===================== Product Identification =====================
MSDS NAME:TETRAETHYLENEPENTAMINE UHP
NIIN:00-412-5242
MSDS Number: CFKYB
=== Responsible Party ===
Company:PFALTZ AND BAUER, INC
Address:172 EAST AURORA ST.
City:WATERBURY
State:CT
ZIP:06708
Country:US
Info Phone Num:203-574-0075
Emergency Phone Num:203-574-0075
Chemtrec Ind/Phone:(800)424-9300
CAGE:93272
=== Contractor Identification ===
Company:KAMPI COMPONENTS CO., INC.
Address:210 RT 13
Box:721
City:BRISTOL
State:PA
ZIP:19007-3517
Country:US
Phone:215-736-2000
Contract Num:SP0450-99-M-NJ70
CAGE:7Z016
Company:LINMARR ASSOCIATES INC
Address:4460 N PARK ST
Box:City:LAS VEGAS
State:NV
ZIP:89129-2678
Country:US
Phone:702-655-7800
Contract Num:SP0450-00-M-D485
CAGE:1GX03
Company:PFALTZ AND BAUER,INC.
Address:172-EAST AURORA STREET
City:WATERBURY
State:CT
ZIP:06708
Country:US
Phone:203-574-0075
CAGE:93272
============= Composition/Information on Ingredients =============
Name:TETRAETHYLENEPENTAMINE
CAS:112-57-2
RTECS #:KH8585000
Minumum % Wt:92.
Maxumum % Wt:98.
Other REC Limits:NONE RECOMMENDED
Name:TRIETHYLENE TETRAMINE
CAS:112-24-3
RTECS #:YE6650000
Minumum % Wt:1.
Maxumum % Wt:5.
Other REC Limits:NONE RECOMMENDED
Name:PENTAETHYLENE HEXAMINE
CAS:4067-16-7
RTECS #:RZ2680000
Minumum % Wt:.5
Maxumum % Wt:2.
Other REC Limits:NONE RECOMMENDED
===================== Hazards Identification =====================
LD50 LC50 Mixture:NOT GIVEN
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYES: CAUSES SEVERE IRRITATION,
CHEMICAL BURNS AND SEVERE INJURY OF CORNEA THATCOULD RESULT IN
PERMANENT IMPAIRMENT OF VISION. SKIN: CAUSES LOCAL DISCOMFORT AND
TISSUE DESTRUCTION. INHALATION: VAPOR I S IRRITATING TO NOSE AND
THROAT. HIGH VAPOR CONCENTRATIONS MAY CAUSE LUNG DAMAGE, ASTHMA.
INGESTION: MODERATELY TOXIC. MAY CAUSE BURNS OF MOUTH AND THROAT.
CHRONIC: REPEATED VAPOR EXPOSURE MAY CAUSE INJURY TO THE
RESPIRATORY TRACT.REPEATEDORAL EXPOSUREW MAY CAUSE KIDNEY AND LIVER
CHANGES.
Explanation of Carcinogenicity:THIS COMPOUND CONTAINS NO INGREDIENTS AT
CONCENTRATIONS OF 0.1% OR GREATER THAT ARE CARCINOGENS OR SUSPECT
CARCINOGENS.
Effects of Overexposure:EYES: IRRITATION, PAIN, EXCESS BLINKING AND
TEAR PRODUCTION, CHEMICAL BURNS OF CORNEA , IMPAIMENT OF VISION.
SKIN: LOCAL DISCOMFORT OR PAIN, SEVERE REDNESS AND SWELLING,
TISSUE DESTRUCTION, FISSURES, ULCERATION, BLEEDING. INHALATION:
INJURY TO RESPIRATORY TRACT, IRRITATION, BURNING SENSATION OF NOSE
AND THROAT, COUGHING, WHEEZING, SHORTNESS OF BREATH, NAUSEA,
VOMITING, LUNG DAMAGE, ASTHMA. INGE STION: BURNS OF MOUTH AND
THROAT, ABDOMINAL PAIN, NAUSEA, VOMITING, DIARRHEA, DIZZINESS,
WEAKNESS, THIRST, COLLAPSE, COMA, LUNG INJURY. DIGESTION: BURNS OF
MOUTH AND THROAT, ABDOMINAL PAIN, NAUSEA, D IZZINESS, WEAKNESS,
COMA.
Medical Cond Aggravated by Exposure:PRE-EXISTING DERMATITIS , ASTHMA,
INFLAMMATORY OR FIBROTIC PULMONARY DISEASE AND/OR RESPIRATORY
CONDITIONS MAY BE WORSENED BY EXPOSURE TO THIS MATERIAL.
