===================== Product Identification =====================
MSDS NAME:HUCKER AMMONIUM OXALATE CRYSTAL VIOLET, 15-4724A
NIIN:00000000000
Status Code:A
MSDS Number: CKBVG
=== Responsible Party ===
Company:CAROLINA BIOLOGICAL SUPPLY CO
Address:2700 YORK RD
City:BURLINGTON
State:NC
ZIP:27215-3387
Country:US
Info Phone Num:800-227-1150
Emergency Phone Num:800-227-1150
Chemtrec Ind/Phone:(800)424-9300
CAGE:59896
=== Contractor Identification ===
Company:CAROLINA BIOLOGICAL SUPPLY CO
Address:2700 YORK RD
Box:City:BURLINGTON
State:NC
ZIP:27215-3387
Country:US
Phone:800-227-1150/910-584-0381
Contract Num:MDA414-98-01180122
CAGE:59896
============= Composition/Information on Ingredients =============
Name:CRYSTAL VIOLET STAIN
CAS:548-62-9
RTECS #:BO9000000
= Wt:3.
Other REC Limits:NONE RECOMMENDED
Name:AMMONIUM OXALATE
CAS:1113-38-8
RTECS #:RO2750000
= Wt:.8
Other REC Limits:NONE RECOMMENDED
Name:ETHYL ALCOHOL (ETHANOL)
CAS:64-17-5
RTECS #:KQ6300000
= Wt:19.
Other REC Limits:NONE RECOMMENDED
OSHA PEL:1000 PPM
ACGIH TLV:1000 PPM; 9596
Name:METHYL ISOBUTYL KETONE (HEXONE) (SARA 313) (CERCLA)
CAS:108-10-1
RTECS #:SA9275000
= Wt:.76
Other REC Limits:NONE RECOMMENDED
OSHA PEL:100 PPM
ACGIH TLV:50 PPM/75 STEL; 9596
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:HEXANE (N-HEXANE) (CERCLA)
CAS:110-54-3
RTECS #:MN9275000
= Wt:.24
Other REC Limits:NONE RECOMMENDED
OSHA PEL:500 PPM
ACGIH TLV:50 PPM; 9596
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYES: MAY CAUSE IRRITATION. SKIN: MAY
CAUSE IRRITATION. INHALATION: MAY CAUSE IRRITATION TO RESPIRATORY
TRACT. INGESTION: MAY CAUSE GASTROINTESTINAL DISCOMFORT.
Effects of Overexposure:EYES: IRRITATION. SKIN: IRRITATION. INHALATION:
IRRITATION TO RESPIRATORY TRACT. INGESTION: GI TRACT DISCOMFORT.
======================= First Aid Measures =======================
Eyes: FLUSH WITH WATER FOR AT LEAST 5 MINUTES, RAISING AND
LOWERING EYELIDS OCCASIONALLY. GET MEDICAL ATTENTION IF NEEDED.
SKIN: THOROUGHLY WASH EXPOSED AREA FOR AT LEAST 15 MIN. REMOVE
CONTAMINATED C LOTHING. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.
INHALATION: MOVE TO FRESH AIR. ASSIST WITH BREATHING IF NEEDED.
GET MEDICAL ATTENTION. INGESTION: GIVE PLENTY OF WATER AND INDUCE
VOMITING IMMEDIA TELY AS DIRECTED BY DOCTOR. GET MEDICAL ATTENTION.
CALL POISON CONTROL CENTER FOR ADVICE.
===================== Fire Fighting Measures =====================
Flash Point Method:CC
Flash Point:=13.1C, 55.6F
ETHYL ALCOHOL
Autoignition Temp:=422.8C, 793.F
Autoignition Temp Text:E. AL
Lower Limits:3.3
Upper Limits:19
Extinguishing Media:USE DRY CHEMICAL, CARBON DIOXIDE, OR APPROPRIATE
FOAM.
Fire Fighting Procedures:FIREFIGHTERS SHOULD WEAR FULL PROTECTIVE
EQUIPMENT AND NIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS.
Unusual Fire/Explosion Hazard:IF HEATED TO DECOMPOSITION, THIS MATERIAL
MAY EMIT OXIDES OF CARBON. DUE TO THE DILUTION OF THE FLAMMABLE
MATERIAL IN THIS MIXTURE IS NOT LIKELY TO POSE A SERIOUS FIRE OR
EXPLOSION THREAT. HOWEVER, IF EXPOSED TO EXCESSIVE HEAT, FLAMMABLE
VAPORS MAY BE RELEASED.
