===================== Product Identification =====================
MSDS NAME:HUMISEAL 1B31
NIIN:01-123-1773
MSDS Number: CCVSZ
=== Responsible Party ===
Company:HUMISEAL DIVISION, COLUMBIA CHASE CORP.
Address:26-60 BROOKLYN QUEENS EXPRESSWAY WEST
Box:445
City:WOODSIDE
State:NY
ZIP:11377-0445
Country:US
Info Phone Num:718-932-0800
Emergency Phone Num:718-932-0800
Preparer's Name:JIM LAWRENCE
Chemtrec Ind/Phone:(800)424-9300
CAGE:0SR97
=== Contractor Identification ===
Company:ARGENT INDUSTRIES INC
Address:477 E WENGER ROAD
Box:City:ENGLEWOOD
State:OH
ZIP:45322
Country:US
Phone:937-836-8633
Contract Num:SP0430-00-M-H812
CAGE:25579
Company:ARGENT INDUSTRIES INC
Address:477 E WENGER ROAD
Box:City:ENGLEWOOD
State:OH
ZIP:45322
Country:US
Phone:937-836-8633
Contract Num:SP0430-99-M-Y159
CAGE:25579
Company:HUMISEAL DIVISION, COLUMBIA CHASE CORP.
Address:26-60 BROOKLYN QUEENS EXPRESSWAY WEST
Box:445
City:WOODSIDE
State:NY
ZIP:11377-0445
Country:US
Phone:718-932-0800
CAGE:0SR97
============= Composition/Information on Ingredients =============
Name:TOLUENE (SARA 313) (CERCLA)
CAS:108-88-3
RTECS #:XS5250000
Minumum % Wt:47.
Maxumum % Wt:53.
Other REC Limits:NONE RECOMMENDED
OSHA PEL:200 PPM; Z-2
ACGIH TLV:S, 50 PPM; 9596
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:METHYL ETHYL KETONE (2-BUTANONE) (MEK) (SARA 313) (CERCLA)
CAS:78-93-3
RTECS #:EL6475000
Minumum % Wt:13.
Maxumum % Wt:18.
Other REC Limits:NONE RECOMMENDED
OSHA PEL:200 PPM
ACGIH TLV:200 PPM/300STEL;9596
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:ACRYLIC POLYMER
Minumum % Wt:32.
Maxumum % Wt:38.
Other REC Limits:NONE RECOMMENDED
Name:OPTICAL BRIGHTENER
< Wt:1.
Other REC Limits:NONE RECOMMENDED
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50 RAT: 5 G/KG, LDLO HUMAN: 50 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYES: SHORT TERM-IRRITATION &
CONJUNCTIVITIS. PROLONGED CONTACT-CORNEAL BURNS. CONCENTRATION >
1000 PPM IRRITATE EYES. SKIN: PROLONGED/REPEATED CONTACT CAUSES
DEFATTING/DRYING CAUSING SKIN IRRITATION & DERMATITIS. SKIN
ABSORPTION ADDS SIGNIFICANTLY TO EXPOSURE. INHALATION: CNS
DEPRESSION. MILD EXPOSURE CAUSES DIZZINESS, WEAKNESS, HEADACHE,
NAUSEA. ETC. EXPOSURES > 1000 PPM MAY CAUSE RESPIRATOR DEP RESSION,
CONVULSIONS, & DEATH. CARDIAC ARRHYTHMIAS, INCLUDING VENTRICULAR
FIBRILLATION, MAY OCCUR. SENSE OF SMELL DULLED BY CONSTANT
EXPOSURE. INGESTION: MODERATELY TOXIC. CAUSES BURNING SENSATION IN
MOUTH & STOMACH.
Explanation of Carcinogenicity:NO INGREDIENT OF A CONCENTRATION OF 0.1%
OR GREATER IS LISTED AS A CARCINOGEN OR SUSPECTED CARCINOGEN.
Effects of Overexposure:SEE HEALTH EFFECTS SECTION. FOR INGESTION, A
MORE SERIOUS HAZARD IS POSED BY VOMITING AFTER SWELLING RESULTING
IN ASPIRATION (BREATHING) OF VOMITUS INTO LUNGS, WHICH MAY RESULT
IN CHEMICAL PNEUMONITIS AND PULMONARY EDEMA/HEMORRAGE, AND MAY BE
FATAL.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
Eyes: FLUSH WITH WATER FOR 15 MINUTES WHILE HOLDING EYELIDS
OPEN. GET MEDICAL ATTENTION. SKIN: FLUSH WITH WATER WHILE REMOVING
CONTAMINATED CLOTHING & SHOES FOLLOWED BY WASHING WITH SOAP &
WATER. CLEA N CLOTHES BEFORE REUSE. INHALATION: MOVE TO FRESH AIR &
GIVE OXYGEN IF BREATHING IS DIFFICULT. GIVE ARTIFICIAL RESPIRATION
IF NOT BREATHING. GET MEDICAL ATTENTION. INGESTION: DO NOT INDUCE
VOMITING. I F VOMITING OCCURS, KEEP HEAD BELOW HIPS TO PREVENT
ASPIRATION OF LIQUID INTO LUNGS. GET MEDICAL ATTENTION. SEE
SUPPLEMENTAL DATA FO0R PHYSICIAN NOTE.
