===================== Product Identification =====================
MSDS NAME:PGR
NIIN:00N010570
MSDS Number: BYHFQ
=== Responsible Party ===
Company:STATE CHEMICAL MFG CO
Address:3100 HAMILTON AVE
City:CLEVELAND
State:OH
ZIP:44114-3763
Country:US
Info Phone Num:216-861-7114
Emergency Phone Num:216-861-7114
CAGE:53798
=== Contractor Identification ===
Company:STATE CHEMICAL MANUFACTURING CO.
Address:3100 HAMILTON AVENUE
Box:City:CLEVELAND
State:OH
ZIP:44114-3701
Country:US
Phone:216-861-7114
CAGE:53798
============= Composition/Information on Ingredients =============
Name:ING 6:IDENTIFIED AS A SUSPECT CARCINOGEN BY NTP.
RTECS #:9999999ZZ
Name:FIRST AID PROC:CARBOXYHEMOGLOBIN LEVELS. MAY INCR
MYOCARDIAL IRRIT. AVOID EPIREPHINE/SIMILAR ACTING DRUGS (ING 9)
RTECS #:9999999ZZ
Name:ING 8:IF AT ALL POSSIBLE.
RTECS #:9999999ZZ
Name:HNDLG/STOR PREC:WINDY DAY WHEN OVERSPRAY CAN BLOW BACK ONTO
SKIN. FLAMM. DO NOT STORE IN DIRECT SUNLIGHT/TEMP (ING 11)
RTECS #:9999999ZZ
Name:ING 10:EXCEEDING 120F. DO NOT STORE NEAR SPKS/OPEN FLAMES.
CONTENTS UNDER PRESS. DO NOT PUNCTURE/INCIN CANS. (ING 12)
RTECS #:9999999ZZ
Name:ING 11:USE PROD OUTDOORS IF POSS. IF YOU MUST USE IT
INDOORS, OPEN ALL WINDOWS & DOORS/USE OTHER MEANS TO (ING 13)
RTECS #:9999999ZZ
Name:ING 12:INSURE FRESH AIR MOVEMENT DURING APPLIC & DRYING. IF
PROPERLY USED, NIOSH/MSHA APPRVD RESP MAY OFFER (ING 14)
RTECS #:9999999ZZ
Name:ING 13:ADDNTL PROT. NIOSH/MSHA APPRVD DUST MASK DOES NOT
PROVIDE PROT AGAINST VAPS. DO NOT USE IN BASEMENT/ (ING 15)
RTECS #:9999999ZZ
Name:ING 14:OTHER UNVENT AREAS. CLEAN UP RAGS. PAPERS, & WASTE
PROMPTLY. ALLOW SOLV TO EVAP, THEN DISPOSE OF IN METAL(ING 16)
RTECS #:9999999ZZ
Name:ING 15:CNTNRS. DO NOT USE ON RUBB, PLASTIC, LINOLEUM/ANY
OTHER ORG MATLS. TO PVNT CLOGGING, TURN CAN UPSIDE (ING 17)
RTECS #:9999999ZZ
Name:ING 16:DOWN & SPRAY SHORT JET OF GAS AFTER EACH JOB. FOLLOW
ALL LBL DIRECTIONS & PREC BEFORE USING PROD. THESE (ING 18)
RTECS #:9999999ZZ
Name:ING 17:PRODS ARE INTENDED FOR INDUST & INSTITUTIONAL USE
ONLY. NOT FOR HOUSEHOLD USE/RESALE. KEEP OUT OF REACH (ING 19)
RTECS #:9999999ZZ
Name:ING 18:OF CHILDREN.
