===================== Product Identification =====================
MSDS NAME:PHENOL
NIIN:00N010990
MSDS Number: BHVLP
=== Responsible Party ===
Company:NATIONAL STARCH AND CHEMICAL CORPORATION
Address:FINDERNE AVENUE
Box:6500
City:BRIDGEWATER
State:NJ
ZIP:08807
Info Phone Num:201-685-5000
Emergency Phone Num:201-685-5000
CAGE:85091
=== Contractor Identification ===
Company:NATIONAL STARCH AND CHEMICAL CORP
Address:10 FINDERNE AVE
Box:6500
City:BRIDGEWATER
State:NJ
ZIP:08807
Country:US
Phone:908-685-5379; FAX:908685-5306
CAGE:85091
============= Composition/Information on Ingredients =============
Name:PHENOL
CAS:108-95-2
RTECS #:SJ3325000
Fraction by Wt: 100%
Other REC Limits:N/K
OSHA PEL:5 PPM SKIN
ACGIH TLV:5 PPM SKIN
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:FIRST AID PROC:(1:4 W/ H*2O).GET MED ATTN
IMMED.INHAL:REMOVE TO FRESH AIR.IF NOT BRTHG GIVE ARTF RESP/O*2.GET
MED ATTN.
RTECS #:9999999ZZ
Other REC Limits:N/K
OSHA PEL:N/K
ACGIH TLV:N/K
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50 ORAL RAT 384 MG/KG.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and
Chronic:CORROSIVE,NEUROTOXIN,CONVULSANT,NARCOTIC,HIGHLY
TOXIC,SENSITIZER.EXCESSIVE EXPOSURE MAY CAUSE EXTENSIVE LIVER &
KIDNEY DAMAGE,WHICH COULD BE FATAL.ACUTE EXPOSURE MAY CAUSE DEATH
FROM RESPIRATORY FAILU RE.EYE CONTACT MAY RESULT IN BLINDNESS.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:EYES:CORR,IRRIT,SEV IRISITIS,LID
DMG,CONJ,REDNESS,BLURRED VISION.SKIN:IRRIT,BURNS,DERM,SENSIT.SKIN
ABSORB/INGEST/INHAL:SEV
IRRIT,THIRST,NAUSEA,VOMIT,DIARRHEA,STUPOR,HYPERPNEA,ABDOMINAL
PAIN,CONVL,COMA ,PULMONARY EDEMA,RESP
FAILURE,JAUNDICE,OLIGURIA,NERVOUS DISORDERS,LIVER/KIDNEY
DAMAGE,DEATH.
Medical Cond Aggravated by Exposure:N/K
======================= First Aid Measures =======================
Eyes:WASH IMMED W/ LRG AMTS OF H*2O 15-20 MIN,OCCAS LIFT
LIDS.GET MED ATTN IMMED.SKIN:REMOVE CONTAM CLTHG IMMED.WASH W/
SOAP/MILD DETERGENT,LRG AMTS H*2O AT LEAST 15-20 MIN.BURNS-USE
STERILE,DRY DRESS ING,BANDAGE SECURE/NOT TIGHT.GET MED ATTN
IMMED.INGEST:IF CONSCIOUS/NO CORR INJURY MED PERS ONLY USE GASTRIC
LAVAGE/EMESIS/ACTIVATED CHARCOAL/60 ML CASTOR OIL/30-60 ML FLEETS
PHOSPHO-SODA (SEE ING 2)
===================== Fire Fighting Measures =====================
Flash Point Method:CC
Flash Point:174F,79C
Lower Limits:8.6%
Upper Limits:1.7%
Extinguishing Media:DRY CHEMICAL,CO*2,WATER SPRAY/FOAM.LARGER
FIRE:WATER SPRAY,FOG/FOAM.ALCOHOL FOAM.USE FLOODING AMTS OF WATER
FOG.
Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA,FULL PROT EQUIP
,FULL FACEPIECE IN PRESS DEMAND/POS PRESS MODE.MOVE CONTR FROM AREA
IF POSS.AVOID BRTHG DUST/FUME.KEEP UPWIND.
