tetraphenylolethane/ech resin propane, 1,2-epoxy-3-phenoxy-; (phenyl glycidyl ether) propane, 1-chloro-2, 3-epoxy-; (epichlorohydrin) (sara supp data:sufficient. it has been classified as an first aid proc:if brthg is dfclt. give artf resp if not ing 5:unconscious/very drowsy. otherwise, give no more than ing 6:(2 tbsps) syrup of ipecac. if ipecac is unavail, give ing 7:to back of victim's throat. keep victim's head below ing 8:such as loss of gag reflex, convls/uncon occur before ing 9:following intubation w/cuffed endotracheal tube. spill proc:for reclaiming/disp. keep out of surf waters, ing 11:notify auths if any expos to gen public/environ ing 12:product is 500,000 lbs, which is based on the
LD50 LC50 Mixture:SEE INGREDIENTS.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:EYE/SKIN CONT:BASED ON SIMILAR PROD
TESTING, PROD IS PRESUMED TO BE MILDLY IRRIT. DUST CAN PRDCE MECH
IRRIT OF EYES. INHAL:PROD MAY PRDCE DUST WHICH MAY CAUSE MECH IRRIT
OF NOSE, THROAT & RESP TRACT. INGEST:BASED ON SIMILAR PROD
TESTING, PROD IS PRESUMED TO BE SLIGHTLY TOX. ING 1:IN TESTING DONE
ON (EFTS OF OVEREXP)
Explanation of Carcinogenicity:PHENYL GLYCIDYL ETHER (PGE):IARC
MONOGRAPHS ON EVAL OF CARCIN RISK OF CHEMS TO MAN, VOL 47, PG 237,
1989: GROUP 2B.
Effects of Overexposure:HLTH HAZ:SOLN OF THIS PROD, IN METHYL ETHYL
KETONE, IT WAS FOUND THAT PROD WAS POS IN IN-VITRO MUTAGENICITY
ASSAYS:SALMONELLA, MOUSE LYMPHOMA CELLS & CHINESE HAMSTER OVARY
CELLS. ING 2:WAS FOUND TO BE MUTAGENIC IN IN-VITRO ASSAYS. MAY
CAUSE CNS DEPRESS, ATOXIA & INCOORD VIA INGEST. ING
3:EPICHLOROHYDRIN HAS (SUPDAT)
Medical Cond Aggravated by Exposure:PREEXISTING SKIN, EYE & RESPIRATORY
DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO THIS PRODUCT.
======================= First Aid Measures =======================
First Aid:EYE:FLUSH W/PLENTY OF WATER FOR AT LST 15 MINS WHILE HOLDING
EYELIDS OPEN. GET MED ATTN. SKIN:REMOVE CONTAM CLTHG/SHOES & WIPE
EXCESS FROM SKIN. FLUSH SKIN W/WATER. FOLLOW BY WASHING W/SOAP &
WATER. I F IRRIT OCCURS, GET MED ATTN. DO NOT RE-USE CLTHG UNTIL
CLEANED. CONTAM LEATHER ARTICLES, INCL SHOES, CANNOT BE DECONTAM &
SHOULD BE DESTROYED. INHAL:REMOVE VICTIM TO FRESH AIR & PROVIDE
OXYG (ING 5)
===================== Fire Fighting Measures =====================
Extinguishing Media:USE WATER FOG, "ALCOHOL" FOAM, DRY CHEMICAL OR
CO*2.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT . MATERIAL WILL NOT BURN UNLESS PREHEATED. COOL FIRE
EXPOSED CONTAINERS W/WATER.
Unusual Fire/Explosion Hazard:EXPLOSIVE DUST CLOUDS MAY BE PRODUCED.
Spill Release Procedures:WEAR NIOSH/MSHA APPRVD RESP & APPROP PERSONAL
PROT CLTHG. MAY BURN, ALTHOUGH NOT READILY IGNITABLE. USE CAUTIOUS
JUDGEMENT WHEN CLEANING UP LG SPILLS. SHOVEL & SWEEP UP/USE INDUS
VACUUM CLEANER. AVOID GENERATING DUST CLOUDS. PUT INTO CNTNRS (ING
11)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:AVOID BRTHG DUST. AVOID CONT W/EYES,
SKIN & CLTHG. STATIC ELEC MAY ACCUM & CREATE FIRE HAZ. GROUND FIXED
EQUIP. BOND & GROUND TRANSFER CNTNRS & EQUIP.
Other Precautions:CNTNRS, EVEN THOSE THAT HAVE BEEN EMPTIED, CAN
CONTAIN RESIDUES OF DUST/SOLID PARTICULATES; THESE RESIDUES MAY
CREATE BOTH HLTH & FIRE/EXPLO HAZS. HANDLE I/A/W HAZ POTNTL OF
CURING AGENT USED. BE SAFE . READ PRODUCT SAFETY INFO & PASS IT ON.
Respiratory Protection:IF EXPOSURE MAY OR DOES EXCEED OCCUPATIONAL
EXPOSURE LIMITS, USE A NIOSH/MSHA APPROVED RESPIRATOR TO PREVENT
OVEREXPOSURE. I/A/W 29 CFR 1910.134 USE EITHER A NIOSH/MSHA APPRVD
ATM-SUPPLYING RESP OR AI R-PURIFYING RESP FOR PARTICULATES.
Ventilation:USE EXPLOSION-PROOF VENTILATION AS REQUIRED TO CONTROL DUST
CONCENTRATIONS.
Protective Gloves:CHEMICAL-RESISTANT GLOVES.
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA . WEAR PROTECTIVE CLOTHING.
Work Hygienic Practices:WASH W/SOAP & WATER BEFORE EATING, DRINKING,
SMOKING OR USING TOILET FACILITIES. LAUNDER CONTAM CLTHG BEFORE
REUSE.
Supplemental Safety and Health
MATLS TO AVOID:PRIMARY & SECONDARY ALIPHATIC AMINES. EFTS OF
OVEREXP:BEEN REPORTED TO PRDCE CANCER IN LAB ANIMALS & TO PRDCE
MUTAGENIC CHANGES IN BACTERIA & CULTURED HUMAN CELLS. IT HAS BEEN
ESTABLISH ED BY IARC AS PROBABLE HUMAN CARCIN (GRP 2A) BASED ON
FOLLOWING CONCLUSIONS:HUMAN EVID:INADEQ; ANIMAL EVID: (ING 4)
Melt/Freeze Pt:M.P/F.P Text:>171F,>77C
Vapor Pres:<1
Vapor Density:>1
Spec Gravity:>1 (H*2O=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:DARK LUMPS.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
CAN REACT VIGOROUSLY W/STRONG OXIDIZING AGENTS, STRONG LEWIS/MINERAL
ACIDS & STRONG MINERAL & ORGANIC BASES/ESP (SUPDAT)
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:CARBON MONOXIDE, ALDEHYDES & ACIDS MAY
BE FORMED DURING COMBUST. RXN W/SOME CURING AGENTS MAY PRDCE
CONSIDERABLE HEAT.
Waste Disposal Methods:DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL
REGULATIONS . PLACE IN AN APPROPRIATE DISPOSAL FACILITY IN
COMPLIANCE W/LOCAL REGULATIONS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.