RTECS #:9999999ZZ
Name:METHANE, DICHLORO-; (METHYLENE CHLORIDE) (SARA 313)
(CERCLA)
CAS:75-09-2
RTECS #:PA8050000
Fraction by Wt: >60%
OSHA PEL:500 PPM; Z-2
ACGIH TLV:50 PPM, A2
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:METHYL ALCOHOL (METHANOL) (SARA 313) (CERCLA)
CAS:67-56-1
RTECS #:PC1400000
Fraction by Wt: <10%
OSHA PEL:S, 200 PPM
ACGIH TLV:S, 200 PPM/250 STEL
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:PROPANE
CAS:74-98-6
RTECS #:TX2275000
Fraction by Wt: <20%
OSHA PEL:1000 PPM
ACGIH TLV:ASPHYXIANT
Name:PROPANE, 2-METHYL-; (ISOBUTANE)
CAS:75-28-5
RTECS #:TZ4300000
Fraction by Wt: <20%
OSHA PEL:N/K
ACGIH TLV:1000 PPM (MFR)
Name:BUTANE; (N-BUTANE)
CAS:106-97-8
RTECS #:EJ4200000
Fraction by Wt: <20%
OSHA PEL:800 PPM
ACGIH TLV:800 PPM
Name:SUPDAT:LOSS OF SENSE OF BALANCE & VISUAL DISTURB. ALSO
COULD CAUSE LIVER DISEASE. METHYLENE CHLORIDE HAS BEEN (ING 7)
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:CHLOROCARBON MATLS HAVE PRDCED SENSIT
OF MYOCARDIUM TO EPINEPHRINE IN LAB ANIMALS & COULD HAVE A SIMILAR
EFT IN HUMANS. ADRENOMIMETICS (E.G. EPINEPHRINE) MAY BE
CONTRAINDICATED EXCEPT FOR LIFE-SUSTAIN ING USES IN HUMANS ACUTELY
OR CHRONICALLY EXPOSED TO CHLOROCARBONS . ACUTE:MAY BE FATAL/CAUSE
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:METHYLENE CHLORIDE:IARC MONO SUPP, VOL
7, PG 194, 1987:GROUP 2B. NTP 7TH ANNUAL RPT ON CARCIN, 1994:ANTIC
TO BE (SUPDAT)
Effects of Overexposure:HLTH HAZ:BLINDNESS IF SWALLOWED. CNTNS
METHANOL. VAP HARMFUL. CNTNS METHYLENE CHLORIDE. OVEREXP TO VAPS
MAY RSLT IN HDCH, NAUS, DROW, DIZZ, NASAL & RESP IRRIT. DELIBERATE
INHAL OF CONTENTS CAN BE HARM FUL/FATAL. EYE IRRITANT. DIRECT CONT
W/SKIN WILL RSLT IN IRRIT. CHRONIC:CAN CAUSE MENTAL CONFUSN,
DEPRESS, (SUPDAT)
Medical Cond Aggravated by Exposure:HEART DISEASE, RESPIRATORY
DISORDERS.
======================= First Aid Measures =======================
First Aid:INGEST:DO NOT INDUCE VOMIT. CALL PHYS IMMED. INHAL:REMOVE
PERSON TO FRESH AIR. IF DFCLTY IN BRTHG OR OTHER SYMPS PERSIST,
CALL PHYS. EYES:FLUSH IMMED W/PLENTY OF COOL WATER FOR @ LEAST 15
MINS. CONT P HYS IMMED. DO NOT WEAR CONT LENSES WHILE WORKING
W/THIS PROD. SKIN:WASH PROMPTLY W/PLENTY OF WATER. IF IRRIT
PERSISTS CONT PHYS. NOTE TO PHYS:OVEREXP TO METHYLENE CHLORIDE MAY
PRDCE ELEVATED (ING 8)
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:-142F,-97C
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL OR FOAM.
Fire Fighting Procedures:NIOSH/MSHA APPRVD PRESS DEMAND SCBA & FULL
PROT EQUIP . WATER MAY BE INEFTIVE, BUT MAY BE USED TO KEEP CANS
COOL. USE SHIELDING TO PROTECT PERS (SUPDAT)
Unusual Fire/Explosion Hazard:THERMAL DECOMPOSITION PRODUCTS MAY
INCLUDE HCL & PHOSGENE . FLAMMABLE. EXPOSURE TO TEMPERATURES ABOVE
120F MAY CAUSE CAN TO VENT, RUPTURE OR BURST.
