===================== Product Identification =====================
MSDS NAME:NANOCHEM(R) HPB (HBR-CONDITIONED)
MSDS Number: EEEKM
Kit Part:=== Responsible Party ===
Company:MATHESON TRI-GAS, INC.
Address:959 ROUTE 46 EAST
City:PARSIPPANY
State:NJ
ZIP:07054-0624
Country:US
Info Phone Num:(USA) 973-257-1100, (WHITBY) 905-668-3570, (EDMONTON)
780-471-4036
Chemtrec Ind/Phone:18004249300
=== Contractor Identification ===
Company:MATHESON TRI-GAS, INC.
Address:959 ROUTE 46 EAST
Box:City:PARSIPPANY
State:NJ
ZIP:07054-0624
Country:US
Phone:(USA) 973-257-1100, (WHITBY) 905-668-3570, (EDMONTON)
780-471-4036
CAGE:Company:MATHESON TRI-GAS, INC.
Address:530 WATSON STREET
Box:City:WHITBY
State:ZIP:L1N 5R9
Country:ONTARIO, CANADA
Phone:(USA) 973-257-1100, (WHITBY) 905-668-3570, (EDMONTON)
780-471-4036
CAGE:
============= Composition/Information on Ingredients =============
Name:METAL OXIDES, TRADE SECRET
Fraction by Wt: 75-95%
Name:METAL BROMIDES, TRADE SECRET
Fraction by Wt: 5-20%
Name:ABSORBED HYDROGEN BROMIDE ON COMPOUND
CAS:10035-10-6
Fraction by Wt: 0-10%
Name:HYDROGEN BROMIDE VAPOR (CANISTER HEAD SPACE)
CAS:10035-10-6
Fraction by Wt: <0.1%
===================== Hazards Identification =====================
Reports of Carcinogenicity:NTP:No IARC:No OSHA:No
Medical Cond Aggravated by Exposure:
======================= First Aid Measures =======================
First Aid: INHALATION: It is unlikely that emergency treatment will be
required. However, in case of contact with media remove to fresh
air. If breathing has stopped, give artificial respiration. If
breathing is difficult, give oxygen. Get medical attention
immediately. SKIN CONTACT: It is unlikely that emergency treatment
will be required. However, in case of contact with media promptly
wash with soap and running water. Remove contaminated clothing.
Wash clothing before reuse. If burns occur, cover affected area
securely with sterile, dry, loose-fitting dressing. Treat
symptomatically and supportively. Get medical attention
immediately. EYE CONTACT: It is unlikely that emergency treatment
will be required. However, in case of contact with compound,
immediately flush with plenty of low pressure water for at least 20
minutes. Remove any contact lenses to ensure thorough flushing.
Call a physician. In case of contact with hydrogen bromide vapors,
wash eyes immediately with large amounts of water, occasionally
lifting upper and lower lids, until no evidence of chemical remains
(at least 15-20 minutes). Continue irrigating with normal saline
until ready to transport to hospital. Cover both eyes with sterile,
dry bandages. Treat symptomatically and supportively. Get medical
attention immediately. INGESTION: The system is sold as a sealed
unit and exposure to the compound via ingestion is not expected. If
ingestion does occur, call a physician. Avoid gastric lavage or
emesis. Give large amounts of water or milk. Repeat if vomiting
occurs. Never make an unconscious person vomit or drink fluids. If
vomiting occurs, keep head lower than hips to help prevent
aspiration. Maintain airway and respiration. Treat symptomatically
and supportively. Get medical attention immediately.
===================== Fire Fighting Measures =====================
Extinguishing Media:Use extinguishing agents appropriate for
surrounding fire.
Fire Fighting Procedures:Move container from fire area if it can be
done without risk. Avoid inhalation of material or combustion
by-products. Stay upwind and keep out of low areas.
Unusual Fire/Explosion Hazard:Negligible fire hazard as long as the
container is not punctured or a wrong gas such as pure oxygen is
not accidentally piped to the canister.
================== Accidental Release Measures ==================
Spill Release Procedures:Collect spilled material in appropriate
container for disposal.
Neutralizing Agent:
====================== Handling and Storage ======================
Handling and Storage Precautions:Store and handle in accordance with
all current regulations and standards. See original container for
storage recommendations. Keep separated from incompatible
substances.
