===================== Product Identification =====================
MSDS NAME:COPPER, S79978ND
Status Code:A
MSDS Number: CKBRW
=== Responsible Party ===
Company:FISHER SCIENTIFIC
Address:ONE REAGENT LANE
City:FAIRLAWN
State:NJ
ZIP:07410
Country:US
Info Phone Num:201-796-7100
Emergency Phone Num:201-796-7100
Chemtrec Ind/Phone:(800)424-9300
CAGE:1B464
=== Contractor Identification ===
Company:FISHER SCIENTIFIC CO. CHEMICAL MFG DIV
Address:1 REAGENT LANE
Box:City:FAIRLAWN
State:NJ
ZIP:07410-2802
Country:US
Phone:201-796-7100
CAGE:1B464
============= Composition/Information on Ingredients =============
Name:COPPER EINECS/ELINCS: 231-159-6.
CAS:7440-50-8
RTECS #:GL5325000
= Wt:100.
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYE: CAUSES EYE IRRITATION. SKIN:
CAUSES SKIN IRRITATION. MAY CAUSE SKIN DISCOLORATION. INGESTION:
CAUSES GASTROINTESTINAL IRRITATION WITH NAUSEA, VOMITING AND
DIARRHEA. MAY CAUSE LIVER AND KIDNEY DAM AGE. INHALATION: DUST IS
IRRITATING TO THE RESPIRATORY TRACT. INHALATION OF FUMES MAY CAUSE
METAL FUME FEVER, WHICH IS CHARACTERIZED BY FLU-LIKE SYMPTOMS WITH
METALLIC TASTE, FEVER, CHILLS, COUGH, WEA KNESS, CHEST PAIN, MUSCLE
PAIN AND INCREASED WHITE BLOOD CELL COUNT. CHRONIC: PROLONGED OR
REPEATED SKIN CONTACT MAY CAUSE DERMATITIS. MAY CAUSE LIVER AND
KIDNEY DAMAGE. MAY CAUSE LUNG DAMAGE. TARGET ORGANS: KIDNEYS,
LIVER, LUNGS.
Effects of Overexposure:SEE HEALTH HAZARDS.
======================= First Aid Measures =======================
Eyes: FLUSH EYES W/PLENTY OF WATER FOR AT LEAST 15 MIN,
OCCASNLY LIFTING UPPER & LOWER LIDS. GET MED AID. SKIN: FLUSH SKIN
W/PLENTY OF SOAP & WATER FOR AT LEAST 15 MIN WHILE REMOVING CONTAM
CLTHG & SH OES. GET MED AID IF IRRIT DEVELOPS OR PERSISTS. INGEST:
INDUCE VOMITING. IF VICTIM IS CONSCIOUS & ALERT, GIVE 2-4 CUPFULS
OF MILK OR WATER. GET MED AID. INHAL: REMOVE FROM EXPOS TO FRESH
AIR IMMED. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF
BREATHING IS DIFFICULT, GIVE OXYGEN. GET MED AID. NOTES TO MD:
INDIVIDUALS W/WILSON'S DISEASE ARE MORE SUSCEPTIBLE TO CHRONIC
COPPER POISONING. ANTIDOTE : USE OF METAL CHELATOR MAY BE OF VALUE.
===================== Fire Fighting Measures =====================
Lower Limits:NOT AVAIL
Upper Limits:NOT AVAIL
Extinguishing Media:USE EXTINGUISHING MEDIA MOST APPROPRIATE FOR THE
SURROUNDING FIRE.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:MATERIAL CAN SPONTANEOUSLY IGNITE
(PYROPHORIC) WHEN EXPOSED TO AIR AT NORMAL OR SLIGHTLY ELEVATED
TEMPERATURES.
================== Accidental Release Measures ==================
Spill Release Procedures:USE PROPER PERSONAL PROTECTIVE EQUIPMENT AS
INDICATED IN SECTION 8, EXPOSURE CONTROLS, PERSONAL PROTECTION.
SWEEP UP, THEN PLACE INTO A SUITABLE CONTAINER FOR DISPOSAL. AVOID
GENERATING DUSTY CONDITIO NS.
====================== Handling and Storage ======================
Handling and Storage Precautions:USE WITH ADEQUATE VENTILATION.
