===================== Product Identification =====================
MSDS NAME:UCARTHERM HEAT TRANSFER FLUID SEE SUPP DATA
NIIN:01-168-2698
MSDS Number: BJDPF
=== Responsible Party ===
Company:UNION CARBIDE CORP
Address:39 OLD RIDGEBURY ROAD
City:DANBURY
State:CT
ZIP:06817
Country:US
Info Phone Num:203-794-2000
Emergency Phone Num:800-UCC-HELP, 304-744-3487
Preparer's Name:PATRICIA L. CODY
CAGE:85926
=== Contractor Identification ===
Company:UNION CARBIDE CORP METALS DIVISION SECTION J-1
Address:OLD RIDGEBURY RD
Box:City:DANBURY
State:CT
ZIP:06817
Country:US
Phone:203-794-2000
CAGE:85926
Company:UNION CARBIDE CORP WELDING AND DIST PRO
CAGE:3P798
============= Composition/Information on Ingredients =============
Name:ETHYLENE GLYCOL (SARA III)
CAS:107-21-1
RTECS #:KW2975000
Fraction by Wt: 94%
OSHA PEL:C 50 PPM
ACGIH TLV:C 50 PPM,VAPOR; 9192
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Name:POTASSIUM HYDROXIDE (SARA III)
CAS:1310-58-3
RTECS #:TT2100000
Fraction by Wt: 2%
OSHA PEL:C, 2 MG/M3
ACGIH TLV:C 2 MG/M3; 9192
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:PHOSPHORIC ACID (SARA III)
CAS:7664-38-2
RTECS #:TB6300000
Fraction by Wt: 1.5%
Other REC Limits:STEL:3MG/M3
OSHA PEL:1 MG/M3/3 STEL
ACGIH TLV:1 MG/M3/3 STEL; 9192
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:NON-HAZARDOUS PROCESSING ADDITIVES
Fraction by Wt: 2.5%
OSHA PEL:NONE ESTABLISHED
ACGIH TLV:NONE ESTABLISHED
Name:SUP DAT:PRINCIPAL TOX EFFTS OF ETHYLENE GLYCOL,WHEN
SWAL,ARE KIDNEY DMG&METABOLIC ACIDOSIS.ETHANOL IS ANTIDOTAL, & ITS
RTECS #:9999999ZZ
Name:SUP DAT:EARLY ADMIN MAY BLOCK THE FORM OF NEPHROTOXIC
METABOLITES OF ETHYLENE GLYCOL IN THE LIVER.ETHANOL SHOULD BE
RTECS #:9999999ZZ
Name:SUP DAT:GIVEN IV,AS A 5% SOL IN SODIUM BICARBONATE,A RATE
OF ABOUT 10ML ETHANOL PH.DESIRED THERAPEUTIC LEVEL OF ETHANOL
RTECS #:9999999ZZ
Name:SUP DAT:IN BLOOD IS 100MG/DL.HEMODIALYSIS MAY BE
REQD.4-METHYLPYRAZOLE,POTENT INHIBITOR OF ALCOHOL DEHYDROGENASE,HAS
RTECS #:9999999ZZ
Name:SUP DAT:BEEN USED THERAPEUTICALLY TO DECREASE THE METABOLIC
CONSEQUENCES OF ETHYLENE GLYCOL POISONING BEFORE COMA,
RTECS #:9999999ZZ
Name:SUP DAT:SEIZURE,& RENAL FAILURE HAVE OCCURRED (20
MG/KG/DAY).PULM EDEMA WITH HYPOXEMIA HAS BEEN DESCRIBED IN A NUMBER
OF
RTECS #:9999999ZZ
Name:SUP DAT:PATIENTS FOLLOWING POISONING WITH ETHYLENE
GLYCOL.MECHANISM PROD HAS'T BEEN ELUCIDATED,IT APPEARS
NONCARDIOGENIC
RTECS #:9999999ZZ
Name:SUP DAT:IN ORIGIN IN SEVERAL CASES.RESP SUPP W/MECH
VENT&POS END-EXPIRATORY PRESS MAY BE REQD.THERE MAY BE CRANIAL
NERVE
RTECS #:9999999ZZ
Name:SUP DAT:INVOLV IN LATE STAGES OF TOXICITY FROM SWALLOWED
ETHYLENE GLYCOL.EFFTS REPTD INVOLVING SEVENTH,EIGHTH& NINTH
RTECS #:9999999ZZ
Name:SUP DAT:CRANIAL NERVES,BILATERAL FACIAL PARAL,DIMIN HEAR &
DYSPHAGIA.
RTECS #:9999999ZZ
Other REC Limits:NONE SPECIFIED
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INGEST:ABDOM
PAIN,NAUS,VOMIT,DIZZ,DROW, MALAISE,BLURRED VISION,IRRIT,LUMBAR
PAIN,OLIGURIA,UREMIA,AND CNS EFFECTS- CONVUL,COMA.CARDIAC FAILURE
AND PULM EDEMA.SEV KIDNEY DMG.INHAL:IRRIT NOSE&THROAT W/HD CH.HIGH
VAPOR CONC MAY PRODUCE NAUS,VOMIT,HDCH,DIZZ,IRREG EYE
MOVEMENTS.EYE:DISCOMF W/CONJUNCT.SKIN:NO ADVERSE EFFECTS.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:INHAL OF MIST MAY PRODUCE SIGNS OF CNS
INVOLV,PARTICULARLY DIZZ AND NYSTAGMUS.REPEATED SKIN CONTACT MAY,
IN A VERY SMALL PROPORTION OF CASES,CAUSE SENSIT WITH THE
DEVELOPMENT OF ALLERGIC CONTACT DERMA TITIS.THE INCIDENCE IS
SIGNIFICANTLY LESS THAN 1% WITH THE UNDILUTED MATERIAL.