Unusual Fire/Explosion Hazard:MOD FIRE HAZ IN HEAT/FLAME.VAP-AIR MIX
EXPLO ABOVE FL PT.VAP HEAVIER THAN AIR,TRAVEL LONG DIST/IGNITE/FL
BACK.AUTOIGNIT:1319F,715C.HAZ DECOMP PROD:SMOKE,FUMES.
================== Accidental Release Measures ==================
Spill Release Procedures:AVOID CONT.STOP LEAK IF SAFE.REDUCE VAP W/
H*2O SPRAY.SML-TAKE UP W/ SAND,OTHER ABSORB;PUT IN CONTR.SML
DRY-SHOVEL INTO CLEAN,DRY CONTR;COVER.REMOVE FROM AREA.LRG-DIKE FAR
AHEAD.KEEP UNNEC PERS AWAY.I SOLATE AREA/DENY ENTRY.VENT CLSD
SPACE.
Neutralizing Agent:N/K
====================== Handling and Storage ======================
Handling and Storage Precautions:MUST BE STORED AWAY FROM
HEAT,FIRE,FLAMES,SOURCES FOR SPARKS & MOISTURE,PREFERABLY IN A
COOL,DRY PLACE.KEEP CONTAINERS TIGHTLY CLOSED.
Other Precautions:N/K
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .
Ventilation:LOCAL AND GENERAL VENTILATION NECESSARY TO KEEP AIR
CONCENTRATION BELOW TLV .
Protective Gloves:APPROPRIATE PROTECTIVE
Eye Protection:CHEM WORK GOGG & FACESHIELD.
Other Protective Equipment:APPROPRIATE PROTECTIVE (IMPERVIOUS) CLOTHING
& EQUIPMENT.EYE-WASH FOUNTAIN WITHIN IMMEDIATE WORK AREA.
Work Hygienic Practices:N/K
Supplemental Safety and Health
SOLV SOL:ALCOHOL,ETHER.ODOR THRESHOLD:0.05 PPM.MATL TO
AVOID:1,3-BUTADIENE,BORONTRIFLUORIDE DIETHYL ETHER COMPLEX;STRONG
OXIDIZERS;PEROXODISULFURIC/PEROXOMONOSULFURIC ACID;REDUCING
AGENTS;SODIUM NITRA TE & TRIFLUOROACETIC ACID;SODIUM
NITRITE.ATTACKS:METALS,PLASTICS,RUBBER,COATINGS.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:359F,182C
Melt/Freeze Pt:M.P/F.P Text:106F,41C
Decomp Temp:Decomp Text:N/K
Vapor Pres:0.36 MMHG
Vapor Density:3.2,AIR=1
Spec Gravity:1.07 (WATER=1)
Evaporation Rate & Reference:<0.01 (BU ACETATE=1)
Solubility in Water:8.4%
Appearance and Odor:COLORLESS TO PINKISH,HYGROSCOPIC CRYSTALLINE SOLID
W/ SHARP,SWEET,TARRY ODOR.
================= Stability and Reactivity Data =================
VIOLENT RXN:ACETALDEHYDE;AL CHLORIDE & NITROBENZENE/NITROMETHANE (UNDER
CO*2) MIX;CA HYPOCHLORITE;FORMALDEHYDE;(SUP DA)
Stability Condition to Avoid:GENERALLY NON-REACTIVE UNDER NORMAL
CONDITIONS,CONTACT W/ STRONG OXIDIZERS MAY CAUSE FIRE & EXPLOSION
HAZARD.
Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY RELEASE
ACRID SMOKE AND IRRITATING FUMES.
Conditions to Avoid Polymerization:HAZARDOUS POLYMERIZATION HAS NOT
BEEN REPORTED TO OCCUR UNDER NORMAL TEMPERATURES AND PRESSURES.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH
FEDERAL,STATE AND LOCAL REGULATIONS .
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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