===================== Product Identification =====================
MSDS NAME:SULFURIC ACID (37.47% TO 100%)
NIIN:00D000015
MSDS Number: BBCBX
=== Responsible Party ===
Company:ALLIED CHEMICAL CORP
Address:COLUMBIA RD & PARK AVE
Box:1087R
City:MORRISTOWN
State:NJ
ZIP:07960
Country:US
CAGE:1L168
=== Contractor Identification ===
Company:ALLIED CHEMICAL COMPANY
Box:1087R
CAGE:1L168
Company:ALLIED-SIGNAL INC
Address:Box:2332R
City:MORRISTOWN
State:NJ
ZIP:07962-2332
Country:US
Phone:201-455-4414
CAGE:1L164
============= Composition/Information on Ingredients =============
Name:SULFURIC ACID (SARA III)
CAS:7664-93-9
RTECS #:WS5600000
Fraction by Wt: <100%
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3; 9192
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
===================== Hazards Identification =====================
Effects of Overexposure:CAUSE SEVERE BURNS TO SKIN/EYES. INHAL:OF MIST
FROM HOT ACID CAN BE INJUROUS TO LUNGS.
======================= First Aid Measures =======================
First Aid:SKIN/EYES:FLUSH WITH WATER FOR 15 MIN. GET DR. DO NOT USE
OILS OR OINTMENTS IN EYES; TREAT SKIN BURNS. INGEST:HAVE VICTIM
DRINK WATER IF POSSIBLE
===================== Fire Fighting Measures =====================
Extinguishing Media:SUITABLE DRY CHEM.,IF FIRE INVOLVES SMALL
AMT.COMBUSTIBLE
Fire Fighting Procedures:USE A GAS MASK W/H*2SO*4 ABSORBING CANISTER
APPRVD BUR.MINES
Unusual Fire/Explosion Hazard:H*2SO*4 REACTS W/STEEL & MANY COMMON
METALS TO PRODUCE H*2 GAS WHICH CAN BE A FIRE & EXPL.HAZARD.
================== Accidental Release Measures ==================
Spill Release Procedures:COVER WITH SODIUM CARBONATE OR AN EQUAL
MIXTURE OF SODA ASH & SLAKED LIME.AFTER MIXING,ADD WATER IF
NECESSARY TO FORM A SLURRY.SODA ASH & LIMESTONE WILL RELEASE CO*2
GAS REQUIRING ADEQUATE VENTILATION .
====================== Handling and Storage ======================
Handling and Storage Precautions:FLAMMABLE H*2 GAS IS GENERATED IN
STEEL DRUMS & TANKS CONTAINING H*2SO*4.SMOKING,OPEN LIGHTS OR
SPARKS MUST NOT BE PERMITTED IN SUCH CASES.
Other Precautions:WHEN DILUTING,ALWAYS ADD THE ACID TO THE WATER
CAUTIOUSLY W/AGITATION CONSIDERABLE HEAT IS DEVELOPED.UNNEUTRALIZED
ACID MUST NOT CONTACT SULFIDE WASTES(SEWERS).DO NOT STORE NEAR
NITRATES,CARBS
============= Exposure Controls/Personal Protection =============
Respiratory Protection:INDUSTRIAL CANISTER TYPE GAS MASK APPROVED BY
U.S.BUREAU OF MINES.
Ventilation:LOCAL EXHAUST AS REQUIRED TO REMOVE ANY MISTS OF TOXIC
GASES
Protective Gloves:RUBBER
Eye Protection:CHEMICAL SAFETY GOGGLES
Other Protective Equipment:FACE SHIELDS AS NECESSARY,RUBBER
APRONS,RUBBER SAFETY SHOES.
Supplemental Safety and Health
ITEM HAS A COMPOSITION RANGE OF 37.47% - 100% H*2,SO*4
================== Physical/Chemical Properties ==================
HCC:C1
Boiling Pt:B.P. Text:233F-625F.
Vapor Pres:0.0
Spec Gravity:1.3-2
Evaporation Rate & Reference:<1,ETHER
Solubility in Water:COMPLETE
Appearance and Odor:SLIGHTLY VISCOUS,CLEAR TO SLIGHTLY CLOUDY LIQ-NONE
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
CONTACT W/COMBUSTIBLES,NITRATES,CARBIDES,CHLORATES,METL.PWDS
Hazardous Decomposition Products:SULFUR TRIOXIDE GAS.
==================== Disposal Considerations ====================
Waste Disposal Methods:ADD SLOWLY TO A LARGE AMT OF SOLUTION OF SODA
ASH & SLAKED LIME BY STIRRING. FLUSH TO AN APPROVED DISPOSAL AREA
W/PLENTY OF WATER AS PERMITTED BY LOCAL & STATE REGULATIONS.IN SOME
CASES,WASTE MAY HAV E TO BE HAULED AWAY BY A DISPOSAL CONTRACTOR.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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