3M MATERIAL SAFETY DATA SHEET 3M(TM) 3-IN-1 FLOOR CLEANER CONCENTRATE (Product No. 24, Twist 'n Fill(tm)
System 10/05/2005
Material Safety Data Sheet
Copyright, 2005, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly
utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is
obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit
thereon.
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: 3M(TM) 3-IN-1 FLOOR CLEANER CONCENTRATE (Product No. 24, Twist 'n Fill(tm)
System
MANUFACTURER: 3M
DIVISION: Commercial Care Division
ADDRESS: 3M Center
St. Paul, MN 55144-1000
EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours)
Issue Date: 10/05/2005
Supercedes Date: Initial Issue
Document Group: 20-5666-1
Product Use:
Specific Use: Versatile, low-foaming cleaner can be used in automatic scrubbers or in mop-on
applications.
SECTION 2: INGREDIENTS
Ingredient C.A.S. No. % by Wt
ALCOHOLS, C11-14-ISO-, C13-RICH, ETHOXYLATED 78330-21-9 40 - 70
2-ETHYL-HEXYLOXYETHANOL 1559-35-9 10 - 30
WATER 7732-18-5 7 - 13
DIETHYLENE GLYCOL MONO(2-ETHYLHEXYL) ETHER 1559-36-0 1- 5
CITRUS ODORANT Trade Secret 0.5 - 1.5
SECTION 3: HAZARDS IDENTIFICATION
3.1 EMERGENCY OVERVIEW
Specific Physical Form: Liquid
Odor, Color, Grade: Dark blue liquid with citrus fragrance.
General Physical Form: Liquid
Immediate health, physical, and environmental hazards:
3.2 POTENTIAL HEALTH EFFECTS
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3M MATERIAL SAFETY DATA SHEET 3M(TM) 3-IN-1 FLOOR CLEANER CONCENTRATE (Product No. 24, Twist 'n Fill(tm)
System 10/05/2005
Eye Contact:
Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision.
Skin Contact:
Moderate Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness.
Inhalation:
Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and
throat pain.
Ingestion:
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.
3.3 POTENTIAL ENVIRONMENTAL EFFECTS
A 3M Product Environmental Data Sheet (PED) is available.
A conservative assessment of this product indicates that its use and proper disposal are likely to present a low environmental risk.
Potential use and misuse are unlikely to cause components to enter the environment in quantities or by routes that could cause adverse
environmental impacts.
SECTION 4: FIRST AID MEASURES
4.1 FIRST AID PROCEDURES
The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are
followed.
Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention.
Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical
attention. Wash contaminated clothing and clean shoes before reuse.
Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention.
If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never
give anything by mouth to an unconscious person. Get medical attention.
SECTION 5: FIRE FIGHTING MEASURES
5.1 FLAMMABLE PROPERTIES
> 200 潞F
Flash Point
Class IIIB Combustible Liquid
OSHA Flammability Classification:
5.2 EXTINGUISHING MEDIA
Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide).
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3M MATERIAL SAFETY DATA SHEET 3M(TM) 3-IN-1 FLOOR CLEANER CONCENTRATE (Product No. 24, Twist 'n Fill(tm)
System 10/05/2005
5.3 PROTECTION OF FIRE FIGHTERS
Special Fire Fighting Procedures: Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus
(SCBA).
Unusual Fire and Explosion Hazards: Non-flammable: ordinary combustible material.
Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition
information.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Accidental Release Measures: Observe precautions from other sections. Call 3M- HELPS line (1-800-364-3577) for more
information on handling and managing the spill. Evacuate unprotected and untrained personnel from hazard area. The spill should be
cleaned up by qualified personnel. Ventilate the area with fresh air. Contain spill. For larger spills, cover drains and build dikes to
prevent entry into sewer systems or bodies of water. Working from around the edges of the spill inward, cover with bentonite,
vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Collect as much
of the spilled material as possible. Clean up residue with water. Collect the resulting residue containing solution. Place in a closed
container approved for transportation by appropriate authorities. Dispose of collected material as soon as possible.