======================= First Aid Measures =======================
First Aid:INGESTION: IF CONSCIOUS, GIVE 2 GLASSES OF MILK OR WATER. DO
NOT INDUCE VOMITING. OBTAIN MEDICAL ATTENTION. SKIN: REMOVE
CONTAMINATED CLOTHING. FLUSH SKIN WITH WATER FOR 15 MINUTES.
OBTAIN MEDICAL AT TENTION. INHALATION: MOVE TO FRESH AIR. GIVE
ARTIFICIAL RESPIRATION IF NOT BREATHING. IF BREATHING IS DIFFICULT,
GIVE OXYGEN. OBTAIN MEDICAL ATTENTION. EYES: FLUSH WITH WATER FOR
15 MINUTES. DO NOT RE MOVE CONTACTS. GET MEDICAL ATTENTION.
===================== Fire Fighting Measures =====================
Flash Point Method:PMCC
Flash Point:=171.1C, 340.F
Lower Limits:0.8
Upper Limits:4.6
Extinguishing Media:APPLY ALCOHOL-TYPE OR ALL-PURPOSE-TYPE FOAMS,
RECOMMENDED TECHNIQUES FOR LARGE FIRES. CARBON DIOXIDE OR DRY
CHEMICAL MEDIA FOR SMALL FIRES.
Fire Fighting Procedures:DO NOT DIRECT SOLID STREAM OF WATER OR FOAM
INTO MOLTEN MATERIAL; THIS MAY CAUSE SPATTERING AND SPREAD THE
FIRE. USE SELF-CONTAINED BREATHING APPARATUS, EYE PROTECTION AND
PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard:DURING FIRE, OXIDES OF NITROGEN WILL BE
EVOLVED.
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR SUITABLE PROTECTIVE EQUIPMENT. AVOID
CONTACT WITH LIQUID & VAPOR. COLLECT FOR DISPOSAL. AVOID DISCHARGE
TO SEWERS OR WATERWAYS. THIS PRODUCT IS RESISTANT TO BIODEGRADATION
IN A BIOLOGICAL WASTEWA TER TREATMENT PLANT. COULD BE TOXIC TO
BIOMASS AND FISH..
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:DANGER! MAY CAUSE ASTHMA WITH POSSIBLE
LONG-TERM LUNG DAMAGE. CAUSES EYE AND SKIN BURNS. HARMFUL AND
CORROSIVE IF SWALLOWED. HARMFUL IF INHALED OR ABSORBED THROUGH THE
SKIN. MAY CAUSE ALLERGIC SKIN RE ACTION AND RESPIRATORY SYSTEM
DAMAGE.
Other Precautions:FOR INDUSTRY USE ONLY. DO NOT BREATHE VAPOR. DO NOT
GET IN EYES, ON SKIN, ON CLOTHING. DO NOT SWALLOW. KEEP CONTAINER
CLOSED. USE WTIH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER
HANDLING. DO NOT ADD NITRATES OR OTHER NITROSATING AGENTS. A
NITCROSAMINE , WHICH AYY CAUSE CANCER , MAY BE FORMED.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:POSITIVE PRESSURE SUPPLIED AIR RESPIRATOR
EQUIPPED WITH FULL FACEPIECE SHOULD BE USED DURING ANY OPERATION
WHERE THERE IS POTENTIAL FOR RELEASE OF PRODUCT TO WORKPLACE AIR.
Ventilation:GENERAL (MECHANICAL) ROOM VENTILATION IS EXPECTED TO BE
SATISFACTORY.LOCAL VENTILATION IS NEEDED AT POINTS WHERE VAPORS CAN
BE EXPECTED TO ESCAPE IN WORKPLACE.
Protective Gloves:BUTYL OR NEOPRENE GLOVES.
Eye Protection:MONOGOGGLES.
Other Protective Equipment:EYEBATH, SAFETY SHOWER, CHEMICAL APRON.
Work Hygienic Practices:WASH HANDS THOROUGHLY WITH SOAP AND WATER
BEFORE EATING, DRINKING, SMOKING OR USING TOILET FACILITIES.
LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
SUDDEN RELEASES OF HOT ORGANIC CHEMICAL VAPORS OR MISTS FROM PROCESS
EQUIPMENT OPERATING AT ELEVATED TEMPERATURES AND PRESSURES, OR
SUDDEN INGRESS OF AIR INTO VACUUM EQUIPMENT MAY RESULT IN IGNITION
W ITHOUT THE PRESENCE OF OBVIOUS IGNITION SOURCES.
