===================== Product Identification =====================
MSDS NAME:CEILCOTE HARDENER 2C, 58270
NIIN:00N086619
MSDS Number: CHFQF
=== Responsible Party ===
Company:MASTER BUILDERS INC
Address:23700 CHAGRIN BLVD
City:CLEVELAND
State:OH
ZIP:44122
Country:US
Info Phone Num:216-831-5500
Emergency Phone Num:800-424-9300(CHEMTREC)
CAGE:FO873
=== Contractor Identification ===
Company:MARTIN MARIETTA CHEM MASTER BUILDERS DIV
Address:23700 CHAGRIN BLVD
Box:City:CLEVELAND
State:OH
ZIP:44122-5506
Country:US
Phone:216-831-5500
CAGE:98898
Company:MASTER BUILDERS DIV MARTIN MARIETTA CORP
Address:23700 CHAGRIN BLVD
City:CLEVELAND
State:OH
ZIP:44122-5506
Phone:(216) 831-5500
CAGE:FO873
============= Composition/Information on Ingredients =============
Name:HYDROPEROXIDE, ALPHA, ALPHA-DIMETHYLBENZYL-; (CUMENE
HYDROPEROXIDE) (SARA 313) (CERCLA)
CAS:80-15-9
RTECS #:MX2450000
Fraction by Wt: 70-85%
OSHA PEL:N/K
ACGIH TLV:N/K
EPA Rpt Qty:10 LBS
DOT Rpt Qty:10 LBS
Name:BENZYL ALCOHOL, ALPHA, ALPHA-DIMETHYL-;
(2-PHENYL-2-PROPANOL)
CAS:617-94-7
RTECS #:DO4562000
Fraction by Wt: 5-15%
OSHA PEL:N/K
ACGIH TLV:N/K
Name:CUMENE (SARA 313) (CERCLA)
CAS:98-82-8
RTECS #:GR8575000
Fraction by Wt: <10%
OSHA PEL:50 PPM, S
ACGIH TLV:50 PPM, S
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:ACETOPHENONE (SARA 313) (CERCLA)
CAS:98-86-2
RTECS #:AM5250000
Fraction by Wt: <2%
OSHA PEL:N/K
ACGIH TLV:10 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:FIRST AID PROC: VOMIT; GIVE LG QTYS OF WATER; GET IMMED MED
ATTN. IF VOMIT OCCURS SPONTANEOUSLY, KEEP HEAD BELOW (ING 6)
RTECS #:9999999ZZ
Name:ING 5: HIPS TO PREVENT ASPIRATION OF LIQS INTO LUNGS. DO
NOT GIVE ANYTHING BY MOUTH TO UNCONSCIOUS PERSON.
RTECS #:9999999ZZ
Name:RESP PROT: IMPORTANT. REFERENCE OSHA REG CFR 29 1910.134
FOR RECOMMENDED RESPIRATORY PROTECTION.
RTECS #:9999999ZZ
Name:EYE PROT: & FULL LENGTH FACESHIELD .
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50: (ORAL, RAT) 800-1600 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHAL: VAPS CAN BE IRRIT TO NOSE, MUC
MEMBS, THROAT & UPPER RESP TRACT. EYES: CONTACT IS EXTREMELY IRRIT
& CORR TO EYE. THIS MATL CAN CAUSE DMG OR BLINDNESS. SKIN CNTCT:
SHORT SINGLE EXPOS MAY CAUSE M OD IRRIT TO MILD BURN. PRLNGD/RPTD
EXPOS MAY CAUSE SEVERE BURN. CUMENE MAY BE ABSORBED THRU SKIN TO
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: INCREASE OVERALL TOXICITY LEVEL.
INGEST: CAN RSLT IN BURNS OF MOUTH, ESOPHAGUS & STOMACH. CHRONIC:
PROD DOES NOT CNTN CARCIN MATLS AS DEFINED BY OSHA HAZ
COMMUNICATIONS ACT 1910.1200. CUMENE & CUMENE HYDROPEROXIDE: LAB
TEST DATA HAS BEEN REPORTED SHOWING THESE CHEMS TO BE MUTAGENIC IN
VITRO.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INHAL: REMOVE VICTIM FROM EXPOS. IF DFCLTY W/BRTHG, ADMIN
OXYGEN. IF BRTHG HAS STOPPED ADMIN ARTF RESP, PREFERABLY
MOUTH-TO-MOUTH. SEEK MED ATTN. EYES: FLUSH EYES W/WATER, LIFTING
UPPER & LOWER LIDS O CCASNLY FOR AT LEAST 15 MIN. SEEK MED ATTN.
