===================== Product Identification =====================
MSDS NAME:48833, EPA 625 BASE/NEUTRAL 3, 1X1ML (SUPDAT)
NIIN:00N084141
MSDS Number: CGSHK
=== Responsible Party ===
Company:SUPELCO INC
Address:SUPELCO PARK
City:BELLEFONTE
State:PA
ZIP:16823-0048
Country:US
Info Phone Num:814-359-3441
Emergency Phone Num:814-359-3441
CAGE:54968
=== Contractor Identification ===
Company:SIGMA-ALDRICH INC.
Address:3050 SPRUCE STREET
Box:14508
City:ST. LOUIS
State:MO
ZIP:63103
Country:US
Phone:314-771-5765/414-273-3850X5996
CAGE:54968
============= Composition/Information on Ingredients =============
Name:FLUORANTHENE (CERCLA). LD50: (ORAL,RAT) 2000 MG/KG
CAS:206-44-0
RTECS #:LL4025000
Fraction by Wt: 0.02%
OSHA PEL:N/K
ACGIH TLV:N/K
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
Name:AZOBENZENE; (DIAZENE, DIPHENYL-AZOBENZENE, 99%)
CAS:103-33-3
RTECS #:CN1400000
Fraction by Wt: 0.02%
OSHA PEL:N/K
ACGIH TLV:N/K
Name:BENZENE, 1,2,4-TRICHLORO-; (1,2,4- TRICHLOROBENZENE) (SARA
313) (CERCLA). LD50:(ORAL,RAT) 756 MG/KG
CAS:120-82-1
RTECS #:DC2100000
Fraction by Wt: 0.02%
OSHA PEL:C, 5 PPM
ACGIH TLV:C, 5 PPM
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
Name:ETHANE, HEXACHLORO-; (HEXACHLOROETHANE) (SARA 313)
(CERCLA). LD50:(ORAL,RAT) 4460 MG/KG
CAS:67-72-1
RTECS #:KI4025000
Fraction by Wt: 0.02%
OSHA PEL:S, 1 PPM
ACGIH TLV:S, 1 PPM
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
Name:NAPTHALENE, 2-CHLORO-; (2-CHLORONAPHTHALENE) (CERCLA).
LD50:(ORAL,RAT) 2078 MG/KG
CAS:91-58-7
RTECS #:QJ2275000
Fraction by Wt: 0.02%
OSHA PEL:N/K
ACGIH TLV:N/K
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:1,3-CYCLOPENTADIENE, 1,2,3,4,5,5-HEXACHLORO-;
(HEXACHLOROCYCLOPENTADIENE) (SARA 302/313). LD50: (ORAL,RAT) 113
MG/KG
CAS:77-47-4
RTECS #:GY1225000
Fraction by Wt: 0.02%
OSHA PEL:0.01 PPM
ACGIH TLV:0.01 PPM
EPA Rpt Qty:10 LBS
DOT Rpt Qty:10 LBS
Name:2-CYCLOHEXEN-1-ONE,3,5,5-TRIMETHYL; (ISOPHORONE) (CERCLA).
