===================== Product Identification =====================
MSDS NAME:STANNOUS CHLORIDE, 3980
NIIN:00-145-2910
Status Code:A
MSDS Number: CHSVP
=== Responsible Party ===
Company:MALLINCKRODT BAKER INC
Address:222 RED SCHOOL LANE
City:PHILLIPSBURG
State:NJ
ZIP:08865
Country:US
Info Phone Num:800-582-2537
Emergency Phone Num:908-859-2151;800-424-9300(CHEMTREC)
CAGE:HO851
=== Contractor Identification ===
Company:MALLINCKRODT BAKER INC
Address:222 RED SCHOOL LANE
Box:City:PHILLIPSBURG
State:NJ
ZIP:08865
Country:US
Phone:800-582-2537
CAGE:HO851
Company:MALLINCKRODT BAKER, INC.
Address:222 RED SCHOOL LANE
Box:City:PHILLIPSBURG
State:NJ
ZIP:08865
Country:US
Phone:800-582-2537
CAGE:70829
============= Composition/Information on Ingredients =============
Name:STANNOUS CHLORIDE, SOLID
CAS:7772-99-8
RTECS #:XP8700000
Fraction by Wt: 98-100%
OSHA PEL:2 MG/M3 (SN)
ACGIH TLV:2 MG/M3 (SN)
Name:SUPDAT:FORM DIHYDRAZINE CHLORIDE, WHICH DECOMPOSES
EXPLOSIVELY WHEN HEATED. CONTACT W/STRONG OXIDIZING AGENTS/ (ING 3)
RTECS #:9999999ZZ
Name:ING 2:ALKALIES WILL GENERATE HEAT & FUMES.
RTECS #:9999999ZZ
Name:HAZ DECOMP PROD:HYDROCHLORIC ACID ARE PRESENT IN AQ SOLNS.
ABSORBS OXYG FROM AIR & FORMS INSOL OXYCHLORIDE. FORMS(ING 5)
RTECS #:9999999ZZ
Name:ING 4:AN INSOLUBLE BASIC SALT WHEN DISSOLVED W/MUCH WATER.
RTECS #:9999999ZZ
Name:EFTS OF OVEREXP:INFO:ANHYDROUS:INVESTIGATED AS A TUMORIGEN,
MUTAGEN, REPRO EFFECTOR. HYDRATE:INVESTIGATED AS A (ING 7)
RTECS #:9999999ZZ
Name:ING 6:MUTAGEN, REPRODUCTIVE EFFECTOR.
RTECS #:9999999ZZ
Name:WASTE DISP METH:CONTAINER & UNUSED CONTENTS I/A/W FEDERAL,
STATE & LOCAL REQUIREMENTS.
RTECS #:9999999ZZ
Name:OTHER PREC:CAUSES IRRITATION TO SKIN, EYES & RESPIRATORY
TRACT. AVOID CONTACT W/EYES, SKIN & CLOTHING. AVOID (ING 10)
RTECS #:9999999ZZ
Name:ING 9:BREATHING DUST. USE ONLY W/ADEQUATE VENTILATION.
RTECS #:9999999ZZ
Name:RESP PROT:EXPOS LEVELS ARE NOT KNOWN, USE NIOSH APPRVD
FULL-FACEPIECE POS-PRESS, AIR-SUPPLIED RESP. WARNING:AIR (ING 12)
RTECS #:9999999ZZ
Name:ING 11:PURIFYING RESPIRATORS DO NOT PROTECT WORKERS IN
OXYGEN-DEFICIENT ATMOSPHERES.
RTECS #:9999999ZZ
Name:VENT:GENRLY PREF BECAUSE IT CAN CONTROL EMISSIONS OF CONTAM
AT ITS SOURCE, PREVENTING DISPERSION OF IT INTO GEN (ING 14)
RTECS #:9999999ZZ
Name:ING 13:WORK AREA. PLEASE REFER TO ACGIH DOCUMENT,
"INDUSTRIAL VENTILATION, A MANUAL OF RECOMMENDED PRACTICES", (ING
15)
RTECS #:9999999ZZ
Name:ING 14:MOST RECENT EDITION, FOR DETAILS.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50:(ORAL,RAT) 700 MG/KG (ANHYDROUS).
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE:INHAL:CAUSES IRRIT TO RESP
TRACT. SYMPS MAY INCL COUGH, SHORTNESS OF BREATH. INGEST:CAUSES
IRRIT TO GI TRACT. SYMPS MAY INCL NAUS, VOMIT & DIARR. MAY CAUSE
BURNING IN MOUTH & THROAT, ABDOM PAIN, REDUCED BLOOD PRESS, STOM
BLEEDING, COLLAPSE & CONVLS. MAY CAUSE LIVER & KIDNEY DMG. SKIN
CONT:CAUSES (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:IRRIT. SYMPS INCL REDNESS, ITCH &
PAIN. EYE CONT:CAUSES IRRIT, REDNESS & PAIN. CHRONIC:RPTD SKIN CONT
W/SOLNS MAY CAUSE SKIN RASHES IN SUSCEPTIBLE INDIVIDUALS. PRLNG
INHAL OF DUST/FUME MAY RS LT IN BENIGN PNEUMOCONIOSIS, PRDCG
DISTINCTIVE CHANGES IN LUNGS W/NO APPARENT
DISABILITY/COMPLICATIONS. TOX (ING 6)
Medical Cond Aggravated by Exposure:PERSONS W/PRE-EXISTING SKIN
DISORDERS OR EYE PROBLEMS, OR IMPAIRED LIVER, KIDNEY OR RESPIRATORY
FUNCTION MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF THE SUBSTANCE.
