===================== Product Identification =====================
MSDS NAME:ALUMINUM SULFATE, LIQUID
Status Code:A
MSDS Number: CLRJM
=== Responsible Party ===
Company:C&R INDUSTRIES, INC. SUB OF C&S CHEMICALS, INC.
Address:1306 MCKINLEY AVENUE
Box:2877
City:JOLIET
State:IL
ZIP:60434-2877
Country:US
Info Phone Num:815-722-6671
Emergency Phone Num:800-424-9300
Chemtrec Ind/Phone:(800)424-9300
CAGE:UO345
=== Contractor Identification ===
Company:C&R INDUSTRIES, INC. SUB OF C&S CHEMICALS, INC.
Address:1306 MCKINLEY AVENUE
Box:2877
City:JOLIET
State:IL
ZIP:60434-2877
Country:US
Phone:815-722-6671
CAGE:UO345
============= Composition/Information on Ingredients =============
Name:ALUMINUM SULFATE
CAS:10043-01-3
RTECS #:BD1700000
> Wt:50.
OSHA PEL:2 MG/M3
ACGIH TLV:2 MG/M3
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:ACUTE ORAL (RAT) LD50 1,900 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:INHALATION: INHALATION OF ALUM MIST
MAY IRRITATE RESPIRATORY TRACT. INGESTION: MAY IRRITATE
GASTROINTESTINAL TRACT. CONCENTRATED SOLUTIONS MAY CAUSE BURNS TO
THE DIGESTIVE TRACT. EYES: MAY CAUSE STRON G IRRITATION OR BURNING
OF THE EYES. SKIN: MAY CAUSE MILD SKIN IRRITATION.
Explanation of Carcinogenicity:ALUMINUM SULFATE 010043-01-3>50 TPQ(LBS)
NONE 5000 DEFINED AS TOXIC CHEMICALS SUBJECT TO REPORTING
REQUIREMENTS OF SECTION 313 OF TITLE III AND OF 40 CFR 372 OR
SUBJECT TO OTHER EPA REGULATIONS.
Effects of Overexposure:ACUTE OVEREXPOSURE TO ALUMINUM SULFATE DUST MAY
CAUSE IRRITATION TO THE RESPIRATORY TRACT.
======================= First Aid Measures =======================
First Aid:EYE: IMMEDIATELY IRRIGATE WITH PLENTY OF WATER FOR 15
MINUTES. FLUSH IMMEDIATELY WITH PLENTY OF WATER, NO LESS THAN 15
MINUTES. IF IRRITATION PERSISTS, SEEK MEDICAL ATTENTION. SKIN:
FLUSH WITH PLENTY OF WATER. REMOVE CONTAMINATED CLOTHING, WASH
SKIN WITH SOAP AND WATER. IF IRRITATION PERSISTS, SEEK MEDICAL
ATTENTION. INHALATION: PROMPTLY REMOVE TO FRESH AIR. INGESTION:
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. IMMEDIATELY
GIVE TO A CONSCIOUS PERSON LARGE QUANTITIES OF MILK OR WATER.
INDUCE VOMITING BY TOUCHING FINGER TO BACK OF THROAT. GET IMMEDIATE
MEDICAL ASSISTANCE.
===================== Fire Fighting Measures =====================
Flash Point Method:SCC
Flash Point:>93.3C, 200.F
Extinguishing Media:USE WATER SPRAY, CARBON DIOXIDE OR DRY CHEMICAL TO
EXTINGUISH FIRES. USE WATER TO KEEP CONTAINERS COOL.
Fire Fighting Procedures:WEAR SELF-CONTAINED, POSITIVE PRESSURE
BREATHING APPARATUS.
================== Accidental Release Measures ==================
Spill Release Procedures:LARGE SPILLS: DIKE UP WITH SODA ASH, AND
NEUTRALIZE AND SO FORTH AS DESCRIBED IN "OTHER INFORMATION"
SECTION.
Neutralizing Agent:SODA ASH
====================== Handling and Storage ======================
Handling and Storage Precautions:AVOID CONTACT WITH EYES, SKIN, AND
CLOTHING. WASH THOROUGHLY AFTER HANDLING. PREVENT MATERIAL FROM
COMING IN CONTACT WITH COMMON METALS.
Other Precautions:NFPA HAZARD RATING. FIRE: MATERIALS THAT WILL NOT
BURN. HEALTH-1, REACTIVITY-0. FIRE-MATERIALS THAT WILL NOT BURN.
SPECIAL-NOT FOR FOOD OR DRUG USE UNLESS MARKED AS SUCH.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WHERE EXPOSURES ARE BELOW THE PERMISSIBLE
EXPOSURE LIMIT (PEL), NO RESPIRATORY PROTECTION IS REQUIRED. WHERE
EXPOSURES EXCEED THE PEL, USE RESPIRATOR APPROVED BY NIOSH FOR THE
MATERIAL AND LEVEL OF EX POSURE. SEE GUIDE TO INDUSTRIAL
RESPIRATORY PROTECTION (NIOSH).
