MATERIAL SAFETY DATA SHEET
D-SCUM
SECTION 01: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
MANUFACTURER'S NAME : ROCHESTER MIDLAND LIMITED
MANUFACTURERS ADDRESS : 851 PROGRESS COURT
OAKVILLE, ONTARIO
EMERGENCY PHONE NUMBER: CANUTEC (613) 996-6666
SUPPLIER IDENTIFIER: NOT AVAILABLE
SUPPLIER'S ADDRESS: NOT AVAILABLE
SUPPLIER EMERGENCY
PHONE NUMBER: NOT AVAILABLE
PRODUCT NAME : HDA-5600
PRODUCT USE : FOAMING ACID SHOWER CLEANER
WHMIS CATEGORY: E, D2B
PREPARED BY : ROCHESTER MIDLAND LIMITED.
PHONE NUMBER OF PREPARER: (905) 847-3000
DATE PREPARED: MAY 31, 2006
SECTION 02: COMPOSITION / INFORMATION ON INGREDIENTS
HAZARDOUS INGREDIENTS % CAS# EXPOSURE LD (50), ROUTE, LC(50), ROUTE, SPECIES
LEVELS SPECIES
3
PHOSPHORIC ACID 15-40 7664-38-2 ACGIH TLV-TWA ORAL 25.5 mg / m
3
1 mg/ m 3500 mg/ Kg (85% UNSPECIFIED EXPOSURE
TLV-STEL SOL鈥橬) DURATION
3
3 mg/ m (RAT) (MOUSE)
OSHA-TWA DERMAL
3
1 mg/ m >1260 mg/ Kg (85%
STEL SOL鈥橬)
3
3 mg/ m (RABBIT)
3
IDLH : 1000 mg/ m
LAURYL DIMETHYL 1-5 1643-20-5 NOT AVAILABLE ORAL NOT AVAILABLE
AMINE OXIDE 2700 mg/Kg
(MOUSE)
64-17-5 ACGIH TLV-TWA ORAL 21000 ppm
ETHANOL 0.1-1
1000 ppm 7060 mg/Kg 4 HOUR EXPOSURE
NIOSH TLV-TWA (RAT) (MOUSE)
1000 ppm
OSHA PEL-TWA
1000 ppm
OTHER INGREDIENTS % CAS# EXPOSURE LD (50), ROUTE, LC(50), ROUTE, SPECIES
LEVELS SPECIES
ETHOXYLATED LINEAR ALCOHOL ORAL
1-5% 68439-46-3 NOT AVAILABLE NOT AVAILABLE
1378 mg/ Kg
(RAT)
DERMAL
>2000 mg/ Kg
(RABBIT)
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MATERIAL SAFETY DATA SHEET
SECTION 03: HAZARDS IDENTIFICATION
POTENTIAL ACUTE HEALTH EFFECTS:
ROUTE OF ENTRY: EYES, SKIN, INHALATION, INGESTION
SKIN CONTACT: MAY CAUSE SEVERE IRRITATION; PROLONGED OR REPEATED CONTACT MAY CAUSE BURNS.
SKIN ABSORPTION : NOT AVAILABLE.
EYE: WILL CAUSE SEVERE BURNS, PERMANENT EYE DAMAGE EVEN BLINDNESSINHALATION: MAY CAUSE
IRRITATION, TISSUE DAMAGE TO MUCOUS MEMBRANES OF THE NOSE, THROAT AND ESOPHAGUS. NOT
EXPECTED TO PRESENT A SIGNIFICANT INHALATION HAZARD UNDER NORMAL USE CONDITIONS
INGESTION: MAY BE FATAL IF SWALLOWED. WILL CAUSE SEVERE BURNS TO MUCOUS MEMBRANES OF MOUTH, THROAT
AND DIGESTIVE TRACT. ASPIRATION OF VOMITED CONTENTS MAY CAUSE CHEMICAL PNEUMONITIS, WHICH CAN
BE FATAL.
ACUTE OVER-EXPOSURE
EFFECTS: AS ABOVE.
CHRONIC OVER EXPOSURE
EFFECTS: DERMATITIS MAY DEVELOP WITH REPEATED OVEREXPOSURE
SECTION 04: FIRST AID MEASURES
EYES: FLUSH EYES WITH ABUNDANT WATER FOR AT LEAST 20 MINUTES WHILE HOLDING EYELIDS OPEN TO ENSURE
COMPLETE IRRIGATION OF THE ENTIRE EYE CAVITY. GET IMMEDIATE MEDICAL ATTENTION.