======================= First Aid Measures =======================
First Aid:INHAL:REMOVE TO FRESH AIR. IF NOT BRTHG, GIVE ARTF RESP. IF
BRTHG IS DFCLT, GIVE OXYG. GET MED ATTN. INGEST:INDUCE VOMIT IMMED
AS DIRECTED BY MED PERS. NEVER GIVE ANYTHING BY MOUTH TO UNCON
PERS. GET MED ATTN. SKIN:IMMED FLUSH W/PLENTY OF WATER FOR AT LST
15 MINS. REMOVE CONTAM CLTHG & SHOES. GET MED ATTN. WASH CLTHG
BEFORE REUSE. THORO CLEAN SHOES BEFORE REUSE. EYES:IMMED FLUSH
W/PLENTY (SUPDAT)
===================== Fire Fighting Measures =====================
Extinguishing Media:USE ANY MEANS SUITABLE FOR EXTINGUISHING
SURROUNDING FIRE.
Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP . AQ
SOLNS OF THIS MATL ARE ACIDIC. AVOID ITS CONT W/EYES & SKIN. AVOID
BRTHG ITS FUMES/DUST. WHEN HEATED (SUPDAT)
Unusual Fire/Explosion Hazard:NOT CONSIDERED TO BE FIRE HAZ. NOT
CONSIDERED TO BE EXPLO HAZ, BUT REACT EXPLOSIVELY WHEN MIXED
W/NITRATES OR HYDROGEN PEROXIDE(>3% SOLN). SEALED CNTNRS(SUPDAT)
================== Accidental Release Measures ==================
Spill Release Procedures:VENTILATE AREA OF LEAK OR SPILL. WEAR
APPROPRIATE PERSONAL PROTECTIVE EQUIP AS SPECIFIED IN EXPOSURE
CONTROLS/PERSONAL PROT SECTION. SWEEP UP & CONTAINERIZE FOR
RECLAMATION OR DISPOSAL. VACUUMING OR W ET SWEEPING MAY BE USED TO
AVOID DUST DISPERSAL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:GEN STOR. KEEP IN TIGHTLY CLSD CNTNR,
STORED IN COOL, DRY, VENTED AREA. PROT AGAINST PHYSICAL DMG.
ISOLATE FROM INCOMPAT SUBSTANCES. CORROSIVE SOLID.
Other Precautions:AQ SOLNS ARE ACIDIC; USE ONLY IN CORROSION-RESIST
VESSELS. CNTNRS OF THIS MATL MAY BE HAZ WHEN EMPTY SINCE THEY
RETAIN PROD RESIDUES(DUST, SOLIDS); OBSERVE ALL WARNINGS & PRECS
LISTED FOR PROD. WARNIN G! HARMFUL IF SWALLOWED/INHALED, (ING 9)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF EXPOS LIM IS EXCEEDED, NIOSH APPRVD FULL
FACEPIECE RESP W/DUST/MIST FILTER MAY BE WORN UP TO 50 TIMES EXPOS
LIM/MAX USE CONC SPECIFIED BY APPROP REGULATORY AGENCY/RESP
SUPPLIER, WHICHEVER IS LOWEST . FOR EMERS/INSTANCES WHERE (ING 11)
Ventilation:VENT HOOD. SYS OF LOC &/OR GEN EXHST IS REC TO KEEP
EMPLOYEE EXPOS BELOW AIRBORNE EXPOS LIMS. LOC EXHST VENT IS (ING
13)
Protective Gloves:IMPERVIOUS GLOVES.
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:ANSI APPRVD EYE WASH FOUNTAIN & DELUGE
SHOWER . WEAR IMPERVIOUS PROT CLTHG, INCL BOOTS, LAB COAT,
APRON/COVERALLS.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
MP:100F,38C (WHEN RAPIDLY HEATED). FIRE FIGHT PROC:TO DECOMP IT EMITS
TOX & CORR FUME OF HYDROCHLORIC ACID. EXPLO HAZ:MAY RUPTURE WHEN
HEATED. FIRST AID PROC:OF WATER FOR AT LST 15 MINS, LIFTING LOWER
& UPPER LIDS OCCAS. GET MED ATTN IMMED. MATLS TO AVOID:HYDRAZINE
HYDRATE TO (ING 2)
================== Physical/Chemical Properties ==================
Melt/Freeze Pt:M.P/F.P Text:SUPP DATA
Spec Gravity:2.71
Solubility in Water:118G/100ML @ 0C.
Appearance and Odor:COLORLESS CRYSTALS; SLIGHT ODOR OF HYDROCHLORIC
ACID.
Percent Volatiles by Volume:0
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
SODIUM, POTASSIUM, BROMINE TRIFLUORIDE, CALCIUM CARBIDE, CALCIUM
ACETYLIDE, ETHYLENE OXIDE & NITRATES. REACTS W/(SUPDAT)
Stability Condition to Avoid:MOISTURE, HEAT, FLAMES, IGNITION SOURCES &
INCOMPATIBLES.
Hazardous Decomposition Products:WHEN HEATED TO DECOMP IT EMITS TOX &
CORR FUME OF HYDROCHLORIC ACID. POWERFUL REDUCING AGENT. SM QTYS OF
(ING 4)
==================== Disposal Considerations ====================
Waste Disposal Methods:WHATEVER CANNOT BE SAVED FOR RECOVERY/RECYCLING
SHOULD BE MANAGED IN APPROP & APPRVD WASTE DISP FACILITY.
PROCESSING, USE/CONTAM OF THIS PROD MAY CHANGE WASTE MANAGEMENT
OPTIONS. STATE & LOC DISP REGS MAY DIFFER FROM FED DISP REGS. DISP
OF(ING 8)
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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