LD50: (ORAL,RAT) 2330 MG/KG
CAS:78-59-1
RTECS #:GW7700000
Fraction by Wt: 0.02%
OSHA PEL:25 PPM
ACGIH TLV:C 5 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:DIPHENYLAMINE, N-NITROSO-; (NITROSODIPHENYLAMINE) (SARA
313) (CERCLA). LD50: (ORAL,RAT) 2170 MG/KG
CAS:86-30-6
RTECS #:JJ9800000
Fraction by Wt: 0.02%
OSHA PEL:N/K
ACGIH TLV:N/K
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
Name:DIPROPYLAMINE, N-NITROSO-; (N-NITROSODI-N-PROPYLAMINE)
(SARA 313) (CERCLA). LD50: (ORAL,RAT) 480 MG/KG
CAS:621-64-7
RTECS #:JL9700000
Fraction by Wt: 0.02%
OSHA PEL:N/K
ACGIH TLV:N/K
EPA Rpt Qty:10 LBS
DOT Rpt Qty:10 LBS
Name:PHTHALIC ACID, BENZYL BUTYL ESTER; (BUTYL BENZYL PHTHALATE)
(SARA 313) (CERCLA). LD50: (ORAL,RAT) 2330 MG/KG
CAS:85-68-7
RTECS #:TH9990000
Fraction by Wt: 0.02%
OSHA PEL:N/K
ACGIH TLV:N/K
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
Name:PHENANTHRENE (CERCLA). LD50:(ORAL,RAT) 700 MG/KG
CAS:85-01-8
RTECS #:SF7175000
Fraction by Wt: 0.02%
OSHA PEL:N/K
ACGIH TLV:N/K
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:METHANE, DICHLORO-; (METHYLENE CHLORIDE) (SARA 313)
(CERCLA). LD50: (ORAL,RAT) 2524 MG/KG
CAS:75-09-2
RTECS #:PA8050000
Fraction by Wt: 99.8%
OSHA PEL:500 PPM; Z-2
ACGIH TLV:50 PPM, A2
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:SUPDAT: METHYLENE CHLORIDE CONCS AS HIGH AS 10,000 PPM
SHOWED SLIGHT LIVER & KIDNEY CHANGES. METHYLENE CHLORIDE (ING 18)
RTECS #:9999999ZZ
Name:ING 17: HAS BEEN SHOWN TO INCR RATE OF SPONTANEOUSLY
OCCURING MALIGNANT TUMORS IN 1 STRAIN OF LAB MICE & BENIGN (ING 19)
RTECS #:9999999ZZ
Name:ING 18: TUMORS IN LAB RATS. OTHER ANIMAL STUDIES, AS WELL
AS SEVERAL HUMAN EPIDEMIOLOGY STUDIES, HAVE INDICATED(ING 20)
RTECS #:9999999ZZ
Name:ING 19: NEGATIVE RESPONSE. METHYLENE CHLORIDE IS NOT
BELIEVED TO POSE CARCIN RISK OT MAN WHEN HNDLD AS REC. (ING 21)
RTECS #:9999999ZZ
Name:ING 20: CH*2CL*2 IS METABOLIZED TO CO & CAN STRESS
CARDIOVASCULAR SYS DUE TO INCR CARBOXYHEMOGLOBIN. IN RATS (ING 22)
RTECS #:9999999ZZ
Name:ING 21: METHYLENE CHLORIDE HAS BEEN SHOWN TO PRDCE
SIGNIFICANT INCREASE IN SALIVARY GLAND TUMORS.
RTECS #:9999999ZZ
Name:FIRST AID PROC: PERSON. NEVER TRY TO MAKE AN UNCON PERSON
VOMIT. DO NOT INDUCE VOMIT. IMMED CONT PHYSICIAN.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:SEE INGREDIENTS
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:CHLOROCARBON MATLS HAVE PRDCED SENSIT
OF MYOCARDIUM TO EPINEPHRINE IN LAB ANIMALS & COULD HAVE A SIMILAR
EFT IN HUMANS. ADRENOMIMETICS (E.G. EPINEPHRINE) MAY BE
CONTRAINDICATED EXCEPT FOR LIFE-SUSTAIN ING USES IN HUMANS
ACUTELY/CHRONICALLY EXPOSED TO CHLOROCARBONS . ACUTE: MAY BE FATAL
IF INHALED.(EFTS OF OVEREXP)
Explanation of Carcinogenicity:METHYLENE CHLORIDE: IARC MONO SUPP, VOL
7, PG 194, 1987: GROUP 2B. NTP 7TH ANNUAL RPT ON CARCINS, 1994:
ANTIC (SUPDAT)
Effects of Overexposure:HLTH HAZ: HARMFUL IF SWALLOWED. CNTNS LOW
CONC(S) OF MATL(S) KNOWN TO STATE OF CALIFORNIA TO CAUSE CANCER.
SUCH CONC(S) IS/ARE SUBSTANTIALLY BELOW OSHA-HCS THRESHOLDS WHICH
WOULD REQ LISTING HEREIN AS COMPONENT OF THIS MIX. LACHRIMATION.