Other Precautions:
============= Exposure Controls/Personal Protection =============
Respiratory Protection:Not required during normal system use. In the
event of system rupture, media removal from the system, or exposure
to the media: The following respirators and maximum use
concentrations are drawn from NIOSH and/or OSHA. 30 ppm Any
supplied-air respirator. Any powered, air-purifying respirator with
acid gas cartridge(s). Any air-purifying respirator with a full
facepiece and an acid gas canister. Any self-contained breathing
apparatus with a full facepiece. Any supplied-air respirator with a
full facepiece. Escape - Any air-purifying respirator with a full
facepiece and an acid gas canister. Any appropriate escape-type,
self-contained breathing apparatus. For Unknown Concentrations or
Immediately Dangerous to Life or Health - Any supplied-air
respirator with full facepiece and operated in a pressure-demand or
other positive-pressure mode in combination with a separate escape
supply. Any self-contained breathing apparatus with a full
facepiece.
Ventilation:Not required during normal system use. In the event of
system rupture, media removal from the system, or exposure to the
media: Provide local exhaust ventilation system. Ensure compliance
with applicable exposure limits.
Protective Gloves:Not required during normal system use. In the event
of system rupture, media removal from the system, or exposure to
the media: Wear appropriate chemical resistant gloves.
Eye Protection:Not required during normal system use. In the event of
system rupture, media removal from the system, or exposure to the
media: Wear splash resistant safety goggles with a faceshield.
Provide an emergency eye wash fountain and quick drench shower in
the immediate work area.
Other Protective Equipment:Not required during normal system use. In
the event of system rupture, media removal from the system, or
exposure to the media: Wear appropriate chemical resistant
clothing.
Supplemental Safety and Health
HYDROGEN BROMIDE: 3 ppm (10 mg/m3) OSHA TWA 3 ppm (10 mg/m3) OSHA
ceiling (vacated by 58 FR 35338, June 30, 1993) 3 ppm ACGIH ceiling
3 ppm (10 mg/m3) NIOSH recommended ceiling
================== Physical/Chemical Properties ==================
Boiling Pt:Not applicable
Vapor Pres:negligible
Vapor Density:Not applicable
Spec Gravity:0.7-0.8
pH:acidic in solution
Evaporation Rate & Reference:Not applicable
Solubility in Water:almost insoluble
Appearance and Odor:PHYSICAL STATE:solid PHYSICAL FORM:Tan pellets
(compound) encased in a stainless steel cylinder (canister)
pressurized with an inert gas. ODOR:odorless
Corrosion Rate:
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:Stable at normal temperatures
and pressure. Heat may result in release of adsorbed hydrogen
bromide. Generates heat upon contact with water and other
adsorbents.
Stability Condition to Avoid:None reported.
Hazardous Decomposition Products:Thermal decomposition products or
contact with water or moisture: oxides of bromine Thermal
decomposition products or contact with water or moisture: oxides of
bromine
Conditions to Avoid Polymerization:Will not polymerize.
=================== Toxicological Information ===================
Toxicological Information:HYDROGEN BROMIDE: TOXICITY DATA: 2858 ppm/1
hour(s) inhalation-rat LC50 LOCAL EFFECTS: Corrosive: inhalation,
skin, eye, ingestion ACUTE TOXICITY LEVEL: Moderately Toxic:
inhalation
===================== Ecological Information =====================
Ecological:Not available
==================== Disposal Considerations ====================
Waste Disposal Methods:Dispose in accordance with all applicable
regulations. If the purification system is ever exposed to toxic
gases or gases containing toxic elements, the media may contain
these toxic materials, or reaction products thereof, and exhibit
the characteristic of toxicity as defined in the hazardous waste
regulations 40 CFR 261 Subpart C or D. System Recharge: The
customer may consult Matheson PBU for the disposal and recharge of
the system. Systems used to purify reactive or flammable gases must
be thoroughly purged with an inert gas prior to disposal.
=================== MSDS Transport Information ===================
Transport Information:U.S. DEPARTMENT OF TRANSPORTATION: No
classification assigned.
===================== Regulatory Information =====================
SARA Title III Information: SARA TITLE III SECTION 302 EXTREMELY
HAZARDOUS SUBSTANCES (40 CFR 355.30): Not regulated. SARA TITLE
III SECTION 304 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355.40): Not
regulated. SARA TITLE III SARA SECTIONS 311/312 HAZARDOUS
CATEGORIES (40 CFR 370.21): ACUTE: Yes CHRONIC: No FIRE: No
REACTIVE: No SUDDEN RELEASE: No SARA TITLE III SECTION 313 (40
CFR 372.65): Not regulated.
Federal Regulatory Information:CERCLA SECTIONS 102a/103 HAZARDOUS
SUBSTANCES (40 CFR 302.4): Not regulated. OSHA PROCESS SAFETY
(29CFR1910.119): HYDROGEN BROMIDE: 5000LBSTQ
State Regulatory Information: California Proposition 65: Not regulated.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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