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE ALL SOURCES OF HEAT, SPARKS OR OPEN
FLAMES. VENTILATE AREA OF SPILL. ABSORB SPILL ON OIL ABSORBENT,
SAND OR VERMICULITE.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:DANGER:POISON. MAY BE HARMFUL/FATAL IF
SWALLOWED. VAP HARMFUL. DIRECT CONT W/EYES OR SKIN WILL RSLT IN
IRRIT. AVOID USING PROD OUTDOORS ON (ING 10)
Other Precautions:NO SMOKING IN AREA OF USE. DO NOT USE IN GEN VICINITY
OF ARC WELDING, OPEN FLAMES OR HOT SURFACES. HEAT &/OR UV RADIA MAY
CAUSE FORMATION OF HCL &/OR PHOSGENE .
============= Exposure Controls/Personal Protection =============
Respiratory Protection:VAPOR HARMFUL. AVOID BRTHG OF VAPORS/SPRAY MIST
OF THIS PROD. WEAR NIOSH/MSHA APPRVD SCBA IF PROD MUST BE USED IN
CONFINED AREA. WEAR NIOSH/MSHA APPRVD CARTRIDGE RESP IF TLV IS
EXCEEDED OR WHEN SPRAYI NG MORE THAN ON-HALF CAN CONTINUOUSLY.
Ventilation:USE WITH ONLY ADEQUATE LOCAL MECHANICAL VENTILATION.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPRVD CHEM WORKERS GOGG .
Other Protective Equipment:HAVE A SOURCE OF COOL, CLEAN WATER NEARBY IN
CASE OF ACCIDENTAL EYE OR SKIN CONT. WEAR LONG PANTS & LONG
SLEEVES.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
FIRE FIGHT PROC:FROM VENTING, RUPTURING OR BURSTING CANS. MATLS TO
AVOID:ON RUBBER, PLASTIC, LINOLEUM OR ANY ORGANIC MATL. HAZ DECOMP
PROD:OF PHOSGENE GASES. EXPLAN OF CARCIN:CARCIN. ANIMAL:LUNG, LIV,
SALIVARY, MAMMARY GLAND (TUMORS). EFTSOF OVEREXP:FATG, LOSS OF
APPETITE, NAUS, VOMIT, COUGH, (ING 6)
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:>-40F,>-40C
Vapor Density:4.0
Spec Gravity:0.9 (WATER =1)
Evaporation Rate & Reference:NOT KNOWN
Solubility in Water:NIL
Appearance and Odor:A CLEAR AEROSOL GEL WITH A STRONG SOLVENT ODOR.
Percent Volatiles by Volume:>90
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS, CAUSTICS OR CHEMICALLY ACTIVE LIGHT METALS. MAY
ADVERSELY AFFECT SOME PLASTICS. DO NOT USE (SUPDAT)
Stability Condition to Avoid:FLAMMABLE. DO NOT EXPOSE TO TEMPERATURES
ABOVE 120F, SPARKS OR OPEN FLAMES.
Hazardous Decomposition Products:BURNING THIS PROD MAY RSLT IN
FORMATION OF CARBON MONOXIDE, CARBON DIOXIDE, HYDROGEN CHLORIDE OR
TRACES (SUPDAT)
==================== Disposal Considerations ====================
Waste Disposal Methods:DO NOT INCIN CANS. CONTENTS UNDER PRESS. DISP OF
LIQ AS AN EPA RCRA HAZARDOUS WASTE. FOLLOW ALL FEDERAL, STATE AND
LOCAL REGULATIONS REGARDING WASTE DISPOSAL.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
*** END OF RECORD *** |
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