=====================  Product Identification  =====================

MSDS NAME:SODIUM BISULFITE, TECHNICAL
NIIN:01-359-4918
MSDS Number: CCJGC
=== Responsible Party ===
Company:SILVER SALES
Address:5115 DOUGLAS FIR RD  SUITE C
City:CALABASES
State:CA
ZIP:91302
Country:US
Info Phone Num:818-591-0788
Emergency Phone Num:818-591-0788       WAS IN TX
Preparer's Name:DLA-HMIS STAFF
CAGE:0WG65
=== Contractor Identification ===
Company:SILVER SALES
Address:5115 DOUGLAS FIR RD  SUITE C
Box:City:CALABASES
State:CA
ZIP:91302
Country:US
Phone:818-591-0788	 WAS IN TX
CAGE:0WG65

=============  Composition/Information on Ingredients  =============

Name:SODIUM METABISULFITE/SODIUM BISULFITE
CAS:7681-57-4
RTECS #:UX8225000
Other REC Limits:NONE RECOMMENDED
OSHA PEL:5 MG/M3
ACGIH TLV:5 MG/M3; 9293

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:TLV IS 5 MG/M3 (RTECS).
Routes of Entry: Inhalation:YES  Skin:NO  Ingestion:NO
Reports of Carcinogenicity:NTP:NO    IARC:NO	OSHA:NO
Health Hazards Acute and Chronic:ACUTE- EYES:DUST/MIST MAY
    IRRITATE/BURN. SKIN:REPEATED/PROLONGED CONTACT WITH DUST/MIST MAY
    CAUSE IRRITATION. INHALATION:DUST/MIST MAY CAUSE RESPIRATORY TRACT
    IRRITATION. ORAL:MAY CAUSE GI IRRITATION.  VERY LARGE DOSES MAY
    CAUSE DEPRESSION &DEATH. CHRONIC- UNKNOWN. TARGET ORGANS:EYES,
    SKIN, LUNGS, GI TRACT.
Effects of Overexposure:EYES, SKIN, RESPIRATORY AND GASTROINTESTINAL
    TRACTS IRRITATION AND BURNS

=======================  First Aid Measures  =======================

First Aid:CALL A DOCTOR IF SYMPTOMS PERSIST. EYE: IMMEDIATELY FLUSH
    WITH WATER FOR 15 MINUTES, HOLDING EYELIDS OPEN. SKIN: WASH WITH
    SOAP & WATER. INHALED:REMOVE TO FRESH AIR. PROVIDE CPR/OXYGEN IF
    NEEDED. ORAL :IF CONSCIOUS, DRINK PLENTY OF WATER ORMILK. INDUCE
    VOMITING. CALL A PHYSICIAN/POISON CONTROL CENTER IMMEDIATELY.

=====================  Fire Fighting Measures  =====================

Flash Point:NON-FLAMMABLE
Extinguishing Media:WATER FOG, CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
    FULL FIRE FIGHTER'S PROTECTIVE GEAR. USE WATER TO COOL FIRE EXPOSED
    CONTAINERS.
Unusual Fire/Explosion Hazard:MAY FORM SODIUM SULFIDE WHICH IS AN
    EXPLOSIVE HAZARD AND STRONGLY ALKALINE IN CONTACT WITH WATER.

==================  Accidental Release Measures  ==================

Spill Release Procedures:VACUUM OR SWEEP UP SPILLAGE. AVOID CREATING
    DUST. PLACE SPILLAGE IN APPROPRIATE CONTAINER FOR WASTE DISPOSAL.
    VENTILATE AREA AND CAUTIOUSLY SPRAY RESIDUE WITH PLENTY OF WATER.
    AVOID BREATHING SULFUR D IOXIDE GAS WHICH WILL BE GENERATED DUE TO
    WATER.
Neutralizing Agent:ALKALI

======================	Handling and Storage  ======================

Handling and Storage Precautions:STORE IN COOL, DRY, WELL-VENTILATED
    PLACE AWAY FROM INCOMPATIBLE MATERIALS.
Other Precautions:DO NOT RAISE DUST. AVOID CONTACT WITH EYES AND SKIN.
    AVOID INHALATION OF DUST OR MIST. WASH THOROUGHLY AFTER HANDLING
    MATERIAL. KEEP OUT OF REACH OF CHILDREN. KEEP AWAY FROM WATER AND
    ACIDS.

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:IF WORKING IN A CONFINED AREA OR IF ENGINEERING
    CONTROLS DO NOT MAINTAIN AIRBORNE CONCENTRATIONS BELOW TLV, USE
    NIOSH- APPROVED SELF-CONTAINED BREATHING APPARATUS OR SUPPLIED AIR
    RESPIRATOR, OPERATED  IN POSITIVE PRESSURE MODE.
Ventilation:LOCAL EXHAUST
Protective Gloves:COTTON
Eye Protection:CHEMICAL SAFETY GOGGLES
Other Protective Equipment:EYE WASH STATION, HARD HAT, FULL WORK
    CLOTHING
Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND
    RECOMMENDED PROCEDURES. DO NOT WEAR CONTACT LENSES.
Supplemental Safety and Health
THIS MSDS HAS BEEN GENERATED FROM A SIMILAR ITEM IN SUPPORT OF A
    TECHNICAL SUPPORT REQUEST. THE MFG. HAS NOT RESPONDED TO REQUEST
    FOR A MSDS. THIS INFORMATION IN THE MSDS IS DEVELOPED BASED ON BEST
    AV AILABLE INFORMATION.

==================  Physical/Chemical Properties  ==================

HCC:C2
Decomp Temp:Decomp Text:>302F,>150C
Spec Gravity:1.48
Solubility in Water:APPRECIABLE
Appearance and Odor:FINE, WHITE, GRANULAR; PUNGENT SULFUR DIOXIDE GAS
    ODOR.

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, ACIDS, WATER.
Stability Condition to Avoid:TEMPERATURES ABOVE 150C (302F) AND
    MOISTURE.
Hazardous Decomposition Products:SULFUR DIOXIDE GAS, SODIUM SULFIDE
    RESIDUE

====================  Disposal Considerations  ====================

Waste Disposal Methods:NEUTRALIZE WITH ALKALI AND FLUSH TO SEWER WITH
    PLENTY OF WATER IF PERMITTED. GOOD VENTILATION IS REQUIRED DURING
    NEUTRALIZATION DUE TO RELEASE OF SO2 GAS. OXIDATION TO SODIUM
    SULFATE USING HYDROGEN PE ROXIDE MAY BE REQUIRED. OBSERVE ALL
    REGULATIONS.

 Disclaimer (provided with this information by the compiling agencies):
 This information is formulated for use by elements of the Department
 of Defense.  The United States of America in no manner whatsoever,
 expressly or implied, warrants this information to be accurate and
 disclaims all liability for its use.  Any person utilizing this
 document should seek competent professional advice to verify and
 assume responsibility for the suitability of this information to their
 particular situation.

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