===================== Product Identification =====================
MSDS NAME:WINDSHIELD DE-ICER
NIIN:00N073625
MSDS Number: CCNZC
=== Responsible Party ===
Company:VALVOLINE CO
Box:14000
City:LEXINGTON
State:KY
ZIP:40512
Country:US
Info Phone Num:606-357-7847
Emergency Phone Num:800-274-5263
CAGE:IO754
=== Contractor Identification ===
Company:THE VALVOLINE CO
Box:14000
City:LEXINGTON
State:KY
ZIP:40512
Country:US
Phone:606-357-7847
CAGE:IO754
Company:VALVOLINE OIL CO
Address:3499 BLAZER PKY
Box:14000
City:LEXINGTON
State:KY
ZIP:40512
Country:US
Phone:606-357-7206 / 800-274-5263
CAGE:72527
============= Composition/Information on Ingredients =============
Name:METHANOL; (METHYL ALCOHOL) (SARA 313) (CERCLA)
CAS:67-56-1
RTECS #:PC1400000
Fraction by Wt: 62%
OSHA PEL:200 PPM, S
ACGIH TLV:200 PPM; 250 STEL, S
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:ETHYLENE GLYCOL (SARA 313) (CERCLA)
CAS:107-21-1
RTECS #:KW2975000
Fraction by Wt: 6%
OSHA PEL:N/K
ACGIH TLV:50 PPM, VAPOR, C
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Name:CARBON DIOXIDE
CAS:124-38-9
RTECS #:FF6400000
Fraction by Wt: 0.0-8.0%
OSHA PEL:5000 PPM
ACGIH TLV:5000 PPM; 30000 STEL
Name:VOLATILE ORGANIC COMPOUND: 606 G/L; 5.060 LBS/GAL
RTECS #:9999999VO
OSHA PEL:N/K
ACGIH TLV:N/K
Name:SUPDAT:AGGRAVATE PRE-EXISTING DISORDERS OF THESE ORGANS IN
HUMANS:LIVER ABNORMS, SPLEEN DMG, NERVS SYS DMG, EYE (ING 6)
RTECS #:9999999ZZ
Name:ING 5: DMG, KIDNEY DMG, LUNG DMG, BRAIN DMG.
RTECS #:9999999ZZ
Name:FIRST AID PROC: VOMIT BY GIVING SYRUP OF IPECAC/BY GENTLY
PLACING 2 FINGERS AT BACK OF THROAT. IF POSS, DO NOT (ING 8)
RTECS #:9999999ZZ
Name:ING 7:LEAVE UNATTENDED. INHAL:IF SYMPS DEVELOP, IMMED MOVE
AWAY FROM EXPOS & INTO FRESH AIR. SEEK IMMED MED ATTN;(ING 9)
RTECS #:9999999ZZ
Name:ING 8: KEEP WARM & QUIET. IF NOT BRTHG, BEGIN ARTF RESP. IF
BRTHG IS DFCLT, ADMIN OXYGEN. NOTE TO MD:PROD CNTNS (ING 10)
RTECS #:9999999ZZ
Name:ING 9: METHANOL WHICH CAN CAUSE INTOXICATION & CNS DEPRESS.
METHANOL METABOLIZES TO FORMIC ACID & FORMALDEHYDE. (ING 11)
RTECS #:9999999ZZ
Name:ING 10:THESE METABOLITES CAN CAUSE METABOLIC ACIDOSIS,
VISUAL DISTURBS & BLINDNESS. SINCE METABOLISM IS REQD FOR(ING 12)
RTECS #:9999999ZZ
Name:ING 11:THESE TOX SYMPS, THEIR ONSET MAY BE DELAYED FROM
6-30 HRS FOLLOWING INGEST. ETHANOL COMPETES FOR THE SAME(ING 13)
RTECS #:9999999ZZ
Name:ING 12:METABOLIC PATHWAY & HAS BEEN USED TO PVNT METHANOL
METABOLISM. ETHANOL ADMIN IS INDICATED IN SYMPTOMATIC (ING 14)
RTECS #:9999999ZZ
Name:ING 13:PATIENTS/AT BLOOD METHANOL CONCS ABOVE 20 UG/DL.
METHANOL IS EFTIVELY REMOVED BY HEMODIALYSIS. PROD CNTNS(ING 15)
RTECS #:9999999ZZ
Name:ING 14:ETHYLENE GLYCOL. ETHANOL DECRS METABOLISM OF
ETHYLENE GLYCOL TO TOX METABOLITES. ETHANOL SHOULD BE ADMIN (ING
16)
RTECS #:9999999ZZ
Name:ING 15: AS SOON AS POSS IN CASES OF SEV POISONING SINCE
ELIM HALF-LIFE OF ETHYLENE GLYCOL IS 3 HRS. IF MED CARE (ING 17)
RTECS #:9999999ZZ
Name:ING 16: WILL BE DELAYED SEVERAL HRS, USE THREE TO FOUR 1-OZ
ORAL "SHOTS" OF 86-PROOF OR HIGHER WHISKEY (ING 18)
RTECS #:9999999ZZ
Name:ING 17: BEFORE/DURING TRANSPORT TO HOSPITAL. HEMODIALYSIS
EFTIVELY REMOVES ETHYLENE GLYCOL & ITS METABOLITES FROM BODY.
