===================== Product Identification =====================
MSDS NAME:31590 DIETHANOLAMINE
NIIN:00F046508
MSDS Number: BYNBL
=== Responsible Party ===
Company:SIGMA CHEMICAL COMPANY
Address:3050 SPRUCE ST
Box:14508
City:SAINT LOUIS
State:MO
ZIP:63178-5000
Country:US
Info Phone Num:314-771-5765/800-325-3010
Emergency Phone Num:314-771-5765/800-325-3010
CAGE:21076
=== Contractor Identification ===
Company:ALDRICH CHEMICAL CO INC
Address:1001 WEST ST PAUL AVE
Box:355
City:MILWAUKEE
State:WI
ZIP:53233
Country:US
Phone:414-273-3850
CAGE:60928
Company:FLUKA CHEMICAL CORP
Address:1001 WEST ST PAUL
Box:City:MILWAUKEE
State:WI
ZIP:53233
Country:US
Phone:414-273-3850
CAGE:63181
Company:SIGMA CHEMICAL COMPANY
Address:3050 SPRUCE ST
Box:14508
City:ST LOUIS
State:MO
ZIP:63178
Country:US
Phone:314-771-5765
CAGE:21076
============= Composition/Information on Ingredients =============
Name:DIETHANOLAMINE, DIETHYLOLAMINE, DIOLAMINE,
2,2'-IMINODIETHANOL *95-4*
CAS:111-42-2
RTECS #:KL2975000
Other REC Limits:3 PPM
ACGIH TLV:13 MG/CUM
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL LD50(RAT): 710 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:HARMFUL IF SWALLOWED, INHALED/ABSORBED
THROUGH SKIN. CORROSIVE, CAUSES BURNS. EXTREMELY DESTRUCTIVE TO
TISSUE OF THE MUCOUS MEMBRANES & UPPER RESPIRATORY TRACT, EYES &
SKIN. INHALATION MAY BE FATAL AS A RESULT OF SPASM, INFLAMMATION &
EDEMA OF THE LARYNX & BRONCHI, CHEMICAL PNEUMONITIS & PULMONARY
EDEMA.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:BURNING SENSATION, COUGHING, WHEEZING,
LARYNGITIS, SHORTNESS OF BREATH, HEADACHE, NAUSEA, VOMITING, BURNS.
======================= First Aid Measures =======================
First Aid:EYES/SKIN: IMMEDIATELY FLUSH W/COPIOUS AMOUNTS OF WATER FOR
15 MINS. INHALATION: REMOVE TO FRESH AIR. GIVE CPR/OXYGEN IF
NEEDED. INGESTION: WASH OUT MOUTH W/WATER PROVIDED PERSON IS
CONSCIOUS. OBTAIN MEDICAL ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Flash Point:280F
Lower Limits:1.6
Upper Limits:10.6
Extinguishing Media:CO2, DRY CHEMICAL POWDER/APPROPRIATE FOAM.
Fire Fighting Procedures:WEAR SCBA & PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS.
AUTOIGNITION TEMP: 689F.
================== Accidental Release Measures ==================
Spill Release Procedures:EVACUATE AREA. SHUT OFF IGNITION SOURCES. WEAR
SCBA, RUBBER BOOTS & HEAVY RUBBER GLOVES. ABSORB ON
SAND/VERMICULITE & PLACE IN CLOSED CONTAINERS FOR DISPOSAL.
VENTILATE AREA & WASH SITE AFTER MATERIAL PICKUP IS COMPLETE.
====================== Handling and Storage ======================
Handling and Storage Precautions:KEEP TIGHTLY CLOSED. HYGROSCOPIC.
STORE UNDER NITROGEN. STORE IN A COOL DRY PLACE.
Other Precautions:DON'T BREATHE VAPOR, GET IN EYES, ON SKIN/CLOTHING.
AVOID PROLONGED/REPEATED EXPOSURE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WEAR APPROPRIATE NIOSH/MSHA APPROVED RESPIRATOR
Ventilation:USE ONLY IN A CHEMICAL FUME HOOD.
Protective Gloves:CHEMICAL RESISTANT
Eye Protection:SAFETY GOGGLES
Other Protective Equipment:PROTECTIVE CLOTHING, SAFETY SHOWER, EYE
BATH, FACESHIELD (8-IN MINIMUM)
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE. WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:422.6F
Melt/Freeze Pt:M.P/F.P Text:80.6-86F
Vapor Pres:<0.98
Vapor Density:3.6
Spec Gravity:1.097
Appearance and Odor:WHITE SOLID/COLORLES LIQUID
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
OXIDIZING AGENTS, COPPER, COPPER ALLOYS, ZINC, GALVANIZED IRON, ACID &
ABSORBS CO2 FROM AIR.
Stability Condition to Avoid:MOISTURE.
Hazardous Decomposition Products:THERMAL: CO, CO2, NITROGEN OXIDES.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISSOLVE/MIX THE MATERIAL W/COMBUSTIBLE SOLVENT
& BURN IN A CHEMICAL INCINERATOR EQUIPPED W/AFTERBURNER & SCRUBBER.
DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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