IRRITATES SKIN. DERM. HEADACHE, DIZZ, NARCOSIS, LIVER DMG, KIDNEY
DMG. (SUPDAT)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
Eyes: FLUSH W/WATER FOR @ LST 15 MINS. SKIN: PROMPTLY WASH
W/MILD SOAP & LG VOL OF WATER. REMOVE CONTAMD CLTHG. INHAL: IMMED
MOVE TO FRESH AIR. GIVE OXYG IF BRTHG IS LABORED. IF BRTHG STOPS,
GIVE ARTF RESP. CONT PHYS. NEVER ADMIN ADRENALINFOLLOWING CH*2C*13
EXPOS. INCR SENSITIVITY OF HEART TO ADRENALIN MAY BE CAUSED BY
OVEREXP TO CH*2C*12. INGEST: NEVER GIVE ANYTHING BY MOUTH TO UNCON
(ING 19)
===================== Fire Fighting Measures =====================
Lower Limits:12.0%
Upper Limits:19.0%
Extinguishing Media:WATER, CO*2, DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH APPROVED PRESSURE DEMAND SCBA &
FULL PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:THERMAL DECOMPOSITION PRODUCTS MAY
INCLUDE HCL & PHOSGENE . THE FOLLOWING TOXIC VAPS ARE FORMED WHEN
THIS MATL IS HEATED TO HYDROGEN CHLORIDE, PHOSGENE.
================== Accidental Release Measures ==================
Spill Release Procedures:TAKE UP WITH ABSORBENT MATERIAL. VENTILATE
AREA. METHYLENE CHLORIDE VAPORS ARE HEAVIER THAN AIR AND WILL
COLLECT IN LOW AREAS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:REFRIGERATE IN SEALED CONTAINER.
POSSIBLE CANCER HAZARD. AVOID EYE/SKIN CONTACT. AVOID BREATHING
VAPORS.
Other Precautions:NO SMOKING IN AREA OF USE. DO NOT USE IN GEN VICINITY
OF ARC WELDING, OPEN FLAMES OR HOT SURFACES. HEAT &/OR UV RADIA MAY
CAUSE FORMATION OF HCL &/OR PHOSGENE .
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WEAR NIOSH APPRVD FACE MASK WITH ORGANIC VAPOR
CANISTER. WEAR NIOSH APPRVD RESPIRATORY PROTECTION.
Ventilation:USE ONLY IN WELL VENTILATED AREA.
Protective Gloves:NEOPRENE GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:NOT APPLICABLE.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
MFR TRADE NAME/PART NO: CH2CL2 200UG/ML EACH. CNDTNS TO AVOID
(POLYMER): FLAMES, HOT GLOWING SURF/ELEC ARCS CAN DECOMPOSE TO FORM
HYDROGEN CHLORIDE GAS & TRACES OF PHOSGENE. EXPLAN OF CARCIN: TO BE
CA RCIN. EFTS OF OVEREXP: SEVERAL CHRONIC INHAL STUDIES RPTD BY
NIOSH REVEALED THAT TEST ANIMALS EXPOSED TO (ING 13)
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:104F,40C
Melt/Freeze Pt:M.P/F.P Text:-143F,-97C
Vapor Pres:349 @ 20C
Vapor Density:2.93
Spec Gravity:1.320
Evaporation Rate & Reference:0.71 (ETHER =1)
Solubility in Water:1.6
Appearance and Odor:CLEAR COLORLESS LIQUID. ETHER-LIKE ODOR.
Percent Volatiles by Volume:100
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG BASES, OXIDIZING AGENTS.
Stability Condition to Avoid:NOT APPLICABLE.
Hazardous Decomposition Products:HCL & PHOSGENE . HYDROGEN CHLORIDE.
Conditions to Avoid Polymerization:LIQ OXYG/OTHER STRONG OXIDANTS MAY
FORM EXPLO MIX W/METHYLENE CHLORIDE. THIS MATL/ITS VAPS WHEN IN
CONT WITH (SUPDAT)
==================== Disposal Considerations ====================
Waste Disposal Methods:COMPLY WITH ALL APPLICABLE FEDERAL, STATE, OR
LOCAL REGULATIONS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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