===================== Product Identification =====================
MSDS NAME:MARSH SPRAY STENCIL INK BLACK
NIIN:00-469-7910
MSDS Number: BDZPL
=== Responsible Party ===
Company:MARSH STENCIL MACHINE CO.
Address:707 E. B STREET
City:BELLEVILLE
State:IL
ZIP:62222
Info Phone Num:618-234-1122
Emergency Phone Num:618-234-1122
CAGE:38512
=== Contractor Identification ===
Company:MARSH STENCIL MACHINE CO
Address:707-EAST B STREET
Box:388
City:BELLEVILLE
State:IL
ZIP:62222
Country:US
Phone:618-234-1122
CAGE:38512
============= Composition/Information on Ingredients =============
Name:TOLUENE (SARA III)
CAS:108-88-3
RTECS #:XS5250000
Other REC Limits:100PPM
OSHA PEL:200 PPM/150 STEL
ACGIH TLV:50 PPM; 9293
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:METHYLENE CHLORIDE (SARA III)
CAS:75-09-2
RTECS #:PA8050000
Other REC Limits:100PPM
OSHA PEL:500 PPM/C,1000; Z2
ACGIH TLV:50 PPM, A2; 9192
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:LPG (LIQUEFIED PETROLEUM GAS)
CAS:68476-85-7
RTECS #:SE7545000
Other REC Limits:800PPM
OSHA PEL:1000 PPM
ACGIH TLV:1000 PPM; 9192
Name:CARBON BLACK
CAS:1333-86-4
RTECS #:FF5800000
Other REC Limits:100PPM
OSHA PEL:3.5 MG/M3
ACGIH TLV:3.5 MG/M3; 9192
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYE, RESPIRATORY AND POSSIBLE SKIN
IRRITANT, MAY CAUSE DIZZINESS, UNCONSCIOUSNESS,OR COMA.
Effects of Overexposure:EYE, RESPIRATORY AND POSSIBLE SKIN IRRITANT,
MAY CAUSE DIZZINESS, UNCONSCIOUSNESS,OR COMA.
Medical Cond Aggravated by Exposure:NONE LISTED BY MFR
======================= First Aid Measures =======================
First Aid:EYE: FLUSH WITH WATER FOR 15 MINUTES & GET MEDICAL ATTENTION.
SKIN:WASH WITH SOAP & WATER. INHALATION:REMOVE TO FRESH AIR, IF
DISCOMFORT PERSISTS, GET MEDICAL ATTENTION. INGESTION CALL
PHYSICIAN IMMED IATELY, DO NOT INDUCE VOMITING.
===================== Fire Fighting Measures =====================
Flash Point:EXTREMELY FLAMMA
Lower Limits:1.8
Upper Limits:0
Extinguishing Media:CO*2, DRY CHEMICAL, ALCOHOL FOAM
Fire Fighting Procedures:WEAR PRESSURE DEMAND SCBA AND FULL PROTECTIVE
EQUIPMENT.
Unusual Fire/Explosion Hazard:THERMAL DECOMPOSITION PRODUCTS MAY
CONTAIN HCL AND PHOSGENE.
================== Accidental Release Measures ==================
Spill Release Procedures:ELIMINATE ALL IGNITION SOURCES. VENTILATE TO
REDUCE AND REMOVE THE PROPELLANT FIRE HAZARDS. ABSORB LIQUID WITH
INERT MATERIAL.
Neutralizing Agent:NOT KNOWN
====================== Handling and Storage ======================
Handling and Storage Precautions:EXPOSURE TO TEMPERATURE ABOVE
120F(54C) MAY CAUSE THE CONTAINER TO BURST, RELEASING THE HIGHLY
FLAMMABLE PROPELLANT.
Other Precautions:PROPELLENT VAPORS ARE HEAVIER THAN AIR. IN CASE OF
RUPTURE, VENTILATE AS TO PREVENT CONCENTRATIONS FROM REACHING
FLAMMABLE LEVELS.(MFG) NO SMOKING IN AREA OF USE. DO NOT USE IN
GENERAL VICINITY OF ARC WELDING, OPEN FLAMES OR (SEE SUPP DATA)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN.
Ventilation:LOCAL EXHAUST PREDERABLE, MECHANICAL ACCETABLE.
Protective Gloves:RUBBER GLOVES
Eye Protection:SAFETY GOGGLES
Other Protective Equipment:NOT KNOWN
Work Hygienic Practices:NOT KNOWN
Supplemental Safety and Health
OTHER PREC: HOT SURFACES. HEAT AND/OR UV RADIATION MAY CAUSE THE
FORMATION OF HCL AND/OR PHOSGENE.
================== Physical/Chemical Properties ==================
HCC:V3
Boiling Pt:B.P. Text:-43F/-41C
Vapor Pres:45MMHG
Vapor Density:>AIR
Spec Gravity:0.99
Evaporation Rate & Reference:>1 ETHER = 1
Solubility in Water:NONE
Appearance and Odor:BLACK WITH CHLORINATED ODOR
Percent Volatiles by Volume:92
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NOT KNOWN.
Stability Condition to Avoid:AVOID EXPOSURE TO HEAT AND FLAME
Hazardous Decomposition Products:HCL PHOSGENE NONE(MFR)
Conditions to Avoid Polymerization:WILL NOT OCCUR(MFR)
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IAW LOCAL, STATE, FEDERAL
REGULATIONS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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