===================== Product Identification =====================
MSDS NAME:25,52631, CEILCOTE 2500 CEILCOTE LIQUID (SUPDAT)
NIIN:00N086694
MSDS Number: CHJKR
=== Responsible Party ===
Company:MASTER BUILDERS INC
Address:23700 CHAGRIN BLVD
City:CLEVELAND
State:OH
ZIP:44122
Country:US
Info Phone Num:216-831-5500
Emergency Phone Num:800-424-9300 (CHEMTREC)
CAGE:FO873
=== Contractor Identification ===
Company:MARTIN MARIETTA CHEM MASTER BUILDERS DIV
Address:23700 CHAGRIN BLVD
Box:City:CLEVELAND
State:OH
ZIP:44122-5506
Country:US
Phone:216-831-5500
CAGE:98898
Company:MASTER BUILDERS DIV MARTIN MARIETTA CORP
Address:23700 CHAGRIN BLVD
City:CLEVELAND
State:OH
ZIP:44122-5506
Phone:(216) 831-5500
CAGE:FO873
============= Composition/Information on Ingredients =============
Name:STYRENE MONOMER; (STYRENE (ST)) (SARA 313). BP: 145C VP: 5
@ 20C. LEL: 1.1%. UEL: 6.1%. LD50 (ORAL, RAT): 5000 MG/KG.
CAS:100-42-5
RTECS #:WL3675000
Fraction by Wt: 40-50%
OSHA PEL:100 PPM
ACGIH TLV:S,50PPM/100STEL;9495
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:TRIMETHYLOLPROPANE DIALLYL ETHER. LD50 (ORAL, RAT): 6500
MG/KG
CAS:682-09-7
RTECS #:TY6667000
Fraction by Wt: <1%
OSHA PEL:100 PPM
ACGIH TLV:S,50PPM/100STEL;9495
Name:SUPDAT: WORKER EXPOS CAUSES TUMORS IN HUMANS. IN 1982, IARC
DETERMD THAT THERE IS "LTD EVID" OF STYRENE (ING 4)
RTECS #:9999999ZZ
Name:ING 3: INDUCING TUMORS IN ANIMALS BASED ON SEVERAL STUDIES.
IN 1987,IARC RECLASSIFIED STYRENE TO GROUP 2B (ING 5)
RTECS #:9999999ZZ
Name:ING 4: "POSSIBLY CARCINOGENIC TO HUMANS." STYRENE IS NOT
CONSIDERED TERATOGENIC, ALTHOUGH A FEW ANIMAL STUDIES (ING 6)
RTECS #:9999999ZZ
Name:ING 5: INDICATED THAT EXPOSURE TO VERY HIGH LEVELS MAY BE A
HAZARD TO DEVELOPING EMBRYOS.
RTECS #:9999999ZZ
Name:FIRST AID PROC: INDUCE VOMIT; GIVE LRG QTIES OF H*2O; GET
IMMED MED ATTN. IF VOMIT OCCURS SPONTANEOUSLY, KEEP (ING 8)
RTECS #:9999999ZZ
Name:ING 7: HEAD BELOW HIPS TO PREVENT ASPIRATION OF LIQS INTO
LUNGS. DO NOT GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
RTECS #:9999999ZZ
Name:OTHER PROT EQUIP: DEPEND ON OPERATION.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:SEE INGREDIENTS.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:INHAL: VAPS CAN BE IRRIT TO NOSE & MUC
MEMBS. HIGH STYRENE EXPOS MAY RSLT IN NARC EFTS, HDCHS & POSS
ASPHY. EYES: CNTCT CAN CAUSE SEV IRRIT, REDNESS, TEARING, BLURRED
VISION. MAY CAUSE CORNEAL INJURY. SKIN CNTCT: PRLNG/RPTD EXPOS CAN
CAUSESKIN IRRIT, REDNESS & EVEN SKIN DMG. SKIN ABSORPTION: NO (EFTS
OF OVEREXP)
Explanation of Carcinogenicity:STYRENE: IARC MONOGRAPHS, SUPPLEMENT,
VOL 7, PG 345, 1987: GROUP 2B ANIMAL: NERV SYS.