SKIN: WASH SKIN WITH SOAP AND WATER FOR AT LEAST 20 MINUTES. REMOVE CONTAMINATED CLOTHING. IF
SYMPTOMS PERSIST, GET MEDICAL ATTENTION.
INHALATION: IF SAFE TO ENTER VICTIMS LOCATION, REMOVE VICTIM TO FRESH AIR. ASSIST BREATHING AS NEEDED. GET
IMMEDIATE MEDICAL ATTENTION.
INGESTION: DO NOT INDUCE VOMITING. IF VICTIM CONSCIOUS, GIVE 1 - 2 GLASSES OF WATER TO DILUTE STOMACH
CONTENTS. GET IMMEDIATE MEDICAL ATTENTION. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS
PERSON.
SECTION 05: FIRE FIGHTING MEASURES
FLASHPOINT AND METHOD OF
DETERMINATION: NONE.
UPPER EXPLOSION LIMIT
(% BY VOLUME): NOT APPLICABLE
LOWER EXPLOSION LIMIT
(% BY VOLUME: NOT APPLICABLE
AUTO-IGNITION TEMPERATURE: NOT AVAILABLE
FLAMMABILITY CLASSIFICATION: NON-FLAMMABLE LIQUID
CONDITIONS OF FLAMMABILITY: NONE
MEANS OF EXTINCTION: AS FOR SURROUNDING FIRE.
SPECIAL FIRE FIGHTING
PROCEDURES: FIREFIGHTERS SHOULD WEAR FULL PROTECTIVE EQUIPMENT AND USE APPROVED SELF
CONTAINED BREATHING APPARATUS. USE WATER SPRAY TO COOL FIRE EXPOSED
CONTAINERS TO PREVENT PRESSURE BUILDUP AND POSSIBLE RUPTURE. DO NOT SPATTER OR
SPLASH PRODUCT.
HAZARDOUS COMBUSTION
PRODUCTS: OXIDES OF CARBON, NITROGEN AND PHOSPHOROUS.
EXPLOSION DATA: AS WITH ANY STRONGLY ACIDIC SOLUTION, CAN REACT WITH 鈥淪OFT鈥? METALS SUCH AS
ALUMINUM AND ZINC GENERATING HYDROGEN GAS. THIS GAS IS FLAMMABLE AND/OR
EXPLOSIVE IN THE PRESENCE OF AN IGNITION SOURCE.
SENSITIVITY TO STATIC
DISCHARGE: NOT SENSITIVE.
SENSITIVITY TO MECHANICAL
IMPACT : NOT SENSITIVE
SECTION 06: ACCIDENTAL RELEASE MEASURES
LEAK AND SPILL
PROCEDURES: EXTINGUISH ALL IGNITION SOURCES. CLEANUP PERSONNEL MUST USE FULL PROTECTIVE EQUIPMENT. REMOVE
UNPROTECTED PERSONNEL AWAY FROM SPILL AREA. VENTILATE AREA. CAUTION: SPILL AREA MAY BE SLIPPERY.
SMALL SPILLS: MOP UP, AND FLUSH AREA WITH WATER.
LARGE SPILLS: DIKE SPILL. DO NOT ALLOW SPILL TO ENTER OPEN WATERWAYS OR SEWERS. RECLAIM ALL MATERIAL POSSIBLE.
ABSORB REMAINDER WITH INERT MATERIAL AND PLACE IN SUITABLE CONTAINERS FOR NEUTRALIZATION AND
DISPOSAL. TRAINED PERSONNEL SHOULD DILUTE AND NEUTRALIZE RESIDUE WITH DILUTED ALKALIS. FLUSH AREA
WITH WATER.
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MATERIAL SAFETY DATA SHEET
SECTION 07: HANDLING AND STORAGE
HANDLING PROCEDURES
AND EQUIPMENT: AVOID CONTACT WITH EYES, SKIN OR CLOTHING. WASH SKIN THOROUGHLY AFTER HANDLING. DO NOT
BREATHE MISTS/ SPRAYS. REMOVE CONTAMINATED CLOTHING AND LAUNDER BEFORE RE-USE KEEP
CONTAINER CLOSED WHEN NOT IN USE. MIX ONLY WITH WATER; ALWAYS ADD PRODUCT TO WATER: NEVER
WATER TO PRODUCT. READ AND FOLLOW LABEL INSTRUCTIONS. DO NOT CONTAMINATE FOOD, WATER OR
FEED DURING USE OR STORAGE OF THIS PRODUCT. DO NOT MIX WITH CHLORINE SANITIZERS (IE BLEACH)
STORAGE
REQUIREMENTS: KEEP CONTAINER CLOSED WHEN NOT IN USE. STORE IN A COOL WELL VENTILATED AREA AWAY FROM
INCOMPATIBLE MATERIALS AND COMBUSTIBLE MATERIALS. KEEP FROM FREEZING. KEEP OUT OF REACH OF
CHILDREN. DO NOT REUSE CONTAINER.
