Material Safety Data Sheet
For GreenMatchTM O Organic Concentrate Herbicide
Cutting Edge Formulations, Inc.
5106 Bristol Industrial Way
Buford, GA 30518
August, 2006
MATERIAL SAFETY DATA SHEET
For GreenMatchTM O Concentrate Herbicide
(EPA Reg. No. 82052 鈥? 1)
Emergency Phone Numbers:
Cutting Edge Formulations: (678) 546-5009
CHEMTREC 24 Hour Number (800) 424-9300
Section 1 鈥? IDENTIFICATION
TM
Product Name: GreenMatch O Concentrate Herbicide
Section 2 鈥? INGREDIENT INFORMATION
TM
GreenMatch O Concentrate consists of:
d-Limonene (technical grade): 74 to 78% (CAS Number: 5989-27-5)
Castor Oil: 1 to 4%
Emulsifiers: 18 to 23%
Section 3 鈥揌EALTH HAZARDS IDENTIFICATION
Health Hazards: Harmful if absorbed through skin. Causes moderate eye irritation. Avoid
contact with skin, eyes, or clothing.
Signs and Symptoms of Exposure: Product may be irritating to the skin, eyes, nose and throat.
Medical Conditions Generally Aggravated by Exposure: Persons with allergies or pre-existing
skin conditions should avoid contact with this product.
Emergency & First Aid Procedures :
Eyes: Remove contact lenses at once. Flush with water for at least 15 minutes.
Skin: Wash affected area with copious amounts of soap and water. If irritation develops, seek
medical attention.
Ingestion: Seek medical attention immediately. Do not induce vomiting. Rinse mouth with water,
then drink one glass of water. Do not leave victim unattended. Never give anything by mouth if
victim is unconscious, is rapidly losing consciousness, or is convulsing.
Inhalation: If symptoms of overexposure are experienced, evacuate to fresh air.
If any symptoms persist, seek medical attention.
The toxicity parameters of the primary ingredient, d-Limonene, are as follows:
It is not acutely toxic.
Oral: LD50 >5 g/kg, rabbit
Dermal: LD50 >5 g/kg, rabbit
Skin: The skin irritancy of limonene in guinea pigs and rabbits is considered moderate
and low, respectively.
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Material Safety Data Sheet
For GreenMatchTM O Organic Concentrate Herbicide
Inhalation: LC50 >1000 ppm
Hazardous Materials Identification System - HMIS:
1 Health Hazard - Mild skin irritant
2 Flammability - Flashpoint 122掳 F (50oC), as determined by TAG Closed Cup
0 Reactivity - Stable
G Protection - Safety glasses, gloves
This substance contains no materials subject to the reporting requirements of SARA TITLE III
SECTION 313.
Chronic Toxicity: Not listed as a carcinogen (OSHA, NTP, IARC, or ACGIH)
Ecotoxicological Information: Product may be toxic to aquatic organisms.
Section 4 鈥揚HYSICAL DATA
Appearance: Clear, colorless liquid
Odor: Orange or lemon-lime aroma
Specific Gravity: 0.854 g/ml (53.3 lb/ cu. ft.) at 68oF (20掳C )
Flashpoint: 122oF (50oC), as determined by TAG Closed Cup
pH: aqueous mixture containing 1% v/v of Concentrate has a pH of 4.8 at 73oF (23oC)
Viscosity: 1.50 at 23oC
Section 5 鈥? FIRE AND EXPLOSION HAZARD DATA
Flash Point: 126掳F (52掳C)
Extinguishing Media: Carbon dioxide, foam or dry chemical
Special Fire Fighting Procedures: SCBA recommended. Smother to exclude air. Do not use
water. Handle as an oil fire.
Unusual Fire and Explosive Hazards: Combustible liquid. Keep away from heat, sparks, and
open flame.
Hazardous Decomposition Materials: Smoke may be acrid and the fumes may be irritating.
Burning generates CO, CO , and smoke.
2
Conditions to Avoid for Stability: Avoid temperatures over 122掳 F (50掳C)
Section 6 鈥? SPILL OR LEAK PROCEDURES
-
Steps to be Taken if Material is Released or Spilled: Use protective gloves to avoid skin
contact. Small spills can be wiped up. Large spills should be absorbed by dirt, sand, or other
suitable absorbents for disposal.
Section 7 鈥揝PECIAL PROTECTION INFORMATION
Eye Protection: Safety goggles or glasses suggested.
Skin Protection: Oil resistant gloves.
Appropriate Hygienic Practices: Wash thoroughly after handling. Launder contaminated clothing
before re-use.
Section 8 鈥? SPECIAL PRECAUTIONS
Precautions to be Taken in Handling and Storing: Usual precautions for combustible liquids.
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Material Safety Data Sheet
For GreenMatchTM O Organic Concentrate Herbicide
Section 9 鈥? REGULATORY INFORMATION
Registration for use as a herbicide has been approved at the U.S. Environmental Protection
Agency (EPA). EPA Registration No. 82052 鈥? 1
Section 10 鈥? TRANSPORTATION INFORMATION
TDG Status: Hazardous DOT Label/Placard [exemption 搂 173.150(f) applies:
IMO Status: Hazardous Highway/Rail: per requirements for Combustible Liquids
IATA Status: Hazardous Air/Ship: per requirements for Flammable Liquids
SHIPPING CLASSIFICATION:
Proper Shipping Name: TERPENE HYDROCARBONS, N.O.S.
Hazard Class: 3
Identification No.: UN2319
Packing Group: III
The listed Transportation Classification does not address regulatory variations due to changes in
package size, mode of shipment or other regulatory descriptors.
Section 11 鈥? ADDITIONAL INFORMATION
National Fire Protection Association Hazard Ratings - NFPA(R):
1 Health Hazard - Slight
2 Flammability - Moderate
0 Reactivity - Minimal
Key Legend Information:
ACGIH American Conference of Governmental Industrial Hygienists
OSHA Occupational Safety and Health Administration
NTP National Toxicology Program
IARC International Agency for Research on Cancer 4
The information contained herein is based on current knowledge and experience: no
responsibility is accepted that the information is sufficient or correct in all cases. Users should
consider these data only as a supplement to other information obtained by the user. No warranty
is expressed or implied regarding the accuracy of this data, the results to be obtained from the use
thereof, or that any such use will not infringe any patent. Users should make independent
determinations of suitability and completeness of information from all sources to assure proper
use and disposal of these materials, the safety and health of employees and customers, and the
protection of the environment. This information is furnished upon the condition the person
receiving it shall determine the suitability for the particular purpose. This MSDS is to be used as a
guideline for safe work practices and emergency response.
Cutting Edge Formulations, Inc.
5106 Bristol Industrial Way, Suite 400
Buford, GA 30518
August, 2006
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