===================== Product Identification =====================
MSDS NAME:VALIANT (PHD & PHD-XT PHD-EXT)
NIIN:00F002798
MSDS Number: BBLSS
=== Responsible Party ===
Company:CAULK/DENTSPLY
Address:LAKEVIEW & CLARKE AVENUES
City:MILFORD
State:DE
ZIP:19963-0359
Info Phone Num:(302) 422-4511
Emergency Phone Num:(302) 422-4511
CAGE:56820
=== Contractor Identification ===
Company:CAULK/DENTSPLY
Address:LAKEVIEW & CLARKE AVENUES
Box:City:MILFORD
State:DE
ZIP:19963-0359
Phone:(302) 422-4511
CAGE:56820
============= Composition/Information on Ingredients =============
Name:TIN
CAS:7440-31-5
RTECS #:XP7320000
Fraction by Wt: 29.7%
OSHA PEL:2 MG/M3
ACGIH TLV:2 MG/M3; 9192
Name:PALLADIUM
Fraction by Wt: 0.3%
OSHA PEL:15 MG/CUM
ACGIH TLV:10 MG/CUM
Name:SILVER (SARA III)
CAS:7440-22-4
RTECS #:VW3500000
Fraction by Wt: 52.5%
OSHA PEL:0.01 MG/M3
ACGIH TLV:0.1 MG/M3; 9192
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Name:COPPER (SARA III)
CAS:7440-50-8
RTECS #:GL5325000
Fraction by Wt: 17.5%
Other REC Limits:1 MG(CU)/M3 (DUST)
OSHA PEL:0.1MG/M3 FUME/1 DUST
ACGIH TLV:0.2MG/M3 FUME; 9192
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:SKIN: PROLONGED OR REPEATED CONTACT
MAY CAUSE IRRITATION OR ALLERGIC REACTION. INHALATION: PROLONGED
EXCESSIVE EXPOSURE TO DUST, MIST, OR FUMES MAY CONTRIBUTE TO
CHRONIC RESPIRATORY AILMENTS.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:SKIN: PROLONGED OR REPEATED CONTACT MAY CAUSE
IRRITATION OR ALLERGIC REACTION. INHALATION: PROLONGED EXCESSIVE
EXPOSURE TO DUST, MIST, OR FUMES MAY CONTRIBUTE TO CHRONIC
RESPIRATORY AILMENTS.
Medical Cond Aggravated by Exposure:ALLERGIC REACTION
======================= First Aid Measures =======================
Eyes: FLUSH W/WATER. OBTAIN MEDICAL ATTENTION.
===================== Fire Fighting Measures =====================
Extinguishing Media:USE DRY POWDER EXTINGUISHING AGENT.
Fire Fighting Procedures:FIRE FIGHTERS SHOULD WEAR FULL PROTECTIVE
CLOTHING INCLUDING SELF-CONTAINED BREATHING APPARATUS.
Unusual Fire/Explosion Hazard:METAL POWDER IN AIR MAY CAUSE FIRE &
EXPLOSION HAZARD. EXPLOSION HAZARD, GOOD HOUSEKEEPING MUST BE
MAINTAINED. MOLTEN METAL CAN IGNITE COMBUSTIBLES.
================== Accidental Release Measures ==================
Spill Release Procedures:PICK UP POWDER SPILLS BY METHODS SUCH AS
VACUUMING OR WET MOPPING-PREVENT DUSTY CONDITIONS.
====================== Handling and Storage ======================
Handling and Storage Precautions:FOLLOW GOOD HOUSEKEEPING PRACTICES &
GOOD INDUSTRIAL HYGIENE IN HANDLING THIS MATERIAL.
Other Precautions:OPERATIONS GENERATING AIRBORNE EXPOSURE SUCH AS
WELDING, MELTING, GRINDING, ETC. SHOULD BE PERFORMED W/VENTILATION.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH APPROVED RESPIRATORS ARE REQUIRED WHEN
CONCENTRATIONS OF DUST & FUMES EXCEED TLV.
Ventilation:LOCAL EXHAUST
Protective Gloves:LEATHER OR RUBBER
Eye Protection:SAFETY GOGGLES
Other Protective Equipment:RUBBER APRON
Work Hygienic Practices:OBSERVE NORMAL CARE WHEN WORKING W/CHEMICALS.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Spec Gravity:9.60
Solubility in Water:NOT SOLUBLE
Appearance and Odor:METALLIC GRAY POWDER.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
MINERAL ACIDS
Hazardous Decomposition Products:HYDROGEN GAS
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF WASTE IN ACCORDANCE W/LOCAL, STATE,
OR FEDERAL REGULATIONS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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