===================== Product Identification =====================
MSDS NAME:ALUMINUM SULFATE, SOLUTION
NIIN:00N068519
MSDS Number: CBHXV
=== Responsible Party ===
Company:GEO SPECIALTY CHEMCIALS INC
Address:9213 ARCH ST
City:LITTLE ROCK
State:AR
ZIP:72206
Country:US
Info Phone Num:501-888-1211
Emergency Phone Num:800-424-9300(CHEMTREC)
CAGE:GO736
=== Contractor Identification ===
Company:GEO SPECIALTY CHEMCIALS INC
Box:UNKNOW
CAGE:GESPE
Company:GEO SPECIALTY CHEMICALS INC
Address:701 WISSAHICKSON AVENUE
City:CEDARTOWN
State:GA
ZIP:30125
Country:US
Phone:770-748-1200
CAGE:GO736
============= Composition/Information on Ingredients =============
Name:ALUMINUM SULFATE (2:3); (ALUMINUM SULFATE, ANHYDROUS)
CAS:10043-01-3
RTECS #:BD1700000
Fraction by Wt: 26.6%
OSHA PEL:2 MG/M3
ACGIH TLV:2 MG/M3
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: BALANCE
OSHA PEL:N/K
ACGIH TLV:N/K
Name:SUPDAT:LG SPILLS SHOULD BE HNDLD ACCORD TO PREDETERMINED
PLAN. FOR ASSISTANCE IN DEVELOPING A PLAN, CALL (ING 4)
RTECS #:9999999ZZ
Name:ING 3:1-800-453-2586. REPORTABLE QUANTITY (RQ):5000 LB AS
100% AL*2(SO*4)*3.
RTECS #:9999999ZZ
Name:FIRST AID PROC:TOUCHING BACK OF THROAT W/FINGER. NEVER GIVE
ANYTHING BY MOUTH/INDUCE VOMIT IN UNCON/CONVULSING (ING 6)
RTECS #:9999999ZZ
Name:ING 5:PERSON. GET MED ATTN. SKIN:IMMED WASH W/SOAP & PLENTY
OF WATER WHILE REMOVING CONTAM CLTHG & SHOES. WASH (ING 7)
RTECS #:9999999ZZ
Name:ING 6:CONTAM CLTHG SEPARATELY BEFORE REUSE. INHAL:REMOVE
PATIENT TO FRESH AIR. IF NOT BRTHG ADMIN CPR/ARTF RESP. (ING 8)
RTECS #:9999999ZZ
Name:ING 7:IF BRTHG IS DFCLT/IRRIT DEVELOPS, GET MED ATTN.
EYES:IMMED FLUSH W/PLENTY OF WATER FOR @ LST 15 MIN USING (ING 9)
RTECS #:9999999ZZ
Name:ING 8:EYEWASH FOUNTAIN, IF AVAIL. LIFT UPPER & LOWER LIDS &
RINSE WELL UNDER THEM. GET MED ATTN, PREF AN (ING 10)
RTECS #:9999999ZZ
Name:ING 9:OPHTHALMOLOGIST. NOTES TO MD:ALL TREATMENTS SHOULD BE
BASED ON OBSERVED SIGNS & SYMPS OF DISTRESS IN (ING 11)
RTECS #:9999999ZZ
Name:ING 10:PATIENT. CONSIDERATION SHOULD BE GIVEN TO POSS THAT
OVEREXP TO MATLS OTHER THAN THIS PROD MAY HAVE (ING 12)
RTECS #:9999999ZZ
Name:ING 11:OCCURRED. ALUMINUM SOLUBLE SALTS MAY CAUSE
GASTROENTERITIS IF INGESTED. TREATMENT INCLUDES USE OF DEMULCENTS.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50(ORAL,RAT):>5000 MG/KG BODY WEIGHT
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INGEST:MAY CAUSE ABDOM PAIN, NAUS,
VOMIT. CAN CAUSE BURNS OF MOUTH, BLEEDING STOM, INCOORD, MUSCLE
SPASMS & KIDNEY INJURY. SKIN ABSORP:NO INFO AVAIL. INHAL:MISTS MAY
BE IRRIT TO MUC MEMBS & RESP TRACT . SKIN:MAY CAUSE IRRIT.
EYE:CAUSES IRRIT & INFLAM. MAY CAUSE SEV DMG. CHRONIC:NO EVIDENCE
OF ADDNL (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZS:ADVERSE EFTS FROM AVAIL INFO.
Medical Cond Aggravated by Exposure:SKIN IRRIT MAY BE AGGRAVATED IN
PERSONS W/EXISTING LEASIONS. BRTHG OF DUST/SPRAYS (MISTS) OF SOLNS
MAY AGGRAVATE ACUTE/CHRONIC ASTHMA & OTHER CHRONIC PULM DISEASE.