SECTION 08: EXPOSURE CONTROLS/ PERSONAL PROTECTION
EYE PROTECTION: WEAR CHEMICAL SPLASH GOGGLES . USE FACE SHIELD IF SPLASHES POSSIBLE.
RESPIRATORY PROTECTION: USE NIOSH APPROVED RESPIRATOR IF EXPOSURE LIMITS ARE EXCEEDED OR IRRITATION OCCURS.
GLOVES: WEAR BUTYL RUBBER, NEOPRENE OR NITRILE GLOVES .
OTHER PROTECTIVE
EQUIPMENT: AS NEEDED TO PREVENT ALL CONTACT WITH PRODUCT.
SPECIFIC ENGINEERING
CONTROLS鈥︹?︹?︹?︹??. USE GENERAL MECHANICAL AND / OR LOCAL EXHAUST. USE CORROSION PROOF EQUIPMENT.
SECTION 09: PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: LIQUID
ODOUR AND APPEARANCE: PEACH FRAGRANCE 鈥? CLEAR DARK RED LIQUID
ODOUR THRESHOLD: SCENT WILL BE PRESENT IN AIR WHEN USED AS DIRECTED
SPECIFIC GRAVITY: 1.18-1.2
VAPOUR PRESSURE : AS WATER
VAPOUR DENSITY (AIR=1): AS WATER
VOC CONTENT (% ): 0.2-2.3 (EPA METHOD 24)
EVAPORATION RATE; SLOWER THAN WATER
0 0
BOILING POINT; >118 C ( 244 F ) APPROX.
PH: <1
FREEZING POINT: NOT AVAILABLE
DENSITY (g/ ml): 1.18-1.2
COEFFICIENT OF WATER/OIL
DISTRIBUTION:. COMPLETELY WATER SOLUBLE
SECTION 10: STABILITY AND REACTIVITY
CHEMICAL STABILITY: STABLE
INCOMPATIBLE MATERIALS: DO NOT MIX WITH ALKALINE OR CHLORINE CONTAINING CHEMICALS (IE BLEACH) , SULFITES,
PEROXIDES OR REDUCING AGENTS. REACTIONS CAN GENERATE A GREAT DEAL OF HEAT AND TOXIC
GASES. AVOID CONTACT WITH ALUMINIUM OR GALVANIZED SURFACES OR OTHER METALS EXCEPT AS
DIRECTED ON THE LABEL.
CONDITIONS OF REACTIVITY: AS ANY STRONG ACID SOLUTION CAN REACT WITH METALS ESPECIALLY 鈥淪OFT鈥? METALS SUCH AS
ALUMINIUM OR ZINC (GALVANIZED) GENERATING HYDROGEN. THIS GAS IS FLAMMABLE AND/OR
EXPLOSIVE IN PRESENCE OF IGNITION SOURCE.
HAZARDOUS DECOMPOSITION
PRODUCTS: OXIDES OF CARBON, NITROGEN AND PHOSPHOROUS.
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MATERIAL SAFETY DATA SHEET
SECTION 11: TOXICOLOGICAL INFORMATION
IRRITANCY OF PRODUCT: CORROSIVE PRODUCT, SEVERE IRRITANT
SENSITIZATION TO
MATERIAL: NONE KNOWN.
CARCINOGENICITY,: NO KNOWN CARCINOGENS LISTED BY OSHA, IARC OR NTP.
REPRODUCTIVE EFFECTS: IT IS WELL DOCUMENTED INGESTION OF ALCOHOLIC BEVERAGES (ETHANOL) CAN CAUSE SIGNIFICANT
HARMFUL EFFECTS IN UNBORN CHILDREN. THERE ARE NO REPORTS OF ADVERSE EFFECTS ON
PREGNANCY FOLLOWING OCCUPATIONAL EXPOSURES.
TERATOGENICITY: NOT AVAILABLE
MUTAGENICITY: PHOSPHORIC ACID COMPONENT BACTERIA MUTAGENIC TEST RESULTS WERE NEGATIVE. NO
REPORTED MUTAGENICITY IN HUMANS OR HUMAN CELL CULTURES. ETHANOL HAS CAUSE MUTAGENIC
EFFECTS IN LIVE ANIMALS . THERE ARE NO REPORTS OF ADVERSE EFFECTS ON PREGNANCY
FOLLOWING OCCUPATIONAL EXPOSURES.