SKIN: REMOVE CONTAM CLTHG. WASH THOROUGHLY W/SOAP & WATER. IF IRRIT
PERSISTS SEEK MED ATTN. WASH CONTAM CLTHG BEFORE REUSE. INGEST: DO
NOT INDUCE (ING 5)
===================== Fire Fighting Measures =====================
Flash Point Method:PMCC
Flash Point:162F,72C
Extinguishing Media:CARBON DIOXIDE, FOAM, DRY CHEMICAL AND WATER FOG.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:EVACUATE AREA, FIGHT FIRE FROM SAFE DIST.
AT HIGHER TEMP VAPS CAN CAUSE PRESS BUILD UP IN SEALED CNTNRS. USE
WATER TO COOL CNTNRS EXPOSED TO FIRE. (SUPDAT)
================== Accidental Release Measures ==================
Spill Release Procedures:VENTILATE AREA, ELIMINATE ALL SOURCES OF
IGNITION. WEAR APPROPRIATE PROTECTIVE GEAR, CONTAIN LEAK OR SPILL,
SALVAGE, CLEAN UP W/NON-COMBUSTIBLE, NON-ACIDIC ABSORBENT MATERIAL
LIKE SAND OR SODA ASH. WA SH DOWN AREA WITH DETERGENT AND WATER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE IN COOL, DRY PLACE.
Other Precautions:DO NOT WEAR CONTACT LENSES WHEN WORKING WITH THIS
MATERIAL.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WEAR NIOSH APPRVD RESP PROT WHENEVER AIRBORNE
CONCS EXCEED TLV CEILINGS OR TWA. USE NIOSH APPRVD RESPS EQUIPPED
W/ORG VAP CARTRIDGE FOR LISTED HAZ. CONFINED SPACES, ROOMS OR TANKS
ARE AREAS WHERE CONC ERN FOR TLVS IS ESPECIALLY (ING 7)
Ventilation:VENT REC. AIR MOVEMENT MUST BE DESIGNED TO INSURE TURNOVER
AT ALL LOCATIONS IN WORK AREA TO AVOID BUILD UP OF HVY VAPS.
Protective Gloves:RUBBER/LATEX GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS (ING 8)
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER .
SELECTION OF SPECIFIC ITEMS SUCH AS BOOTS & APRON DEPEND ON
OPERATION.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EXPLO HAZ: ELEC GROUNDING IS NOT RECOMMENDED. CNDTNS TO AVOID: POSSIBLY
LEADING TO PRESS BUILDUP & CNTNR FAILURE/EXPLO. EXCESS HEAT,FUMES &
SMOKE CAN OCCUR IF PROD IS NOT MIXED & USED ACCRD TO DIRECTI ONS.
NOT SENSITIVE TO MECH IMPACT. MATLTO AVOID: RXN. NEVER MIX CUMENE
HYDROPEROXIDE W/COBALT NAPHTHENATE DIRECTLY.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:DECOMPOSES
Melt/Freeze Pt:M.P/F.P Text:-40F,-40C
Vapor Pres:2.0 @ 20C
Vapor Density:> AIR
Spec Gravity:1.05
Solubility in Water:NONE
Appearance and Odor:CLEAR YELLOW LIQUID; SHARP AROMATIC ODOR.
Percent Volatiles by Volume:10
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
OXIDIZING & REDUCING AGENTS, ACIDS, ISOCYANATES, ORG COBALTS, AMINES &
METAL SALTS MAY RSLT IN VIOLENT EXPLO (SUPDAT)
Stability Condition to Avoid:STABLE AT ROOM TEMPS; AVOID TEMPS >140F
&/OR CONTAM. HIGHER TEMPS &/OR CONTAM PROMOTES EXOTHERMIC DECOMP
(SUPDAT)
Hazardous Decomposition Products:CARBON MONOXIDE & DIOXIDE, KETONES,
ALCOHOLS, METHANE, ETHANE, PHENOLS & VARIOUS HYDROCARBONS FROM
INCOMPLETE COMBUST.
==================== Disposal Considerations ====================
Waste Disposal Methods:HANDLE DISP OF WASTE MATL IN MANNER WHICH
COMPLIES W/LOC, STATE, PROVINCE & FED REGS. INCIN AT AGENCY APPRVD
WASTE DISP FACILITIES. EMPTY CNTNRS SHOULD BE THOROUGHLY WASHED
BEFORE DISP. RQ: CASRN 80-1 5-9: 50 LBS; 98-82-8: 500 LBS;
98-86-2:5000 LBS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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