In the event of a release of this material, the user should determine if the release qualifies as reportable according to
local, state, and federal regulations.
SECTION 7: HANDLING AND STORAGE
7.1 HANDLING
Keep out of the reach of children. This product is not intended to be used without prior dilution as specified on the product label.
Avoid breathing of vapors, mists or spray. Avoid skin contact. Avoid eye contact. Do not eat, drink or smoke when using this
product. Wash exposed areas thoroughly with soap and water. Avoid contact with oxidizing agents.
7.2 STORAGE
Store away from oxidizing agents. Store away from strong bases.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 ENGINEERING CONTROLS
Use in a well-ventilated area.
NOTE: When used as directed and diluted and dispensed with a TWIST 'n FILL(TM) Chemical Dispenser, special ventilation is not
required.
8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE)
8.2.1 Eye/Face Protection
Avoid eye contact.
NOTE: When used as directed and diluted and dispensed with a TWIST 'n FILL(TM) Chemical Dispenser, eye contact with the
concentrate is not expected to occur.
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3M MATERIAL SAFETY DATA SHEET 3M(TM) 3-IN-1 FLOOR CLEANER CONCENTRATE (Product No. 24, Twist 'n Fill(tm)
System 10/05/2005
If the product is not used with the Twist 'n Fill system or if there is an accidental release, the following eye protection is
recommended: Indirect Vented Goggles
8.2.2 Skin Protection
Avoid skin contact.
NOTE: When used as directed and diluted and dispensed with a TWIST 'n FILL(TM) Chemical Dispenser, skin contact with the
concentrate is not expected to occur.
If the product is not used with the Twist 'n Fill system or if there is an accidental release, select and use gloves and/or protective
clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing
manufacturer for selection of appropriate compatible materials. Gloves made from the following material is recommended: Butyl
Rubber
8.2.3 Respiratory Protection
Avoid breathing of vapors, mists or spray.
NOTE: When used as directed and diluted and dispensed with a TWIST 'n FILL(TM) Chemical Dispenser, respiratory protection is
not required.
If the product is not used with the Twist 'n Fill system or if there is an accidental release, select one of the following NIOSH approved
respirators based on airborne concentration of contaminants and in accordance with OSHA regulations: Half facepiece or fullface air-
purifying respirator with organic vapor cartridges. Consult the current 3M Respiratory Selection Guide for additional information or
call 1-800-243-4630 for 3M technical assistance.
8.2.4 Prevention of Swallowing
Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water.
8.3 EXPOSURE GUIDELINES
Ingredient Authority Type Limit Additional Information
CHROMIUM (VI), CERTAIN WATER ACGIH TWA, as Cr 0.01 mg/m3 Table A1
INSOLUBLE COMPOUNDS
MANGANESE COMPOUNDS OSHA CEIL, as Mn 5 mg/m3 Table Z-1A
MANGANESE, INORGANIC ACGIH TWA, as Mn 0.2 mg/m3
COMPOUNDS
SOURCE OF EXPOSURE LIMIT DATA:
ACGIH: American Conference of Governmental Industrial Hygienists
CMRG: Chemical Manufacturer Recommended Guideline
OSHA: Occupational Safety and Health Administration
AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL)
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Liquid
Specific Physical Form:
Dark blue liquid with citrus fragrance.
Odor, Color, Grade:
Liquid
General Physical Form:
> 200 潞F
Flash Point
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3M MATERIAL SAFETY DATA SHEET 3M(TM) 3-IN-1 FLOOR CLEANER CONCENTRATE (Product No. 24, Twist 'n Fill(tm)
System 10/05/2005
> 200 潞F
Boiling point
<=27 psia [@ 131 潞F]
Vapor Pressure
1 [Ref Std: WATER=1]
Specific Gravity
7-8
pH
Complete
Solubility in Water
0.5 - 1.5 % [Test Method: calculated per CARB title 2]
Volatile Organic Compounds
7 - 15 %
Percent volatile
5.51 g/l - 16.52 g/l [Test Method: calculated per CARB title 2]
VOC Less H2O & Exempt Solvents
< 100 centipoise
Viscosity
SECTION 10: STABILITY AND REACTIVITY
Stability: Stable.
