===================== Product Identification =====================
MSDS NAME:818 3428,FLEXICOLOR AR DEVELOPER REPLENISHER PART C
NIIN:01-285-1765
Status Code:A
Kit Part:Y
MSDS Number: CKTGD
=== Responsible Party ===
Company:EASTMAN KODAK COMPANY
Address:343 STATE STREET
City:ROCHESTER
State:NY
ZIP:14650
Country:US
Info Phone Num:716-722-5151/(800) 242-2424
Emergency Phone Num:716 722-5151
Preparer's Name:NOT PROVIDED
CAGE:19139
=== Contractor Identification ===
Company:EASTMAN KODAK CO GOVERNMENT MARKETS CONTRACTS
Address:343 STATE ST
Box:City:ROCHESTER
State:NY
ZIP:14650-1115
Country:US
Phone:716-722-5151/(800) 242-2424
CAGE:19139
============= Composition/Information on Ingredients =============
Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Minumum % Wt:50.
Maxumum % Wt:55.
Other REC Limits:NOT PROVIDED
Code:F
Code:F
Name:4-(N-ETHYL-N-2-HYDROXYETHYL)-2-METHYLPHENYLENEDIAMINE
SULFATE
CAS:25646-77-9
Code:F
RTECS #:KJ6477000
Minumum % Wt:45.
Maxumum % Wt:50.
Other REC Limits:0.1 MG/M3 (MFR)
OSHA PEL:NOT PROVIDED
ACGIH TLV:NOT PROVIDED
Name:SODIUM BISULFITE
CAS:7631-90-5
RTECS #:VZ2000000
Minumum % Wt:1.
Maxumum % Wt:5.
Other REC Limits:NOT PROVIDED
OSHA PEL:5 PPM (SO2)
ACGIH TLV:5 MG/M3
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:NOT PROVIDED
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EFFECTS OF EXPOSURE: CONTAINS
4-(N-ETHYL-N-2-HYDROXYETHYL)-2-METHYLPHENYLENEDIAMINE SULFATE. MAY
CAUSE KIDNEY DAMAGE BASED ON ANIMAL DATA. INHALATION: LIBERATES
SULFUR DIOXIDE GAS WHICH CAN CAUSE IRRI TATION TO THE RESPIRATORY
TRACT. SOME ASTHMATICS OR HYPERSENSITIVE INDIVIDUALS MAY EXPERIENCE
DIFFICULT BREATHING. EYES: CAUSES IRRITATION. SKIN: CAUSES
IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION. I NGESTION: MAY BE
FATAL IF SWALLOWED. MAY CAUSE IRRITATION OF THE GASTROINTESTINAL
TRACT. SOME ASTHMATICS OR SULFITE-SENSITIVE INDIVIDUALS MAY
EXPERIENCE WHEEZING, CHEST TIGHTNESS, STOMACH UPSET, HIVES ,
FAINTNESS, WEAKNESS AND DIARRHEA.
Explanation of Carcinogenicity:CARCINOGENICITY CLASSIFICATION
(COMPONENTS PRESENT AT 0.1% OR MORE): INTERNATIONAL AGENCY FOR
RESEARCH ON CANCER (IARC): NONE. AMERICAN CONFERENCE OF
GOVERNMENTAL INDUSTRIAL HYGIENISTS (ACGIH): NONE. NATIONAL
TOXICOLOGY PROGRAM (NTP): NONE. OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION (OSHA): NONE.
Effects of Overexposure:INHALATION: LIBERATES SULFUR DIOXIDE GAS WHICH
CAN CAUSE IRRITATION TO THE RESPIRATORY TRACT. EYES: CAUSES
IRRITATION. SKIN: CAUSES IRRITATION. MAY CAUSE ALLERGIC SKIN
REACTION. INGESTION: MAY CAUSE IRRITATION OF THE GASTROINTESTINAL
TRACT.
Medical Cond Aggravated by Exposure:SOME ASTHMATICS, HYPERSENSITIVE OR
SULFITE-SENSITIVE INDIVIDUALS MAY EXPERIENCE DIFFICULT BREATHING,
WHEEZING, CHEST TIGHTNESS, STOMACH UPSET, HIVES, FAINTNESS,
WEAKNESS AND DIARRHEA.
