CHEMTREC)
Preparer's Name:MARVIN A FRIEDMAN
CAGE:DO146
=== Contractor Identification ===
Company:CONAP INC
Address:1405 BUFFALO ST
City:OLEAN
State:NY
ZIP:14760-1139
Phone:716-372-9650
CAGE:DO146
Company:CONAP INC.,WHOLLY OWNED SUBSIDIARY OF CYTEC INDUSTRIES
INC.
Address:1405 BUFFALO STREET
Box:City:OLEAN
State:NY
ZIP:14760
Country:US
Phone:716-372-9650
CAGE:16245
============= Composition/Information on Ingredients =============
Name:XYLENE (SARA 313) (CERCLA)
CAS:1330-20-7
RTECS #:ZE2100000
Fraction by Wt: 15-25%
OSHA PEL:100 PPM
ACGIH TLV:100 PPM/150 STEL
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:SOLVENT NAPHTHA (PETROLEUM), LIGHT AROMATIC; (PETROLEUM
NAPHTHA, LIGHT AROMATIC SOLVENT)
CAS:64742-95-6
RTECS #:WF3400000
Fraction by Wt: 15-25%
OSHA PEL:N/K
ACGIH TLV:N/K
Name:ISOCYANIC ACID, METHYLENEDI-P-PHENYLENE ESTER; (METHYLENE
BISPHENYL ISOCYANATE) (MDI) (SARA 313)
CAS:101-68-8
RTECS #:NQ9350000
Fraction by Wt: 10-14%
OSHA PEL:C 0.02 PPM
ACGIH TLV:0.005 PPM
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50:(ORAL,RAT) >5 G/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE:DIRECT CONTACT WITH THIS
MATERIAL MAY CAUSE MODERATE EYE AND SKIN IRRITATION. INHALATION
OVEREXPOSURE MAY CAUSE ALLERGIC RESPIRATORY REACTION. REPEATED AND
PROLONGED DERMATITIS CONTACT WITH THIS MATERIAL MAY CAUSE ALLERGIC
SKIN REACTION. INHALATION OVEREXPOSURE MAY CAUSE IRRITATION OF
RESPIRATORY TRACT AND EYES. TOXICOLOGICAL INFORMATION FOR PRODUCT
IS UNDER SECTION 3. HAZARDS IDENTIFICATION . TOXICOLOGICAL
INFORMATION ON OSHA REGULATED COMPONENTS OF THIS PRODUCT IS AS
FOLLOWS:ACUTE OVEREXPOSURE TO METHYLENEDIPHENYL DIISOCYANATE (MDI)
VAPOR MAY CAUSE SEVERE RESPIRATORY IRRIT. RPTD OVEREXP TO LOW LEV
MAY (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: CAUSE RESP SENSIT & ALLERGIC RXN.
RESP SENSIT MANIFESTS ITSELF AS SEV BRTHG DFCLTY SIMILAR TO ASTHMA.
THIS RXN MAY OCCUR 6-24 HRS AFTER EXPOS & @ EXPOS LEV BELOW EST PEL
LIM. SKIN EXPOS TO L IQ MAY CAUSE MOD IRRIT & ALLERGIC SKIN RXN. IT
IS ALSO EYE IRRITANT. ORAL LD50 IN RATS IS >15.8 G/KG. DERM LD50 IN
RABBITS IS >7.9 G/KG. 2-HR INHAL LC50 OF DUST OF MONOMERIC MDI IS
>400 MG/M3 (0.20 MG /L/4H4). MATL WAS MUTAGENIC IN AMES TEST.
HOWEVER, IT WAS NEG IN MOUSE MICRONUCLEUS ASSAY. XYLENE HAS ACUTE
ORAL LD50 (RAT) OF 4.3 G/KG & 4-HR INHAL LC50 (RAT) OF 5000-67000
PPM. LIQ XYLENE IS SEV EY E & MOD SKIN IRRITANT. (SUPDAT)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INGEST:CALL MD IMMEDIATELY . SKIN:IMMED WASH AFFECTED AREAS
W/SOAP & PLENTY OF WATER. REMOVE CONTAMD CLTHG & SHOES. OBTAIN MED
ATTN. DESTROY/THORO CLEAN SHOES BEFORE REUSE. DO NOT REUSE CONTAMD
CLTHG W/OUT LAUNDERING. EYE:IMMED IRRIGATE W/PLENTY OF WATER FOR @
LEAST 15 MINS. OBTAIN MED ATTN IF IRRIT PERSISTS. INHAL:REMOVE FROM
EXPOS. ADMIN OXYG IF THERE IS DFCLTY IN BRTHG. GIVE ARTF RESPIRAT
ION IF PERSON IS NOT BRTHG & CONTINUE UNTIL NORM BRTHG IS EST.
OBTAIN MED ATTN W/OUT DELAY.
===================== Fire Fighting Measures =====================
Flash Point Method:CC
Flash Point:81.0F,27.2C
Extinguishing Media:USE CARBON DIOXIDE, DRY CHEMICAL, WATER OR ALCOHOL
FOAM. IF WATER SPRAY/ALCOHOL FOAM IS USED, IT SHOULD BE IN LG QTYS.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT . USE WATER TO KEEP FIRE-EXPOSED CONTAINERS COOL.
Unusual Fire/Explosion Hazard:WATER OR ALCOHOL FOAM MAY REACT
VIGOROUSLY W/HOT ISOCYANATE RELEASING CARBON DIOXIDE. DO NOT RESEAL
CONTAMD CNTNRS SINCE PRESS BUILD-UP MAY CAUSE RUPTURE.