RTECS #:9999999ZZ
Name:SPILL PROC: BEEN COMPLETED. STOP SPILL AT SOURCE. PVNT FROM
ENTERING DRAINS, SEWERS, STREAMS/OTHER BODIES OF (ING 20)
RTECS #:9999999ZZ
Name:ING 19:WATER. PVNT FROM SPREADING. IF RUNOFF OCCURS, NOTIFY
AUTHS AS REQD. PUMP/VACUUM TRANSFER SPILLED PROD TO (ING 21)
RTECS #:9999999ZZ
Name:ING 20: CLEAN CNTNRS FOR RECOVERY. ABSORB UNRECOVERABLE
PROD. TRANSFER CONTAMD ABSORB, SOIL & OTHER MATLS TO (ING 22)
RTECS #:9999999ZZ
Name:ING 21:CNTNRS FOR DISP. PVNT RUN-OFF TO SEWERS,
STREAMS/OTHER BODIES OF WATER. IF RUN-OFF OCCURS, NOTIFY PROPER(ING
23)
RTECS #:9999999ZZ
Name:ING 22: AUTHS AS REQD, THAT SPILL HAS OCCURED.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYE:EXPOS CAUSES IRRIT. SYMPS MAY INCL
STINGING, TEARING, REDNESS & SWELL. SKIN:EXPOS MAY CAUSE MILD
IRRIT. PRLNGD/RPTD EXPOS MAY DRY SKIN. SYMPS MAY INCL REDNESS,
BURNING, DRYING & CRACKING & SKIN BU RNS. INGEST:SINGLE DOSE ORAL
TOX IS MOD. SWALLOWING MAY BE HARMFUL. INHAL:EXPOS TO VAP/MIST IS
POSS. (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:SHORT-TERM INHAL TOX IS LOW. BRTHG SM
AMTS DURING NORM HNDLG IS NOT LIKELY TO CAUSE HARMFUL EFTS; BRTHG
LG AMTS MAY BE HARMFUL. SYMPS OF EXPOS: GI IRRIT (NAUS, VOMIT,
DIARR), IRRIT (NOSE, THR OAT, RESP TRACT), CNS DEPRESS (DIZZ, DROW,
WEAK, FATG, NAUS, HDCH, UNCON), VISUAL IMPAIRMENT (INCL BLINDNESS)
& (SUPDAT)
Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN DISORDERS AND
LUNG DISORDERS, EG ASTHMA-LIKE CONDITIONS, MAY BE AGGRAVATED BY
EXPOSURE TO THIS MATERIAL.
======================= First Aid Measures =======================
Eyes:IMMED MOVE AWAY FROM EXPOS & INTO FRESH AIR. FLUSH
GENTLY W/WATER FOR AT LEAST 15 MIN WHILE HOLDING LIDS APART; SEEK
IMMED MED ATTN. SKIN:REMOVE CONTAMD CLTHG. WASH EXPOSED AREA W/SOAP
& WATER. I F SYMPS PERSIST, SEEK MED ATTN. LAUNDERCLTHG BEFORE
REUSE. INGEST:SEEK MED ATTN. IF DROWSY/UNCON, DO NOT GIVE ANYTHING
BY MOUTH; PLACE ON LEFT SIDE W/HEAD DOWN. IF CONSCIOUS & ALERT,
INDUCE (ING 7)
===================== Fire Fighting Measures =====================
Lower Limits:3.2%
Extinguishing Media:ALCOHOL FOAM, WATER FOG.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT . REFER TO PERSONAL PROTECTIVE EQUIPMENT SECTION OF MSDS.
Unusual Fire/Explosion Hazard:VAPS ARE HVR/AIR & MAY TRAVEL ALONG
GROUND/BE MOVED BY VENT & IGNITED BY HEAT, PILOT LIGHTS, OTHER
FLAMES & IGNIT SOURCES AT LOCATIONS DIST FROM MATL (SUPDAT)
================== Accidental Release Measures ==================
Spill Release Procedures:SM SPILL:ABSORB LIQ ON VERMICULITE, FLOOR
ABSORB/OTHER ABSORB MATL & TRANSFER TO HOOD. LG SPILL:ELIM ALL
IGNIT SOURCES (FLARES, FLAMES INCL PILOT LIGHTS, ELEC SPKS). PERS
NOT WEARING PROT EQUIP SHOULD BE EXCLUDED FROM AREA UNTIL CLEAN-UP
HAS (ING 19)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:CNTNRS OF MATL MAY BE HAZ WHEN
EMPTIED. SINCE EMPTIED CNTNRS RETAIN PROD RESIDUES (VAP, LIQ &/OR
SOLID), ALL HAZ PRECS GIVEN IN MSDS MUST BE OBSERVED.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NOT REQUIRED UNDER NORMAL CONDITIONS OF USE. USE
NIOSH APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN .
Ventilation:NOT REQUIRED UNDER NORMAL CONDITIONS OF USE.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EXPLO HAZ: HNDLG POINT. NEVER USE WELDING/CUTTING TORCH ON/NEAR DRUM
(EVEN EMPTY) BECAUSE PROD (EVEN JUST RESIDUE) CAN IGNITE EXPLO.
COMBUST MAY FORM CARBON DIOXIDE & CARBON MONOXIDE. EFTS OF OVEREXP:
DEATH. OVEREXP TO MATL (OR ITS COMPONENTS) HAS BEEN SUGGESTED AS
CAUSE OF FOLLOWING EFTS IN LAB ANIMALS & MAY (ING 5)
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:147F,64C
Vapor Pres:97.68 @68F
Vapor Density:>1
Spec Gravity:0.875-0.895
VOC Pounds/Gallon:606
Evaporation Rate & Reference:FASTER THAN ETHYL ETHER
Appearance and Odor:COLORLESS, CLEAR LIQUID AEROSOL.
Percent Volatiles by Volume:85-100
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:MAY FORM CARBON DIOXIDE AND CARBON
MONOXIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DESTROY BY LIQUID INCINERATION. DISPOSE OF IN
ACCORDANCE WITH ALL APPLICABLE LOCAL, STATE AND FEDERAL
REGULATIONS.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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