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Section 1
MATERIAL SAFETY DATA SHEET # 212
CloroClean
Hercules Chemical Company Inc.
Last Reviewed: 12/2/1999
Date Prepared: 11/17/1999
111 South Street
Passaic NJ 07055
Meets OSHA 29 CFR 1910.1200
Phone (800) 221-9330
Fax (800) 333-3456
Section 2 - Hazardous Ingredients/Identity Information
Hazardous Components (Specific Chemical Identity;
Upper Bound
Common Name(s), CAS Numbers) OSHA PEL ACGIH TLV Other Limits
Limit if SARA
Reportable
Granular caustic and metal cleaning compound.
N/A
Sodium hydroxide (CAS 1310-73-2) 2mg/M鲁 2mg/M鲁
HMIS Hazard Rating: Health: 2 Flammability: 0 Reactivity: 2 Personal Protection: E
Section 3 - Physical/Chemical Characteristics
Boiling Point (掳C): Specific Gravity Vapor Density Vapor Pressure
(H2O = 1): (Air = 1): (mm Hg):
NA 1.20 N/A N/A
Solubility in Water:
Evaporation Rate:
Melting Point (掳 F)
(Butyl Acetate = 1)
Not determ N/A Appreciable: 42g/100cc of
water at 0掳 C.
White to off white granular solid w/gray None.
Appearance And Color: Odor:
granules.
Section 4 - Fire And Explosion Hazard Data
Flash Point: Flammable Limits: LEL: UEL:
N/A N/A
N/A
Extinguishing Media: Product is non-flammable. Use appropriated fire fighting methods for surrounding fire.
Special Firefighting Procedures:
As appropriate for surrounding fire. Carbon dioxide or dry chemical extinguishers preferred if container are open and
product is exposed. See Unusual Hazards.
Unusual Fire And Explosion Hazards:
Hot or molten product will react violently with water, liberating heat and causing splashing. Contact with water can
rapidly generate flammable/explosive hydrogen gas.
Continued on Next Page
Hercules Chemical Material Safety Data Sheet # 212 CloroClean Page 2
Section 5 - Reactivity Data
Stability: Stable Conditions To Avoid: Can react violently with acids and many organic compounds.
Incompatability
(Materials To Avoid):
Hazardous Decomposition: Not determined.
Hazardous Polymerization: Caustic soda & trichloroethylene are especially hazardous since they react to form sponta
Section 6 - Health Hazard Data
Routes of Entry: Inhalation Skin Ingestion
Yes Yes Yes
Health Hazards:
Caustic soda is a corrosive material. Sodium Hydroxide: Acute Oral LD50=140-340 mg/kg (Rat) Acute Dermal LD
50=1.35 gm/kg (Rabbit)
Carcinogenicity: NTP IARC OSHA Regulated
NO NO NO
Signs And Symptoms of Exposure:
INHALATION: Airborne concentrations of dust of caustic soda may cause damage to the upper respiratory tract and
even to the lung tissue proper which could produce chemical pneumonia, depending upon the severity of exposure.
SKIN CONTACT: Caustic soda is destructive to tissues contracted and produces severe burns. EYE CONTACT:
Caustic Soda is destructive to eye tissues on contact. Will cause severe burns that result in damage to the eyes and
even blindness. INGESTION: Caustic soda, if swallowed, can cause severe burns and complete tissue perforation
of mucous membranes of the mouth, throat, esophagus, and stomach.
Medical Conditions Generally Aggravated By Exposure:
EFFECTS OF OVEREXPOSURE -- ACUTE OVEREXPOSURE: Corrosive to all body tissues with which it comes in
contact. CHRONIC OVEREXPOSURE: Chronic local effect may consist of multiple areas of superficial destruction
of the skin or of primary irritant dermatitis. Similarly, inhalation of dust, spray or mist may result in varying degrees of
irritation or damage to the respiratory tract tissues and an increased susceptibility to respiratory illness.
Emergency And First Aid Procedures:
EYES: Object is to flush material out immediately then seek medical attention. Immediately flush eyes with large
amounts of water for at least 15 minutes, holding lids apart to ensure flushing of the entire surface. Washing eyes
within 1 minute is essential to achieve maximum effectiveness. Seek medical attention. SKIN: Wash contaminated
areas with plenty of water. Remove contaminated clothing and footwear and wash clothing before reuse. Discard
footwear which cannot be decontaminated. Seek medical attention immediately. INHALATION: Get person out of
contaminated area to fresh air. If breathing has stopped, resuscitate and administer oxygen if readily available.
Seek medical attention immediately. INGESTION: Never give anything by mouth to an unconscious person. If
swallowed, do not induce vomiting. Give large quantities of water. If available give several glasses of milk. If
vomiting occurs spontaneously, keep airways clear. Seek medical attention immediately.
Continued on Next Page
Hercules Chemical Material Safety Data Sheet # 212 CloroClean Page 3
Section 7 - Precautions For Safe Handling And Use:
Steps To Be Taken In Case Material Is Released Or Spilled:
Get complete protective equipment. Shovel spilled material into steel containers, flush area with ample water, rinse
with dilute acid, preferably acetic acid, and finally with water.
Waste Disposal Method:
Dissolve and/or flush to holding area for pH adjustment and dilute before discharging to sewer or stream. For large
quantities follow state/local regulations.
Precautions To Be Taken In Handling And Storing:
Store in a cool, dry place. Keep separate from acids. Do not allow water to enter container, heat and flammable
hydrogen gas will evolve. Contact with some foods will release carbon monoxide gas.
Other Precautions:
Wear complete protective equipment when handling product in large quantities.
Section 8 - Control Measures:
Respiratory Protection:
Filter or dust type respirator.
Special
Ventilation: Local Exhaust None
Mechanical
Neoprene or vinyl.
Gloves:
N/A
Other:
Eye Protection: Chemical safety goggles plus face shield when
Other Protective
Clothing:
Work/Hygienic Practices Use good personal hygiene practices.
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