Effects of Overexposure:HLTH HAZ: KNOWN INFO AVAIL. INGEST: INTAKE CAN
CAUSE GI IRRIT, NAUS, VOMIT, DIARR, HDCH, & DROW. MAY CAUSE CHEM
PNEUM IF ASPIRATED INTO LUNGS. CHRONIC: MATLS ARE NOT KNOW
MUTAGENIC/REPRO HLTH HAZS. AN IMAL & HUMAN DATA INDICATED THAT
STYRENE MONOMER IS NOT CARCINOGEN. NATIONAL CANCER INSTITUTE
CONCLUDED FROM (SUPDAT)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INHAL: REMOVE VICTIM FROM EXPOS. IF DIFFICULTY W/BRTHG,
ADMINISTER OXYGEN. IF BRTHG HAS STOPPED ADMINISTER ARTF RESP,
PREFERRABLY MOUTH-TO-MOUTH. SEEK MED ATTN. EYES: FLUSH W/H*2O,
LIFTING UPPER & LOW ER LIDS OCCAS FOR 15 MIN. SEEK MED ATTN. SKIN:
REMOVE CONTAMD CLTHG. WASH THOROUGHLY W/SOAP & H*2O. IF IRRIT
PERSISTS SEEK MED ATTN. WASH CONTAMD CLOTHING BEFORE REUSE. INGEST:
DO NOT (ING 7)
===================== Fire Fighting Measures =====================
Flash Point Method:PMCC
Flash Point:82.4F,28.0C
Lower Limits:SEE ING 1
Upper Limits:SEE ING 1
Extinguishing Media:CARBON DIOXIDE, FOAM, DRY CHEMICAL & WATER FOG.
Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP . AT
HIGHER TEMPS VAPS CAN CAUSE PRESS BUILDUP IN SEALED CONTAINER. USE
WATER TO COOL CONTAINERS EXPOSED TO FIRE.
Unusual Fire/Explosion Hazard:VAPS HVR/AIR CAN CONCENTRATE, TRAVEL TO
SOURCE OF IGNITIONS, & FLASH BACK. RESIDUE IN CNTNR CAN IGNITE
EXPLOSIVELY. ELECTRICAL GROUNDING IS REC (SUPDAT)
================== Accidental Release Measures ==================
Spill Release Procedures:VENTILATE AREA, ELIMINATE ALL SOURCES OF
IGNITION. WEAR APPROPRIATE PROTECTIVE GEAR, CONTAIN LEAK OR SPILL,
SALVAGE, CLEAN UP RESIDUE WITH ABSORBENT MATERIAL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:CONFINED SPACES, ROOMS/TANKS ARE AREAS
WHERE CONCERN FOR TLV'S IS ESPECIALLY IMPORTANT. REFERENCE OSHA
REGULATION CFR 29 1910.134 FOR REC RESP PROT.
Other Precautions:DO NOT WEAR CONTACT LENSES WHEN WORKING WITH THIS
MATERIAL.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WEAR RESPIRATOR PROTECTION WHENEVER AIRBORNE
CONCENTRATIONS EXCEED TLV CEILINGS OR TWA. USE NIOSH APPROVED
RESPIRATORS EQUIPPED WITH AN ORGANIC VAPOR CARTRIDGE FOR LISTED
HAZARD.
Ventilation:IS REC. AIR MOVEMENT MUST BE DESIGNED TO INSURE TURNOVER AT
ALL LOCATIONS IN WORK AREA TO AVOID BUILD UP OF HEAVY VAPS.
Protective Gloves:RUBBER/LATEX GLOVES.
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:ANSI APPRVD EMER EYE WASH & DELUGE SHOWER .
SELECTION OF SPECIFIC ITEMS SUCH AS BOOTS & APRON WILL (ING 9)
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
MFR'S TRADE NAME/PART #: CEILCOAT LINING. EXPLO HAZ: WHEN TRANSFERRING
MATL IN CNTNRS 1 GALLON (4 LITERS) OR LRGR. CNDTNS (STAB): PROD IS
NOT MIXED & USED ACCORDING TO DIRECTIONS. EFTS OF OVEREXP: A C
HRONIC STUDY IN RATS & MICE THAT STYRENE WAS NOT CARCINOGENIC.
THERE IS NO EPIDEMIOLOGY EVID THAT PRLNGD (ING 3)
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:SEE ING 1
Vapor Pres:SEE ING 1
Vapor Density:> AIR
Spec Gravity:1.0
Solubility in Water:NIL
Appearance and Odor:PURPLISH LIQUID; AROMATIC SWEET ODOR.
Percent Volatiles by Volume:50
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
PEROXIDE, OXIDIZING, & REDUCING AGENTS, METAL SALTS SUCH AS FERRIC AND
ALUMINUM CHLORIDES.
Stability Condition to Avoid:NOT SENSITIVE TO MECH IMPACT. AVOID
EXCESSIVE CATALYST & HEAT. EXCESSIVE HEAT, FUMES & SMOKE CAN OCCUR
IF THIS (SUPDAT)
Hazardous Decomposition Products:OXIDES OF CARBON AND NITROGEN; ACRID
FUMES AND VARIOUS UNKNOWN HYDROCARBONS FROM INCOMPLETE COMBUSTION.
==================== Disposal Considerations ====================
Waste Disposal Methods:HANDLE DISPOSAL OF WASTE MATERIAL IN MANNER
WHICH COMPLIES WITH LOCAL, STATE, PROVINCE AND FEDERAL REGULATION.
LANDFILL IF SOLIDIFIED OR INCINERATION AT AGENCY APPROVED
WASTE-DISPOSAL FACILITIES.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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