Materials and Conditions to Avoid: Strong bases; Strong oxidizing agents
Hazardous Polymerization: Hazardous polymerization will not occur.
Hazardous Decomposition or By-Products
Substance Condition
Carbon monoxide During Combustion
Carbon dioxide During Combustion
SECTION 11: TOXICOLOGICAL INFORMATION
Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its
components.
SECTION 12: ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
A 3M Product Environmental Data Sheet (PED) is available.
CHEMICAL FATE INFORMATION
A 3M Product Environmental Data Sheet (PED) is available.
SECTION 13: DISPOSAL CONSIDERATIONS
Waste Disposal Method: Incinerate in an industrial or commercial facility. As a disposal alternative, dispose of waste product in a
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3M MATERIAL SAFETY DATA SHEET 3M(TM) 3-IN-1 FLOOR CLEANER CONCENTRATE (Product No. 24, Twist 'n Fill(tm)
System 10/05/2005
facility permitted to accept chemical waste.
EPA Hazardous Waste Number (RCRA): Not regulated
Since regulations vary, consult applicable regulations or authorities before disposal.
SECTION 14:TRANSPORT INFORMATION
ID Number UPC ID Number UPC
70-0713-1133-9 70-0713-1134-7
Not regulated per U.S. DOT, IATA or IMO.
These transportation classifications are provided as a customer service. As the shipper YOU remain responsible for
complying with all applicable laws and regulations, including proper transportation classification and packaging. 3M鈥檚
transportation classifications are based on product formulation, packaging, 3M policies and 3M鈥檚 understanding of applicable
current regulations. 3M does not guarantee the accuracy of this classification information. This information applies only to
transportation classification and not the packaging, labeling, or marking requirements. The original 3M package is certified
for U.S. ground shipment only. If you are shipping by air or ocean, the package may not meet applicable regulatory
requirements.
SECTION 15: REGULATORY INFORMATION
US FEDERAL REGULATIONS
311/312 Hazard Categories:
Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - No
Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA):
Ingredient C.A.S. No % by Wt
DIETHYLENE GLYCOL MONO(2- 1559-36-0 1- 5
ETHYLHEXYL) ETHER (GLYCOL ETHERS)
2-ETHYL-HEXYLOXYETHANOL (GLYCOL 1559-35-9 10 - 30
ETHERS)
STATE REGULATIONS
CHEMICAL INVENTORIES
The components of this product are in compliance with the chemical notification requirements of TSCA.
All the components of this product are listed on China's Inventory of Chemical Substances.
The components of this product are in compliance with notification requirements in the Philippines.
The components of this product are listed on the Canadian Domestic Substances List.
INTERNATIONAL REGULATIONS
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3M MATERIAL SAFETY DATA SHEET 3M(TM) 3-IN-1 FLOOR CLEANER CONCENTRATE (Product No. 24, Twist 'n Fill(tm)
System 10/05/2005
This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: OTHER INFORMATION
NFPA Hazard Classification
Health: 2 Flammability: 1 Reactivity: 0 Special Hazards: None
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are
presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the
inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to
be generated in significant quantities.
HMIS Hazard Classification
Health: 2 Flammability: 1 Reactivity: 0 Protection: X - See PPE section.
Hazardous Material Identification System (HMIS庐) hazard ratings are designed to inform employees of chemical hazards in the workplace. These
ratings are based on the inherent properties of the material under expected conditions of normal use and are not intended for use in emergency
situations. HMIS庐 ratings are to be used with a fully implemented HMIS庐 program. HMIS庐 is a registered mark of the National Paint and Coatings
Association (NPCA).
No revision information is available.
DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M
MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of
use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely
within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may
have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy.
In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M.
3M MSDSs are available at www.3M.com
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