======================= First Aid Measures =======================
First Aid:INHALATION: IF SYMPTOMATIC, MOVE TO FRESH AIR. TREAT
SYMPTOMATICALLY. GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. EYES:
IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. GET
MEDICAL ATTEN TION. SKIN: IMMEDIATELY FLUSH WITH PLENTY OF WATER
FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING AND
SHOES. WASH CONTAMINATED CLOTHING BEFORE REUSE. DESTROY OR
THOROUGHLY CLEAN CONTAMIN ATED SHOES. GET MEDICAL ATTENTION IF
SYMPTOMS OCCUR. INGESTION: INDUCE VOMITING AS DIRECTED BY MEDICAL
PERSONNEL. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
CALL A PHYSICIAN OR POISON CONT ROL CENTER IMMEDIATELY.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:WATER, CARBON DIOXIDE (CO2), DRY CHEMICAL, ALCOHOL
FOAM.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
PROTECTIVE CLOTHING. FIRE OR EXCESSIVE HEAT MAY PRODUCE HAZARDOUS
DECOMPOSITION PRODUCTS. USE WATER SPRAY TO KEEP FIRE EXPOSED
CONTAINERS COOL.
Unusual Fire/Explosion Hazard:ELEVATED TEMPERATURE CAN CAUSE
DECOMPOSITION.
================== Accidental Release Measures ==================
Spill Release Procedures:PREVENT RUNOFF FROM ENTERING DRAINS, SEWERS,
OR STREAMS. ABSORB SPILL WITH VERMICULITE OR OTHER INERT MATERIAL,
THEN PLACE IN A CONTAINER FOR CHEMICAL WASTE.
Neutralizing Agent:NOT PROVIDED
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE IN A COOL PLACE. KEEP AWAY FROM
INCOMPATIBLE SUBSTANCES. KEEP CONTAINER CLOSED. KEEP FROM CONTACT
WITH OXIDIZING MATERIALS. KEEP AWAY FROM HEAT. EXERCISE CAUTION IF
HEATING, ESPECIALLY IN A CLOS ED CONTAINER.
Other Precautions:AVOID BREATHING MIST OR VAPOR AT CONCENTRATIONS
GREATER THAN THE EXPOSURE LIMITS. AVOID CONTACT WITH EYES AND
PROLONGED OR REPEATED CONTACT WITH SKIN. USE ONLY WITH ADEQUATE
VENTILATION. WASH THOROUGH LY AFTER HANDLING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF ENGINEERING CONTROLS DO NOT MAINTAIN AIRBORNE
CONCENTRATIONS BELOW RECOMMENDED EXPOSURE LIMITS, AN APPROVED
RESPIRATOR MUST BE WORN. RESPIRATOR TYPE: ACID GAS. IF RESPIRATORS
ARE USED, A PROGRAM SH OULD BE INSTITUTED TO ASSURE COMPLIANCE WITH
OSHA STANDARD 29 CFR 1910.134.
Ventilation:GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES PER
HOUR) SHOULD BE USED. VENTILATION RATES SHOULD BE MATCHED TO
CONDITIONS.
Protective Gloves:WEAR IMPERVIOUS GLOVES APPROPRIATE FOR RISK OF
EXPOSURE.
Eye Protection:WEAR SAFETY GLASSES WITH SIDE SHIELDS (OR GOGGLES).
Other Protective Equipment:EYE BATH, SAFETY SHOWER, WASHING FACILITIES.
WEAR PROTECTIVE CLOTHING APPROPRIATE FOR RISK OF EXPOSURE.
Work Hygienic Practices:NOT PROVIDED
Supplemental Safety and Health
SUPPLEMENTARY LOCAL EXHAUST VENTILATION, CLOSED SYSTEMS, OR RESPIRATORY
PROTECTION MAY BE NEEDED IN SPECIAL CIRCUMSTANCES SUCH AS POORLY
VENTILATED SPACES, EVAPORATION FROM LARGE SURFACES, SPRAYING, H
EATING, ETC.