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE SOURCES OF IGNIT. WHERE EXPOS LEV IS
NOT KNOWN, WEAR NIOSH/MSHA APPRVD, POS PRESS, SELF-CONTAINED RESP.
WHERE EXPOS LEV IS KNOWN, WEAR NIOSH/MSHA APPRVD RESP SUITABLE FOR
LEV OF EXPOS. IN ADDN TO PROT CLTHG/EQUIP IN CONTROL MEASURES
SECTION WEAR IMPERVIOUS BOOTS. COVER SPILLS W/SOME INERT ABSORB
MATL; SWEEP UP & PLACE IN WASTE DISP CNTNR. FLUSH AREA WITH WATER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:STATEMENTS OF HAZARD:WARNING:FLAM LIQ
& VAP. CNTNS DIPHENYLMETHANE DIISOCYANATE (MDI). MAY CAUSE SEV
ALLERGIC RESP RXN. HARMFUL IF INHALED.
Other Precautions:VAP EXTREMELY IRRIT. MAY CAUSE ALLERGIC SKIN. CAUSES
EYE IRRIT. CONTAM/EXCESS HEAT MAY RSLT IN DANGEROUS PRESS. CHRONIC
HAZ WARNING:CHRONIC TOX HAZ. CNTNS MATL WHICH MAY CAUSE RESP SYS
DMG. RISK OF EF TS DEPEND ON DURATION & LEV OF EXPOS. KEEP AWAY
FROM HEAT, SPK, & FLAME. DO NOT BREATHE VAP. AVOID C ONT (OTHER
INFO)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WHERE EXPOSURES ARE BELOW PEL LIM, NO RESP PROT
IS REQD. WHERE EXPOS EXCEED PEL, USE NIOSH/MSHA APPRVD RESP FOR
MATL & LEVEL OF EXPOSURE. SEE "GUIDE TO INDUSTRIAL RESPIRATORY
PROTECTION" (NIOSH).
Ventilation:WHERE MATL IS NOT USED IN CLSD SYS, GOOD ENCLOSURE & LOC
EXHUAST VENT SHOULD BE PROVIDED TO CONTROL EXPOSURE.
Protective Gloves:IMPERVIOUS GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:APRON, WORKPANTS, LONG SLEEVE WORK
SHIRT/DISPOSABLE COVERALLS ARE REC TO PVNT SKIN CONT. EYEWASH EQUIP
& SFTY SHOWER SHOULD BE PROVIDED IN AREAS OF POTENTIAL EXPOSURE.
Work Hygienic Practices:FOOD, BEVERAGES, & TOBACCO PRODS SHOULD NOT BE
CARRIED, STORED/CONSUMED WHERE MATL IS IN USE. BEFORE EATING,
DRINKING/SMOKING, WASH FACE & HANDS W/SOAP & WATER. AVOID SKIN
CONT. SHOWER AFTER(OTHER INFO)
Supplemental Safety and Health
EFTS OF OVEREXP: ACUTE OVEREXP TO XYLENE VAP MAY CAUSE RESP & EYE
IRRIT, HDCH, NAUS, DIZZ, STAGG GAIT, & FATG. RPTD OVEREXP TO XYLENE
MAY CAUSE REVERSIBLE EYE DMG, PERIPHERAL & CENTRAL NEUROPATHY. CHR
ONIC EXPOS TO HIGH CONC OF XYLENE MAY CAUSE LIVER & KIDNEY DMG.
ACUTE OVEREXP TO PETRO NAPTHA VAPS MAY CAUSE(OTHER INFO)
================== Physical/Chemical Properties ==================
Spec Gravity:1.01
Evaporation Rate & Reference:NOT KNOWN
Solubility in Water:NEGLIGIBLE
Appearance and Odor:BROWN LIQUID, SLIGHT AROMATIC HYDROCARBON ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
CAN REACT WITH WATER TO BUILD UP PRESS IN CLOSED CONTAINERS. AVOID
ACIDS, BASES, STRONG ACIDS, OXIDIZING AGENTS & WATER.
Stability Condition to Avoid:AVOID CONTACT W/ACIDS, OXIDIZING AGENTS,
BASES OR AMINES. DO NOT HEAT ABOVE 400F (204.4C).
Hazardous Decomposition Products:THERM DECOMP/COMBUST MAY PRDCE SODIUM
HYPOCHLORITE, CALCIUM HYPOCHLORITE, OXIDES OF CARBON, OXIDES OF
NITROGEN, MDI VAPORS, & TRACE OF HCN.
=================== Toxicological Information ===================
Toxicological Information:OTHER INFO: SHOULD HAVE FIRE-SAFE PRACTICES &
ELEC EQUIP I/A/W ELEC & FIRE PROT CODES (NFPA-30) GOVERNING CLASS I
FLAMMABLE LIQUIDS. HYGIENE PRACT: COMPLETION OF WORKSHIFT. LAUNDER
WORK CLTHG @ END OF WORKSHIFT PRIOR TO REUSE. STORE STREET CLTHG
SEPARATELY FROM WORK CLTHG & PROT EQUIP. WORK CLTHG & SHOES MUST
NOT BE TAKEN HOME.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSAL MUST BE MADE IN ACCORDANCE WITH
APPLICABLE GOVERNMENTAL, STATE, AND LOCAL REGULATIONS.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
*** END OF RECORD *** |
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