MINIMIZE DUST GENERATION AND ACCUMULATION. AVOID CONTACT W/SKIN AND
EYES. AVOID INGESTION AND INHALATION. STORE IN A TIGHTLY CLOSED
CONTAINER. STORE IN A COOL, DRY, WELL -VENTILATED AREA AWAY FROM
INCOMPATIBLE SUBSTANCES. DO NOT EXPOSE TO AIR.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:FOLLOW THE OSHA RESPIRATOR REGULATIONS FOUND IN
29 CFR 1910.134 OR EUROPEAN STANDARD EN 149. ALWAYS USE A NIOSH OR
EUROPEAN STANDARD EN 149 APPROVED RESPIRATOR WHEN NECESSARY.
Ventilation:USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION TO KEEP
AIRBORNE CONCENTRATIONS BELOW THE PERMISSIBLE EXPOSURE LIMITS.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:EYE WASH AND DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA . WEAR APPROPRIATE PROTECTIVE CLOTHING TO MINIMIZE
CONTACT WITH SKIN.
Supplemental Safety and Health
EXPOS LIMS: COPPER: ACGIH: FUME: (0.2) MG/M3; DUSTS &MISTS, AS CU: (1)
MG/M3. NIOSH: AS CU: 1 MG/M3 TWA (DUSTS & MISTS); 0.1 MG/M3 TWA
(FUME) DUSTS AS MISTS AS CU: 100 MG/M3 IDLH. OSHA - FINAL PELS: F
UME, AS CU: 0.1 MG/M3 TWA; DUSTS & MISTS, AS CU: MG/. OSHA VACATED
PELS: COPPER: FUME, AS CU: 0.1 MG/M3 TWA.
================== Physical/Chemical Properties ==================
Boiling Pt:=2595.C, 4703.F
Melt/Freeze Pt:=1083.C, ######F
Decomp Temp:Decomp Text:NOT AVAILABLE
Vapor Pres:1 MM HG @ 1628C
Vapor Density:NOT AVAIL
Spec Gravity:8.92
pH:NOT AVAILABLE
Solubility in Water:INSOLUBLE
Appearance and Odor:RED TO BROWN SOLID; NO ODOR REPORTED.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
LIQ COPPER EXPLODES ON CNTCT W/WATER. REACTS VIOLENTLY W/AMMONIUM
NITRATE, BROMATES, IODATES, CHLORATES, ETHYLENE OXIDE, HYDRAZOIC
ACID, POTASSIUM OXIDE, DIMETHYL SULFOXIDE + TRICHLOROACETIC ACID,
HYDROGEN PEROXIDE, SODIUM
Stability Condition to Avoid:INCOMPAT MATLS; DUST GENERATION, MOISTURE,
EXPOS TO AIR. STABLE AT ROOM TEM IN CLOSED CNTNRS UNDER NORM
STORAGE & HNDLG CNDTNS. EXPLOSIVE PEROXIDES MAY FORM ON
CONCENTRATION.
Hazardous Decomposition Products:COPPER FUMES
Conditions to Avoid Polymerization:HAS NOT BEEN REPORTED.
=================== Toxicological Information ===================
Toxicological Information:LD50/LC50: NOT AVAIL. CARCINOGENICITY: CAS
#7440-50-8: NOT LISTED BY ACGIH, IARC, NIOSH, NTP OR OSHA.
EPIDEMIOLOGY: NO DATA AVAIL. TERATOGENICITY: EXPERIMENTAL STUDIES
SHOW TERATOGENIC EFTS IN LAB ANI MALS. REPRO EFTS: NO DATA AVAIL.
NEUROTOXICITY: NO DATA AVAIL. MUTAGENICITY: NO DATA AVAIL. OTHER
STUDIES: EXPERIMENTAL STUDIES SHOW TUMORIGENIC EFTS IN LAB ANIMALS.
--FEDERAL REG INFO: TWA 0.2 MG/M3 (FUME). OEL-AUSTRALIA: TWA 1
MG/M3 (DUST). OEL-BELGIUM: TWA 0.2 MG/M3 (FUME). OEL-BELGIUM: TWA 1
MG/M3 (DUST). OEL-DENMARK: TWA 0.1 MG/M3 (FUME). OEL-DENMARK: TWA 1
MG/M3 (DUST). OEL-FINLAND: TWA 0.2 MG/M3 (FUME). (ECOLOGICAL INFO)
===================== Ecological Information =====================
Ecological:ECOTOXICITY: NOT AVAIL. ENVIRONMENTAL FATE: NOT AVAIL.
PHYSICAL/CHEM: NOT AVAIL. OTHER: NOT AVAIL. --TOXICOLOGICAL INFO:
OEL-FINLAND: TWA 1 MG/M3. OEL-FINLAND: TWA 1 MG/M3 (DUST).
