===================== Product Identification =====================
MSDS NAME:146 4452 BROWN TONER, CONCENTRATE
NIIN:01-248-7958
MSDS Number: BJDPW
=== Responsible Party ===
Company:EASTMAN KODAK COMPANY
Address:343 STATE STREET
City:ROCHESTER
State:NY
ZIP:14650
Country:US
Info Phone Num:716-477-3194 MSDS :800- 242-2424
Emergency Phone Num:716-722-5151
CAGE:19139
=== Contractor Identification ===
Company:EASTMAN KODAK CO GOVERNMENT MARKETS CONTRACTS
Address:343 STATE ST
Box:City:ROCHESTER
State:NY
ZIP:14650-1115
Country:US
Phone:716-722-5151/(800) 242-2424
CAGE:19139
Company:EASTMAN KODAK CO US CUSTOMER SERVICE/GOVERNMENT SALES
Address:800 LEE RD
Box:City:ROCHESTER
State:NY
ZIP:14650-3129
Country:US
Phone:800-828-6203
CAGE:5K871
============= Composition/Information on Ingredients =============
Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: 70 - 80%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:NOT RELEVANT
ACGIH TLV:NOT RELEVANT
Name:SODIUM CARBONATE
CAS:497-19-8
RTECS #:VZ4050000
Fraction by Wt: 5 - 10%
Other REC Limits:NONE RECOMMENDED
Name:SODIUM HYDROXIDE (CERCLA)
CAS:1310-73-2
RTECS #:WB4900000
Fraction by Wt: <1%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:2 MG/M3
ACGIH TLV:C 2 MG/M3; 9495
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:POTASSIUM POLYSULFIDE/POTASSIUM SULFIDE
CAS:37199-66-9
RTECS #:TT5950000
Fraction by Wt: 15 - 20%
Other REC Limits:NONE RECOMMENDED
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL LD50 (RAT): 0.5-5.0 G/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION OF VAPOR IRRITATING. MAY
CAUSE IRRITATION TO MUCOUS MEMBRANES, UPPER RESPIRATORY TRACT. EYE
CONTACT CAUSES BURNS, VAPOR IRRITATING TO EYES. SKIN CONTACT CAUSES
IRRITATION. HARMFUL IF SWALLO WED.
Explanation of Carcinogenicity:THIS COMPOUND CONTAINS NO INGREDIENTS AT
CONCENTRATIONS OF 0.1% OR GREATER THAT ARE CARCINOGENS OR SUSPECT
CARCINOGENS.
Effects of Overexposure:MUCOUS MEMBRANE IRRITATION, RESPIRATORY TRACT
IRRITATION, HEADACHE, NAUSEA, DIZZINESS, CONFUSION, WEAKNESS,
UNCONSCIOUSNESS, CONVULSIONS, DEATH, EYE BURNS, EYE IRRITATION,
SKIN IRRITATION. IF FREE GAS TRIC ACIDITY IS HIGH, HYDROGEN SULFIDE
IS LIBERATED IN STOMACH AND MAY CAUSE SYSTEMIC TOXIC EFFECTS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INHALATION: IF SYMPTOMATIC, MOVE TO FRESH AIR. GET MEDICAL
ATTENTION IF SYMPTOMS PERSIST. EYES: WASH OUT IMMEDIATELY WITH
WATER. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR. SKIN: WASH WITH
SOAP AND WATER . GET MEDICAL ATTENTION IF SYMPTOMS OCCUR.
INGESTION: INDUCE VOMITING AS DIRECTED BY MEDICAL PERSONNEL. NEVER
GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. CALL PHYSICIAN OR
POISON CONTROL ASAP.
===================== Fire Fighting Measures =====================
Flash Point:NONFLAMMABLE
Lower Limits:NOT GIVEN
Upper Limits:NOT GIVEN
Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, DRY CHEMICAL, ALCOHOL
FOAM.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
PROTECTIVE CLOTHING. FIRE OR EXCESSIVE HEAT MAY PRODUCE HAZARDOUS
DECOMPOSITION PRODUCTS.
Unusual Fire/Explosion Hazard:MAY CAUSE SPONTANEOUS HEATING AND
IGNITION WHEN ABSORBED ON COMBUSTIBLE, POROUS MATERIAL (E.G. RAGS,
PAPER, SAWDUST, COTTON, CLOTHING).
================== Accidental Release Measures ==================
Spill Release Procedures:COLLECT IN A NONCOMBUSTIBLE CONTAINER FOR
PROMPT DISPOSAL. CLEAN SURFACE TO REMOVE RESIDUAL CONTAMINATION.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:DO NOT GET IN EYES AND AVOID CONTACT
WITH SKIN AND CLOTHING. AVOID BREATHING VAPOR. USE WITH ADEQUATE
VENTILATION. KEEP FROM CONTACT WITH OXIDIZERS.
Other Precautions:KEEP CONTAINER TIGHTLY CLOSED. KEEP AWAY FROM
INCOMPATIBLE SUBSTANCES.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE SHOULD BE NEEDED. A FULL-FACE
POSITIVE-PRESSURE AIR-SUPPLIED RESPIRATOR MUST BE WORN IF HAZARDOUS
DECOMPOSITION PRODUCTS ARE LIKELY TO BE RELEASED OR HAVE BEEN
RELEASED.
Ventilation:GOOD GENERAL VENTILATION, TYPICALLY 10 AIR CHANGES PER
HOUR, SHOULD BE USED. RATES SHOULD MATCH CONDITIONS.
Protective Gloves:IMPERVIOUS
Eye Protection:SAFETY GLASSES W/SIDE SHIELDS OR GOGGLES
Other Protective Equipment:CHEMICAL RESISTANT CLOTHING AS NECESSARY TO
PREVENT SKIN CONTACT. AN EMERGENCY EYEWASH AND SHOWER SHOULD BE
AVAILABLE.
Work Hygienic Practices:WASH HANDS THOROUGHLY WITH SOAP AND WATER
BEFORE EATING, DRINKING, SMOKING OR USING TOILET FACILITIES.
Supplemental Safety and Health
REMOVE AND WASH CONTAMINATED CLOTHING BEFORE REUSE.
================== Physical/Chemical Properties ==================
HCC:B3
NRC/State Lic Num:NOT RELEVANT
Boiling Pt:B.P. Text:>212F,>100C
Melt/Freeze Pt:M.P/F.P Text:NOT GIVEN
Vapor Pres:18
Vapor Density:0.6
Spec Gravity:1.23
pH:11.7
Evaporation Rate & Reference:NOT GIVEN
Solubility in Water:COMPLETE
Appearance and Odor:AMBER LIQUID, SULFUR ODOR
Percent Volatiles by Volume:70-80%
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ACIDS, STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE,
OXIDES OF SULFUR, HYDROGEN SULFIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISCHARGE, TREATMENT OR DISPOSAL MAY BE SUBJECT
TO NATIONAL, STATE OR LOCAL LAWS. MAY REQUIRE NEUTRALIZATION IF PH
< 2.0 OR PH > 12.5. DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE
FEDERAL, STATE AND LOCAL REGULATIONS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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