================== Accidental Release Measures ==================
Spill Release Procedures:VENTILATE AREA OF SPILL. ELIMINATE ALL SOURCES
OF IGNITION. REMOVE ALL NON-ESSENTIAL PERSONNEL FROM AREA. CLEAN-UP
PERSONNEL SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND CLOTHING.
ABSORB MATERIAL WITH SUITABLE ABSORBENT AND CONTAINERIZE FOR
DISPOSAL.
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE TIGHTLY CLOSED IN A COOL, DRY,
WELL VENTILATED AREA SUITABLE FOR GENERAL CHEMICAL STORAGE.
Other Precautions:NONE
============= Exposure Controls/Personal Protection =============
Respiratory Protection:A NIOSH/MSHA CHEMICAL CARTRIDGE RESPIRATOR
SHOULD BE WORN IF PEL OR TLV IS EXCEEDED.
Ventilation:LOCAL EXHAUST PREFERRED, MECHANICAL (GENERAL) ACCEPTABLE.
Protective Gloves:RUBBER, NEOPRENE, PVC, OR EQUIVALENT.
Eye Protection:SPLASH PROOF CHEMICAL SAFETY GOGGLES SHOULD BE WORN AT
ALL TIMES.
Other Protective Equipment:EYE WASH, LAB COAT, AND SAFETY SHOWER.
Supplemental Safety and Health
NONE
================== Physical/Chemical Properties ==================
HCC:F3
Vapor Pres:NO INFORMATION AVAILABLE
Spec Gravity:<1
Evaporation Rate & Reference:NO INFORMATION AVAILABLE.
Solubility in Water:COMPLETE
Appearance and Odor:DEEP PURPLE SOLUTION WITH ODOR OF ETHANOL.
Percent Volatiles by Volume:97
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
WATER REACTIVE MATERIALS, STRONG OXIDIZERS.
Stability Condition to Avoid:EXCESSIVE HEAT, FLAME.
Hazardous Decomposition Products:IF HEATED TO DECOMPOSITION, MAY EMIT
OXIDES OF CARBON AND NITROGEN.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
=================== Toxicological Information ===================
Toxicological Information:TOXICOLOGICAL PROPERTIES OF THIS MIXTURE HAVE
NOT BEEN THROUGHLY EVALUATED. DATA IS LISTED FOR INDIVIDUAL ITEMS.
CRYSTAL VIOLET STAIN - (ORAL-RAT) = 420MG/KG. AMMONIUM OXALATE- NO
TOXICITY DATA. ETHYL ALCOHOL - LD50 (ORAL-RAT) - 7,060 MG/KG; LC50
(IHL-RAT) = 8,000 PPM/4H. HEXANE: LD50 (ORAL-RAT) = 28,710 MG/KG,
(IHL-HUMAN) - 5,000 PPM/10M. CRYSTAL VIOLET STAIN: MUTATION
REFERENCES CITED. REPRODUC TIVE EFFECTS REFERENCES CITED.
TUMORIGENIC REFERENCES CITED. AMMONIUM OXALATE: NO CHRONIC EFFECTS
DATA FOUND. ETHYL ALCOHOL: MUTATION DATA CITED. METHYL ISOBUTYL
KETONE: NO CHRONIC EFFECTS CITED. HEXA NE: MUTATION DATA CITED.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH ALL APPLICABLE
FEDERAL, STATE, AND LOCAL REGULATIONS. ALWAYS CONTACT A PERMITTED
WASTE DISPOSER (TSD) TO ASSURE COMPLIANCE. EPA WASTE NUMBER: METHYL
ISOBUTYL KETONE (U161).
=================== MSDS Transport Information ===================
Transport Information:NON-REGULATED MATERIAL.
===================== Regulatory Information =====================
SARA Title III Information:HAZARD CATEGORY FOR SECTION 311/312
REPORTING: ACUTE. SARA SEC. 313: CRYSTAL VIOLET STN, AMMONIUM
OXALATE, ETHYL ALCOHOL, AND HEXANE: SARA EHS SEC. 302 TPQ: NO;
SARA SEC 313 CHEMICALS NAME LIST= NO; CHEMICAL CATEGORY=NO; CERCLA
SECTION 103 RQ LBS= NO; RCRA SEC 261.33=NO. METHYL ISOBUTYL KETONE:
SARA EHS SEC 302 TPQ=NO; SARA SEC 313 CHEMICALS NAME LIST= YES;
CHEMICAL CATEGORY = NO ; CERCLA SEC 10 3 RQ LBS= 5000 LBS.; RCRA
SEC 261.33 = YES.
Federal Regulatory Information:EA TSCA STATUS: ON TSCA INVENTORY.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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