================== Physical/Chemical Properties ==================
HCC:C2
NRC/State Lic Num:NOT RELEVANT
Boiling Pt:>100.C, 212.F
Melt/Freeze Pt:M.P/F.P Text:NOT PROVIDED
Decomp Temp:>170.C, 338.F
Vapor Pres:18.0 MM HG @ 68F
Vapor Density:0.6
Spec Gravity:1.19
pH:2.1
Viscosity:NOT PROVIDED
Evaporation Rate & Reference:NEGLIGIBLE
Solubility in Water:COMPLETE
Appearance and Odor:YELLOW LIQUID, STRONG SULFUR DIOXIDE ODOR
Percent Volatiles by Volume:50-60 BY WT
Corrosion Rate:NOT PROVIDED
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG BASES, STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:STABLE; HOWEVER, MATERIAL CAN DECOMPOSE
ABOVE 170C (338F). AVOID TEMPERATURES ABOVE 70C (158F).
Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE,
OXIDES OF SULFUR, OXIDES OF NITROGEN.
=================== Toxicological Information ===================
Toxicological Information:DATA FOR
4-(N-ETHYL-N-2-HYDROXYETHYL)-2-METHYLPHENYLENEDIAMINE SULFATE.
ACUTE TOXICITY DATA: ORAL LD50 (MALE RAT): 25-50 MG/KG (TARGET
ORGAN EFFECTS: KIDNEY). ORAL LD50 (FEMALE RAT): 30 MG/KG (TARGET
ORGAN EFFECTS: KIDNEY). ORAL LD50 (MOUSE): 141 MG/KG (TARGET ORGAN
EFFECTS: KIDNEY). DERMAL LD50: > 2000 MG/KG. SKIN IRRITATION:
MODERATE. REPEATED SKIN APPLICATION: MODERATE IRRITATION. SKIN
SENSITI ZATION: MODERATE TO STRONG. SKIN SENSITIZATION (HUMAN):
POSITIVE. EYE IRRITATION (UNWASHED EYES): MODERATE. EYE IRRITATION
(WASHED EYES): SLIGHT. INHALATION STUDY (164 MG/M3, 6 HOURS, RAT):
0/10 DIED.
===================== Ecological Information =====================
Ecological:THIS MATERIAL IS A STRONGLY ACIDIC AQUEOUS SOLUTION AND
EXPECTED TO HAVE THE FOLLOWING PROPERTIES: A LOW BIOCHEMICAL OXYGEN
DEMAND, A LITTLE POTENTIAL TO CAUSE OXYGEN DEPLETION IN AQUEOUS
SYSTEMS, A H IGH POTENTIAL TO AFFECT SECONDARY WASTE TREATMENT
MICROBIAL METABOLISM, A MODERATE POTENTIAL TO AFFECT GERMINATION
AND/OR EARLY GROWTH OF SOME PLANTS, A LOW POTENTIAL TO PERSIST IN
THE ENVIRONMENT, A LOW POTENTIAL TO BIOCONCENTRATE. AFTER DILUTION
WITH A LARGE AMOUNT OF WATER, FOLLOWED BY SECONDARY WASTE
TREATMENT, THIS MATERIAL IS NOT EXPECTED TO CAUSE ADVERSE
ENVIRONMENTAL EFFECTS.
==================== Disposal Considerations ====================
Waste Disposal Methods:CONTRACT WITH A LICENSED CHEMICAL DISPOSAL
AGENCY.
=================== MSDS Transport Information ===================
Transport Information:FOR TRANSPORTATION INFORMATION REGARDING THIS
PRODUCT CALL THE KODAK WORLDWIDE TRANSPORTATION HAZMAT HOT LINE:
(716) 722-2400 BETWEEN 8 A.M. AND 5 P.M. (EASTERN STANDARD TIME),
MONDAY THROUGH FRIDAY.
===================== Regulatory Information =====================
SARA Title III Information:CHEMICAL(S) SUBJECT TO THE REPORTING
REQUIREMENTS OF SECTION 313 OF TITLE III OF THE SUPERFUND
AMENDMENTS AND REAUTHORIZATION ACT (SARA) OF 1986 AND 40 CFR PART
372: NONE.
Federal Regulatory Information:NOT PROVIDED
State Regulatory Information:MATERIAL(S) KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER: NONE. MATERIAL(S) KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE ADVERSE REPRODUCTIVE EFFECTS: NONE.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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