================== Physical/Chemical Properties ==================
HCC:C2
Boiling Pt:=340.C, 644.F
B.P. Text:DECOMPOSES
Melt/Freeze Pt:=-37.C, -34.6F
Decomp Temp:=340.C, 644.F
Vapor Pres:<0.01 @20C
Vapor Density:6.5
Spec Gravity:0.994
Evaporation Rate & Reference:<0.01 (N-BUTYL ACETATE=1)
Solubility in Water:COMPLETE 100%
Appearance and Odor:PALE YELLOW LIQUID; AMINE ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NITRITES, ACIDS, OXIDIZING AGENTS, ALDEHYDES, KETONES, EPOXIDES,
ACRYLATES, ORGANIC HALIDES.
Stability Condition to Avoid:SOME DECOMPOSITION CAN OCCUR UPON VIGOROUS
HEATING: E.G. APPLICATION OF HIGH-PRESSURE STEAM, FLAME. DO NOT MIX
WITH NITRITES OR NITROSATING AGENTS BECAUSE NTIROSAMINE MAY BE
FORMED
Hazardous Decomposition Products:BURNING: CO, CO2, NITROGEN OXIDES.
VIGOROUS HEATING THERMAL DECOMPOSITION CAN PRODUCE ETHYLENEDIAMINE,
DIETHYLENETRIAMINE, VOLATILE AMINES, AMMONIA.
==================== Disposal Considerations ====================
Waste Disposal Methods:INCINERATE IN A FURNACE WHERE PERMITTED UNDER
FEDERAL FEDERAL, STATE AND LOCAL REGULATIONS.
===================== Regulatory Information =====================
SARA Title III Information:NO COMPONENTSPRESENT IN THIS PRODUCT AT A
LEVEL WHICH COULD REQUIRE REPORTING UNDER SARA 301,311,312.
SUPERFUND AMENDMENTS AND REACTHORIZATION ACT OF 1986, SARA, TITLE
III REQUIRESSUBMISSION OF ANNUA L REPORTS OF RELEASES OF TOXIC
CHEMICALS THAT APPERR IN 40 CFR 372 (FOR SARA 313). THIS
INFORMATION MUST INCLUDE IN ALL MSDS'S THAT ARE COPIED AND
DISTRIBUTED FOR THIS MATERIAL.
Federal Regulatory Information:COMPREHENHENSIVE ENVIRONMENTAL RESPONSE
COMPENSATION AND LIABILITY ACT (CERCLA) REQUIRES NOTIFICATION OF
THE NATIONAL RESPONSE CENTER OF RELEASESOF QUANTITIES OF HAZARDOUS
SUBSTANCES EQUAL TO OR GREAT ER THAN THE REPORTABLE QUANTITIES (RQ)
IN 40 CFR 302.4. NO COMPONENT PRESENT IN THIS PRODUCT AT A LEVEL
WHICH COULD REQUIRE REPORTING UNDER THE STATUTE. COMPONENTS PRESENT
IN THIS PRODUCT AT A LEVEL W HICH COULD REQUIRE REPORTING UNDER
THIS STATUTE ARE: NONE. TSCA INVENTORY STATUS: ALL COMPONENTS OF
THIS PRODUCT ARE ON THE TSCA INVENTORY OR ARE EXEMPT UNDER 40 CFR
720.30
State Regulatory Information:CALIFORNIA PROPOSITION 65: THIS PRODUCT
CONTAINS NO LISTED SUBSTANCES KNOWN TO THE STATE OF CALIFORNIA TO
CAUSE CANCER. BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM AT LEVELS
WHICH WOULD REQUIRE Q WARNING UNDER THE STATUTE. MASSACHUSETTS 105
CMR 670.000 RIGHT TO KNOW (MSL) . COMPONENTS PRESENT IN THIS
PRODUCT AT A LEVEL WHICH COULD REQUIRE REPORTING ARE:
TETRAETHYLENEPENTAMINE CAS# 112-57-2, 93% AND
TRIETHYLENETETRAMINE, CAS#112-24-3, 5%. PENNSYLVANIA RIGHT TO KNOW.
COMPONENTS IN THIS PRODUCTWHICH COULD REQUIRE REPORTING ARE:
TETRAETHYLENEPENTAMINE, CAS 112-57-2, 93%
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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