TOXICOLOGICALLY SYNERGISTIC
PRODUCTS: MIXING THIS PRODUCT WITH NITRIC ACID, NITROUS ACID AND OTHER NITROSATING AGENTS MAY
PRODUCT NITROSAMINES WHICH HAVE BEEN FOUND TO BE CARCINOGENIC IN ANIMAL TESTING. NOT
A LIKELY OCCURRENCE UNDER NORMAL USE.
OTHER INFORMATION: ETHANOL COMPONENT CAN BE EXCRETED THROUGH BREAST MILK.
SECTION 12: ECOLOGICAL INFORMATION
THERE IS NO ECOLOGICAL INFORMATION AVAILABLE FOR PRODUCT. INDIVIDUAL COMPONENT INFORMATION (AS AVAILABLE) ONLY.
ECOTOXICOLOGICAL INFORMATION TO FOLLOW IS BASED LARGELY OR COMPLETELY ON INFORMATION FOR COMPONENTS
EXPRESSED ON A 100% ACTIVE INGREDIENT BASIS.
ECOTOXICOLOGICAL INFORMATION:
AQUATIC TOXICITY: FISH SPECIES DATA: PHOSPHORIC ACID LC 50 MOSQUITO FISH: 138 mg/ L
ETHANOL LC 50, 96 HR, BLUEGILL : 93 碌g/ L
ETHOXYLATED LINEAR ALCOHOL LC50, 96 HR STATIC ACUTE, FATHEAD MINNOW: 8.5 mg/L
AQUATIC TOXICITY: INVERTEBRATES: ETHANOL EC 50, 48 HR, DAPHNIA PULEX : 24 碌g/ L
ETHOXYLATED LINEAR ALCOHOL LC50, 96 HR STATIC ACUTE, DAPHNIA: 5.3 mg/L
AQUATIC TOXICITY: (GROWTH INHIBITION) PLANTS: ETHANOL EC 50, 1-2 HR, GREEN ALGAE : 10000-25000 碌g/ L
ACUTE AQUATIC TOXICITY: OTHER: ETHANOL LC 50, 3 HR, MOOR FROG HATCHABILITY :0.89-187.4 碌g/ L
BIODEGRADABILITY: LAURYL DIMETHYLAMINE OXIDE COMPONENT IS BIODEGRADABLE ETHOXYLATED LINEAR ALCOHOL
COMPONENT IS READILY BIODEGRADABLE . ETHOXYLATED LINEAR ALCOHOL COMPONENT HAS 88% OXYGEN
REMOVAL IN 28 DAYS. 100% DOC REMOVAL
MOBILITY: PHOSPHORIC ACID COMPONENT WHEN RELEASED IN THE SOIL MAY LEACH INTO GROUNDWATER. WHEN
RELEASED TO WATER, ACIDITY MAY BE READILY REDUCED BY NATURAL WATER HARDNESS MINERALS.
PERSISTENCE: THE PHOSPHATE COMPONENT OF PHOSPHORIC ACID MAY PERSIST INDEFINITELY.
BIOACCUMULATIVE: NOT AVAILABLE
CHEMICAL FATE INFORMATION: NOT AVAILABLE
OTHER INFORMATION: NOT AVAILABLE
SECTION 13: DISPOSAL CONSIDERATIONS
IN ACCORDANCE WITH MUNICIPAL, PROVINCIAL AND FEDERAL REGULATIONS.
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MATERIAL SAFETY DATA SHEET
SECTION 14: TRANSPORT INFORMATION
TDG(CANADA) PHOSPHORIC ACID, LIQUID
8
UN 1805
PACKING GROUP III
ADDITIONAL INFORMATION: NOT AVAILABLE
MARINE POLLUTANT: NO
SECTION 15: REGULATORY INFORMATION:
DSL STATUS: LISTED
WHMIS CLASSIFICATION: D2B, E
THIS PRODUCT HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD CRITERIA OF THE
CPR(CONTROLLED PRODUCTS REGULATIONS) AND THE MSDS CONTAINS ALL THE INFORMATION
REQUIRED BY THE CPR.
SECTION 16: OTHER INFORMATION
DISCLAIMER: THIS INFORMATION WAS COMPILED FROM CURRENT, RELIABLE SOURCES AND IS BELIEVED TO BE
CORRECT. AS DATA AND/ OR REGULATIONS CHANGE, AND CONDITIONS OF USE ARE BEYOND OUR
CONTROL, NO WARRANTY, EXPRESSED OR IMPLIED, IS MADE AS TO COMPLETENESS OR
CONTINUING ACCURACY OF THIS INFORMATION
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