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:=-1.1C, 30.F
Lower Limits:1.6
Upper Limits:11.2
Extinguishing Media:FOAM, CARBON DIOXIDE, DRY CHEMICAL
Fire Fighting Procedures:FIGHT AS A FLAMMABLE LIQUID FIRE. WEAR SELF-
CONTAINED BREATHING APPARATUS.
Unusual Fire/Explosion Hazard:VAPOR IS FLAMMABLE & HEAVIER THAN AIR &
MAY TRAVEL TO SOURCE OF IGNITION & FLASH BACK.
================== Accidental Release Measures ==================
Spill Release Procedures:ABSORB WITH INERT MATERIAL (SAND, VERMICULITE,
ETC.). LARGE SPILLS MAY BE SCOOPED UP WITH NON-SPARKING TOOLS.
REMOVE SOURCES OF IGNITION. PROVIDE VENTILATION AND/OR RESPIRATORY
PROTECTION.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPARKS, OPEN
FLAMES AND INCOMPATIBLE MATERIALS. STORE AT AMBIENT TEMPERATURE.
BOND/GROUND CONTAINERS DURING TRANSFER OPERATIONS.
Other Precautions:KEEP CONTAINER CLOSED. USE ADEQUATE VENTILATION.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF ENGINEERING CONTROLS FAIL OR NON-ROUTINE USE
OR AN EMERGENCY OCCURS; WEAR AN MSHA/NIOSH APPROVED RESPIRATOR WITH
ORGANIC VAPOR CARTRIDGE OR AN AIR-SUPPLIED RESPIRATOR OR SCBA, AS
REQUIRED. USE IAW 29 CFR 1910.134.
Ventilation:USE ADEQUATE EXPLOSION-PROOF MECHANICAL VENTILATION OR
LOCAL EXHAUST TO MAINTAIN EXPOSURE BELOW TLV(S).
Protective Gloves:BUNA-N, SOLVEX, ETC, - IMPERVIOUS
Eye Protection:CHEMICAL SPLASH GOGGLES.
Other Protective Equipment:PREVENT CONTACT TO WORKERS AS REQUIRED.
Work Hygienic Practices:WASH HANDS AFTER HANDLING AND BEFORE EATING,
DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHES BEFORE REUSE.
Supplemental Safety and Health
PHYSICIAN NOTE: IF MORE THAN 2 ML/KG INGESTED & VOMITING HAS NOT
OCCURRED, EMESIS SHOULD BE INDUCED WITH SUPERVISION. KEEP VICTIM
HEAD BELOW HIPS TO PREVENT ASPIRATION. IF SYMPTOMS LIKE LOSS OF GAG
RE FLEX, CONVULSIONS OR UNCONSCIOUS OCCUR BEFORE EMESIS, CONSIDER
GASTRIC LAVAGE USING CUFFED ENDOTRACHEAL TUBE.
================== Physical/Chemical Properties ==================
HCC:F2
Boiling Pt:=82.2C, 180.F
Vapor Pres:45.4
Vapor Density:4.0
Spec Gravity:0.88
VOC Pounds/Gallon:592
Evaporation Rate & Reference:3.62 (N-BUTYL ACETATE=1)
Solubility in Water:NEGLIGIBLE, < 0.1 %
Appearance and Odor:WATER CLEAR, LOW VISCOSITY LIQUID; AROMATIC ODOR.
Percent Volatiles by Volume:62-68
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:NOT APPLICABLE.
Hazardous Decomposition Products:CARBON MONOXIDE AND CARBON DIOXIDE.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
=================== Toxicological Information ===================
Toxicological Information:INH-RAT LCLO: 4000 PPM/4 HRS
===================== Ecological Information =====================
Ecological:NOT PROVIDED
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND
FEDERAL ENVIRONMENTAL REGULATIONS. CONTACT THE APPROPRIATE
ENVIRONMENTAL AGENCIES. RCRA WASTE NUMBER/RQ: TOLUENE, U220/1000
LBS; MEK, U159/5000 LBS. CERC LA: TOLUENE, 1000 LBS; MEK, 5000 LBS.
=================== MSDS Transport Information ===================
Transport Information:SEE TRANSPORTATION DATA.
===================== Regulatory Information =====================
SARA Title III Information:TOLUENE: 313 CHEMICAL, MEK: 313 CHEMICAL,
Federal Regulatory Information:TOLUENE CERCLA RQ: 1000 LB, RCRA CODE
U220, MEK CERCLA RQ: 5000 LB, RCRA CODE U159
State Regulatory Information:NOT PROVIDED
======================= Other Information =======================
======================================================================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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