===================== Product Identification =====================
MSDS NAME:D2286 DIETHANOLAMINE ACS REAGENT
NIIN:00F054184
MSDS Number: CFGRF
=== Responsible Party ===
Company:SIGMA CHEMICAL COMPANY
Address:3050 SPRUCE ST
Box:14508
City:SAINT LOUIS
State:MO
ZIP:63178-5000
Country:US
Info Phone Num:314-771-5765/800-325-3010
Emergency Phone Num:314-771-5765/800-325-3010
CAGE:21076
=== Contractor Identification ===
Company:SIGMA CHEMICAL COMPANY
Address:3050 SPRUCE ST
Box:14508
City:ST LOUIS
State:MO
ZIP:63178
Country:US
Phone:314-771-5765
CAGE:21076
============= Composition/Information on Ingredients =============
Name:DIETHANOLAMINE, DIETHYLOLAMINE, DIOLAMINE,
2,2'-IMINODIETHANOL *97-2*
CAS:111-42-2
RTECS #:KL2975000
Other REC Limits:3 PPM
ACGIH TLV:13 MG/CUM
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL LD50(RAT): 620 UL/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:HARMFUL IF INGESTED, INHALED/ABSORBED
THROUGH SKIN. INHALATION: EXTREMELY DESTRUCTIVE TO TISSUE OF THE
MUCOUS MEMBRANES & UPPER RESPIRATORY TRACT & MAY RESULT IN EDEMA OF
THE LARYNX & BRONCHI, CHEMICA L PNEUMONITIS & PULMONARY EDEMA.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:SPASM, INFLAMMATION, BURNING SENSATION,
COUGHING, WHEEZING, LARYNGITIS, SHORTNESS OF BREATH, HEADACHE,
NAUSEA, VOMITING.
======================= First Aid Measures =======================
First Aid:EYES/SKIN: FLUSH W/COPIOUS AMOUNTS OF WATER FOR 15 MINS.
INHALATION: REMOVE TO FRESH AIR. GIVE CPR/OXYGEN IF NEEDED.
INGESTION: WASH OUT MOUTH W/WATER IF CONSCIOUS. OBTAIN MEDICAL
ATTENTION IN ALL CAS ES.
===================== Fire Fighting Measures =====================
Flash Point:280F
Extinguishing Media:CO2, DRY CHEMICAL POWDER/APPROPRIATE FOAM.
Fire Fighting Procedures:WEAR SCBA & PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS.
================== Accidental Release Measures ==================
Spill Release Procedures:EVACUATE AREA. SHUT OFF SOURCES OF IGNITION.
WEAR SCBA, RUBBER BOOTS & HEAVY RUBBER GLOVES. ABSORB ON
SAND/VERMICULITE & PLACE IN CLOSED CONTAINERS FOR DISPOSAL.
VENTILATE AREA & WASH SITE AFTER MATER IAL PICKUP IS COMPLETE.
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE IN A COOL DRY PLACE. KEEP
TIGHTLY CLOSED.
Other Precautions:AVOID PROLONGED/REPEATED EXPOSURE. DON'T GET IN EYES,
SKIN/CLOTHING. DON'T BREATHE VAPOR.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WEAR APPROPRIATE NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation:CHEMICAL FUME HOOD
Protective Gloves:CHEMICAL RESISTANT
Eye Protection:SAFETY GOGGLES
Other Protective Equipment:PROTECTIVE CLOTHING, SAFETY SHOWER & EYE
BATH.
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE. WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:422.6F
Melt/Freeze Pt:M.P/F.P Text:80.6-87.8F
Spec Gravity:1.097
Appearance and Odor:COLORLESS LIQUID W/WHITE SOLID
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
OXIDIZING AGENTS, COPPER, COPPER ALLOYS, ZINC, GALVANIZED IRON, ACID.
Stability Condition to Avoid:AIR
Hazardous Decomposition Products:THERMAL COMBUSTION: CO, CO2 & NITROGEN
OXIDES.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISSLOVE/MIX W/A COMBUSTIBLE SOLVENT & BURN IN A
CHEMICAL INCINERATOR EQUIPPED W/AN AFTERBURNER & SCRUBBER,
IAW/FEDERAL, STATE & LOCAL REGULATIONS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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