Medical Cond Aggravated by Exposure:MAY AGGRAVATE EXISTING KIDNEY
DISEASE.
======================= First Aid Measures =======================
First Aid:SKIN:REMOVE CONTAM CLOTHING&FLUSH W/WATER. INHAL:REMOVE TO
FRESH AIR.GET MD IF SYMPTOMS PERSIST.EYES:FLUSH IMMED WITH WATER
FOR SEVERAL MINUTES.INGEST:IF CONSCIOUS, GIVE TWO GLASSES OF WATER
AND INDUC E VOMIT.GET MD IMMED.IF MEDICAL ADVICE IS DELAYED, AND
THE PERSON HAS SWALLOWED MODERATE VOLUMES OF ETHYLENE GLYCOL (A FEW
OUNCES), THEN GIVE THREE TO FOUR OUNCES OF HARD LIQUOR SUCH AS
WHISKEY.
===================== Fire Fighting Measures =====================
Flash Point Method:PMCC
Flash Point:260F,127C
Lower Limits:3.2,INGRED 1
Upper Limits:1.5,INGRED 1
Extinguishing Media:APPLY ALCOHOL OR ALL-PURPOSE TYPE FOAMS BY MFR'S
RECOMND TECHNQ FOR LG FIRES.USE H20,CO2 OR DRY CHEM ON SML FIRES.
Fire Fighting Procedures:DO NOT DIRECT A SOLID STREAM OF WATER OR FOAM
INTO HOT BURNING POOLS; MAY CAUSE FROTHING. USE SCBA AND PROTECTIVE
CLOTHING.
Unusual Fire/Explosion Hazard:NONE
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR SUITABLE PROTECTIVE EQUIPMENT. SMALL
SPILLS SHOULD BE FLUSHED WITH LARGE AMOUNTS OF WATER. LARGE SPILLS
SHOULD BE COLLECTED FOR DISPOSAL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:DO NOT SWALLOW.AVOID CONT WITH
EYES.AVOID BREATHING VAPORS.USE ADEQUATE VENTILATION.WASH
THOROUGHLY AFTER HANDLING. KEEP CONTR CLOSED.AVOID MIST.
Other Precautions:SUDDEN RELEASE OF HOT ORGANIC CHEM VAPORS OR MISTS
FROM PROCESS EQUIP OPERATING AT ELEVATED TEMP OR SUDDEN INGRESS OF
AIR INTO VACUUM EQUIP,MAY IGNITE.ANY USE OF THIS PRODUCT SHOULD BE
THOROUGHLY EVAL UATED TO MAINTAIN SAFE OPER CONDITIONS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR WITH ORGANIC
VAPOR CARTRIDGE AND DUST/MIST PRE-FILTER RECOMMENDED.IF EXCEEDS
EXPOSURE LIMITS SELECT IN ACCORDANCE WITH 29CFR1910.134.
Ventilation:MECH VENT IS EXPECTED TO BE ADEQ IF HANDLED IN COVERED
EQUIP. LOCAL EXHST VENT IS NEEDED AT POINTS WHERE VAPOR IS EXPEC.
Protective Gloves:NATRL RUB, NITRILE, NEOPRENE OR PC.
Eye Protection:MONOGOGGLES OR FACESHIELD.
Other Protective Equipment:EYE BATH AND SAFETY SHOWER.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
MANUFACTURERS PART NUMBER:SYNONYMS PM-6141, PM-6165, PM-6167, PM-6169,
PM-6171, PM-6173, PM-6175
================== Physical/Chemical Properties ==================
HCC:N1
Boiling Pt:B.P. Text:329F,165C
Melt/Freeze Pt:M.P/F.P Text:-13F,-25C
Vapor Pres:1.2 MMHG
Vapor Density:2.1 INGRD1
Spec Gravity:1.133 @ 20/20C
Evaporation Rate & Reference:0.1 BUTYL ACETATE=1
Solubility in Water:BY WEIGHT, 100
Appearance and Odor:YELLOW-GREEN LIQUID; GLYCOL ODOR
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
AVOID STRONG BASES AND ACIDS AT HIGH TEMPS; CONTAM W/ STRONG OXID
AGENTS & MAT REACTIVE W/HYDROXYL CMPDS.
Stability Condition to Avoid:NONE
Hazardous Decomposition Products:BURNING CAN PRODUCE CARBON MONOXIDE
AND/OR CARBON DIOXIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:INCINERATE IN A FURNACE WHERE PERMITTED UNDER
APPROPRIATE FEDERAL, STATE & LOCAL REGS. AT VERY LOW CONC IN H20,
ETHYLENE GLYCOL IS READILY BIODEGRADABLE IN A BIOLOGICAL WASTEWATER
TREATMENT PLANT.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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