======================= First Aid Measures =======================
First Aid:REMOVE PATIENT FROM IMMED SOURCE OF EXPOS & ASSURE INDIVIDUAL
IS BRTHG. IF NOT BRTHG, USE ARTF RESP/CPR. GET MED ATTN. INGEST:IF
PATIENT IS CONSCIOUS & ALERT, GIVE 2/MORE GLASSES OF WATER/MILK TO
DRIN K. IF AVAIL, GIVE ONE TBSP OF SYRUP OF IPECAC TO INDUCE VOMIT.
IF VOMIT HAS NOT OCCURRED IN 20 MIN, SAME DOSE OF SYRUP OF IPECAC
MAY BE RPTD 1 ADDNL TIME. ALTERNATIVELY, INDUCE VOMIT BY (ING 5)
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:NOT COMBUST. USE APPROP EXTING MEDIA FOR MATL THAT
IS SUPPLYING FUEL. USE WATER SPRAY TO COOL SURROUNDING AREA
(SUPDAT)
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT . DIKE AREA TO PREVENT RUNOFF AND
CONTAMINATION OF WATER SOURCES.
Unusual Fire/Explosion Hazard:UNDER FIRE CNDTNS (OR @ TEMPS >650C
(1202F)), PROD DECOMPOSES TO GIVE OFF SULFUR TRIOXIDE, OXIDIZING
AGENT WHICH WILL SUPPORT COMBUST. SULFUR TRIOXIDE (SUPDAT)
================== Accidental Release Measures ==================
Spill Release Procedures:ABSORB SM SPILLS ON SAND/VERMICULITE. PLACE IN
APPROP CNTNRS FOR DISP. RESIDUAL SPILLAGE SHOULD BE CLEANED FROM
HARD SURFS AS APPROP. IF SPILLED ON GROUND, AFFECTED AREA SHOULD BE
SCRAPED CLEAN & MATL PLACED IN APPROP CNTNR FOR DISP. DO NOT
(SUPDAT)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:DO NOT BRTHE MISTS, SWALLOW, GET IN
EYES, ON SKIN/CLTHG. CNTNRS SHOULD BE STORED IN COOL AREA IN
TIGHTLY CLSD CNTNRS.
Other Precautions:AVOID STORING @ TEMPS NEAR/BELOW FREEZING POINT. PROT
EQUP SHOULD BE USED DURING:MFR/FORMULATION OF PROD, REPAIR &
MAINTENANCE OF CONTAM EQUIP, CLEAN UP OF LEAKS & SPILLS, ANY
ACTIVITY THAT MAY RLST I N EXPOS TO CONCS THAT EXCEED EXPOS LIMS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH/MSHA APPRVD RESP SUITABLE FOR PROT
FROM ACID DUSTS & MISTS IF CONC EXCEEDS SUGGESTED EXPOS LIMS. USE
NIOSH/MSHA APPRVD POS PRESS SUPPLIED AIR/SCBA FOR EMER/OTHER CNDTNS
WHERE HIGHER LEVEL OF PROT IS REQ.
Ventilation:PROVIDE ADEQ VENT. USE LOC EXHST AS NEEDED TO MAINTAIN
AIRBORNE EXPOS BELOW CTL LIMS.
Protective Gloves:RUBBER GLOVES.
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:ANSI APPROVED EMERGENCY EYE WASH AND DELUGE
SHOWER . LONG-SLEEVED CLOTHING. HAVE OXYGEN READILY AVAILABLE.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
PH (1% AQUEOUS SOLN):3.5. EXTING MEDIA:& TO MAINTAIN FIRE TEMP BELOW
DECOMP TEMP. EXPLO HAZS:WILL REACT W/WATER TO FORM SULFURIC ACID.
SPILL PROC:FLUSH MATL TO PUBLIC SEWER SYS/ANY WATERWAYS. WEAR APP
ROP PROT CLTHG & EQUIP DURING CLEAN UP ACTIVITIES. ENSURE ADEQ
DECONTAM OF TOOLS & EQUIP FOLLOWING CLEAN UP. (ING 3)
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:214F,101C
Melt/Freeze Pt:M.P/F.P Text:>5F,>-15C
pH:SUPDAT
Solubility in Water:MISCIBLE
Appearance and Odor:CLEAR, COLORLESS LIQUID @ 20C (68F)
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
REACTS WITH STRONG ALKALI TO FORM ALUMINUM HYDROXIDE. WEAKLY CORROSIVE
TO CARBON STEEL.
Stability Condition to Avoid:AT TEMPS >650C (1202F), PROD DEDCOMPOSES
TO FORM ALUMINUM OXIDE & SULFUR TRIOXIDE. PROT FROM HIGH TEMPS.
Hazardous Decomposition Products:THERMAL DECOMPOSITION PRODUCTS INCLUDE
ALUMINUM OXIDE AND SULFUR OXIDES.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND
FEDERAL REGULATIONS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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