Ventilation:ADEQUATE VENTILATION
Protective Gloves:IMPERVIOUS GLOVES RECOMMENDED.
Eye Protection:CHEMICAL SPLASH PROOF GOGGLES OR FACE SHIELD.
Other Protective Equipment:IMPERVIOUS GLOVES AND APRONS ARE RECOMMENDED
TO PREVENT SKIN CONTACT. ,
Work Hygienic Practices:BEFORE EATING, DRINKING, OR SMOKING, WASH FACE
AND HANDS THOROUGHLY WITH SOAP AND WATER. AVOID UNNECESSARY SKIN
CONTACT.
Supplemental Safety and Health
PRODUCT NAME: ALUMINUM SULFATE, LIQUID. SYNONYMS: LIQUID ALUM,
PAPERMAKERS ALUM. CAS NO.: 010043-01-3. CHEMICAL FAMILY: INORGANIC
SALT. MOLECULAR WEIGHT: ~590. HEALTH-1, FLAMMABILITY-0,
REACTIVITY-0, PERSONAL PROTECTION-X.
================== Physical/Chemical Properties ==================
HCC:V7
Boiling Pt:=101.1C, 214.F
Melt/Freeze Pt:M.P/F.P Text:NOT AVAILABLE
Vapor Pres:SIMILAR TO WATER
Spec Gravity:1.32-1.35
Evaporation Rate & Reference:SIMILAR TO WATER
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR,AMBER,LGHT GREEN,LIGHT BLUE/GREEN-BLUE LIQUID
W/FAINT SHARP ODOR/ NO ODOR
Percent Volatiles by Volume:66-69 WT
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ALUM CORRODES IRON AND ALUMINUM. THIS PRODUCT IS INCOMPATIBLE WITH
ALKALIES.
Stability Condition to Avoid:IF EVAPORATED TO DRYNESS, RESIDUE SHOULD
NOT BE EXPOSED TO TEMPERATURES ABOVE 760C (1400F). THESE YIELD
TOXIC AND CORROSIVE GASES.
Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY PRODUCE
SULFUR DIOXIDE OR SULFUR TRIOXIDE.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
=================== Toxicological Information ===================
Toxicological Information:TOXICOLOGICAL INFORMATION ON THE OSHA
REGULATED COMPONENTS OF THIS PRODUCT IS AS FOLLOWS: THE ACUTE ORAL
(RAT) LD50 VALUE FO ALUMINUM SULFATE IS 1,900 MG/KG. ACUTE
OVEREXPOSURE TO ALUMINUM SULFATE MAY PRODUCE SKIN AND EYE
IRRITATION. INHALATION OVEREXPOSURE TO ALUMINUM SULFATE DUSTS MAY
CAUSE IRRITATION TO THE RESPIRATORY TRACT.
===================== Ecological Information =====================
Ecological:NO AQUATIC LC50, BOD OR COD DATA AVAILABLE. OCTANOL/H2O
PARTITION COEF: NT AVAILABLE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSAL MUST BE MADE IN ACCORDANCE WITH
APPLICABLE GOVERNMENTAL REGULATIONS.
=================== MSDS Transport Information ===================
Transport Information:D.O.T SHIPPING INFORMATION: SHIPPING NAME: OTHER
REGULATED SUBSTANCES. HAZARD CLASS: 9. PACKING GROUP: III. UN
NUMBER: 3082. IMDG PAGE: NOT APPLICABLE. D.O.T. HAZARDOUS
SUBSTANCES: (PROUDCT REPORTABLE QUANTITY) ALUMINUM SULFATE (10,000
LBS). TRANSPORT LABEL REQUIRED: 3082 ON WHITE SQUARE OR 3082 ON
POINT PANELS OR ORANGE PANELS. EXAMPLES: ENVIRONMENTALLY HAZARDOUS
SUBSTANCES, LIQUID, NOS, 9, UN 30 82, PG III (ALUMINUM SULFATE,
SOLUTION) OR OTHER REGULATED SUBSTANCES, LIQUID, NOS, NA 3082, PG
III (ALUMINUM SULFATE, SOLUTION).
===================== Regulatory Information =====================
SARA Title III Information:THE FOLLOWING COMPONENTS ARE DEFINED AS
TOXIC CHEMIALS SUBJECT TO REPORTING REQUIREMENTS OF SECTION 313 OF
TITLE III AND OF 40 CFR 372 OR SUBJECT TO OTHER EPA REGULATIONS.
ALUMINUM SULFATE, 010043-01- 3, TPQ(LBS)-NONE, RQ(LBS)-5000,
S313-NONE, RCRA-NONE, TSCA 12B-NO. PRODUCT CLASSIFICATION UNDER
SECTION 31 OF SARA.
Federal Regulatory Information:US TSCA: THIS PRODUCT IS MANUFACTURER IN
COMPLIANCE WITH ALL PROVISIONS OF THE TOXIC SUBSTANCE CONTROL ACT,
15 U.S.C.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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