OEL-FRANCE: TWA 0.2 MG/M3 (FUME). OEL-FRANCE: TWA 1 MG/M3; STEL 2
MG/M3 (DUST). OEL-GERMANY: TWA 0.1 MG/M3 (FUME). OEL-GERMANY: TWA 1
MG/M3. OEL-GERMANDY: TWA 1 MG/M3 (DUST). OEL-HUNGARY: TWA 0.2
MG/M3; STEL 0.4 MG/M3 (D UST). OEL-INDIA: TWA 0.2 MG/M3 (FUME).
OEL-THE NETHERLANDS: TWA 02 MG/M3 (FUME). OEL-THE NETHERLANDS: TWA
1 MG/M3 (DUST). OEL-THE PHILIPPINES: TWA 1 MG/M3 (FUME).
OEL-POLAND: TWA 0.1 MG/M3 (FUME). (TR ANSPORT INFO)
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT WITH FEDERAL,
STATE AND LOCAL REGULATIONS. RCRA D-SERIES MAXIMUM CONCENTRATION OF
CONTAMINANTS: NONE LISTED. RCRA D-SERIES CHRONIC TOXICITY REFERENCE
LEVELS: NONE LIS TED. RCRA F-SERIES: NONE LISTED. RCRA P-SERIES:
NONE LISTED. RCRA U-SERIES: NONE LISTED.
=================== MSDS Transport Information ===================
Transport Information:US DOT, IATA, RID/ADR, IMO, CANADA TDG: NO INFO
AVAIL. --ECOLOGICAL INFO: OEL-RUSSIA: STEL 0.5 PPM (1 MG/M3)
(DUST). OEL-SWEDEN: TWA 0.2 MG/M3 (RESP DUST). OEL-SWEDEN: TWA 0.2
MG/M3 (FUME). OEL-SWEDEN : TWA 1 MG/M3 (TOTAL DUST).
OEL-SWITZERLAND: TWA 0.1 MG/M3; STEL 0.2 MG/M3 (FUME).
OEL-SWITZERLAND: TWA 1 MG/M3; STEL 1 MG/M3. OEL-THAILAND: TWA 0.1
MG/M3 (FUME). OEL-THAILAND: TWA 1 MG/M3. OEL-UNITED KINGDOM: TWA
0.2 MG/M3 (FUME). OEL-UNITED KINGDOM: TWA 1 MG/M3. OEL IN BULGARIA,
COLOMBIA, JORDAN, KOREA CHECK ACGIH TLV.
===================== Regulatory Information =====================
SARA Title III Information:SECTION 302 (RQ) CAS #7440-50-8: FINAL RQ =
5000 LBS (2270 KG) (NO REPORTING OF RELS). SECTION 302 (TPQ) NONE
OF CHEMS IN PROD HAVE TPQ. SARA CODES: CAS #7440-50-8: ACUTE,
CHRONIC, FLAM. SECTION 313: THIS MATL CNTNS COPPER (#7440-50-8,
100%) WHICH IS SUBJECT TO REPORTING REQS OF SECTION 313 OF SARA
TITLE III & 40 CFR PART 373.
Federal Regulatory Information:CAS #7440-50-8 IS LISTED ON TSCA
INVENTORY. NONE OF CHEMS ARE ON HLTH & SFTY REPORTING LIST. NONE OF
CHEMS IN PROD ARE UNDER CHEM TEST RULE. NONE OF CHEMS ARE LISTED
UNDER TSCA SECTION 12B. NONE OF CH EMS IN MATL HAVE SNUR UNDER
TSCA. EUROPEAN/INTERNATL REGS - EUROPEAN LABELING I/A/W EC
DIRECTIVES HAZ SYMBOLS: NOT AVAIL. WGK (WATER DANGER/PROT) CAS
#7440-50-8: 0. CANADA - CAS #7440-50-8 IS LISTED O N CANADA'S
DSL/NDSL LIST. PROD HAS WHMIS CLASSIFICATION OF D2B. IT IS NOT
LISTED ON CANADA'S INGRED DISCLOSURE LIST. EXPOS LIMS: CAS
#7440-50-8: OEL-ARAB REPUBLIC OF EGYPT: TWA 0.1 MG/M3 (FUME).
OEL-AUSTRALIA: (TOXICOLOGICAL INFO)
State Regulatory Information:CAS #7440-50-8 CAN BE FOUND ON FOLLOWING
STATE RIGHT TO KNOW LISTS: CA, NJ, FL, PA, MN, MA. CALIFORNIA NO
SIGNIFICANT RISK LEVEL: NONE OF CHEMS IN THIS PROD ARE LISTED.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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