BREAK-FREE DIV OF SAN BAR -- BREAK-FREE CLP AEROSOL (NON-CHLORIN.. Page 1 of 5
BREAK-FREE DIV OF SAN BAR -- BREAK-FREE CLP AEROSOL (NON-CHLORINATED FORMULA) - CLEANING COM
MATERIAL SAFETY DATA SHEET
NSN: 6850001053084
Manufacturer's CAGE: 65983
Part No. Indicator: B
Part Number/Trade Name: BREAK-FREE CLP AEROSOL (NON-CHLORINATED FORMULA)
===========================================================================
General Information
===========================================================================
Item Name: CLEANING COMPOUND, SOLVENT
Company's Name: BREAK-FREE DIV OF SAN/BAR CORP
Company's Street: 1035 S LINWOOD AVE
Company's P. O. Box: 25020
Company's City: SANTA ANA
Company's State: CA
Company's Country: US
Company's Zip Code: 92799-5020
Company's Emerg Ph #: 800-424-9300(CHEMTREC)/202-483-7616
Company's Info Ph #: 714-953-1900/202-483-7616
Record No. For Safety Entry: 023
Tot Safety Entries This Stk#: 028
Status: FE
Date MSDS Prepared: 09JUL92
Safety Data Review Date: 07MAR94
Supply Item Manager: CX
MSDS Preparer's Name: DONALD E. YODER
MSDS Serial Number: BSTWZ
Specification Number: MIL-C-81302
Spec Type, Grade, Class: 2 CL AND IIA TY
Hazard Characteristic Code: G3
Unit Of Issue: CN
Unit Of Issue Container Qty: 16.0 OZ
Type Of Container: CAN, AEROSOL
Net Unit Weight: 0.9 LBS
===========================================================================
Ingredients/Identity Information
===========================================================================
Proprietary: NO
Ingredient: POLYALPHAOLEFIN BASE STOCK
Ingredient Sequence Number: 01
Percent: 61.6
NIOSH (RTECS) Number: 1004246PS
CAS Number: 68649-12-7
OSHA PEL: NOT ESTABLISHED
ACGIH TLV: NOT ESTABLISHED
Other Recommended Limit: NONE RECOMMENDED
-------------------------------------
Proprietary: NO
Ingredient: PROPRIETARY INGREDIENTS (SYNTHETIC OILS, ESTERS AND OTHER
INGREDIENTS)
Ingredient Sequence Number: 02
Percent: 16.4
NIOSH (RTECS) Number: 1004255PI
OSHA PEL: NOT ESTABLISHED.
ACGIH TLV: NOT ESTABLISHED.
Other Recommended Limit: NONE RECOMMENDED
-------------------------------------
Proprietary: NO
Ingredient: HYDROTREATED HEAVY NAPHTHENIC DISTILLATE, PETROLEUM/
LUBRICATING OIL BASE STOCK
Ingredient Sequence Number: 03
Percent: 1.2
NIOSH (RTECS) Number: PY8035000
http://hazard.com/msds/h/q244/q216.html 7/5/00
BREAK-FREE DIV OF SAN BAR -- BREAK-FREE CLP AEROSOL (NON-CHLORIN.. Page 2 of 5
CAS Number: 64742-52-5
OSHA PEL: 5 MG/M3 OIL MIST
ACGIH TLV: 5 MG/M3 OIL MIST
Other Recommended Limit: NONE RECOMMENDED
-------------------------------------
Proprietary: NO
Ingredient: ETHYLHEXYL ACETATE
Ingredient Sequence Number: 04
Percent: 13.5
NIOSH (RTECS) Number: AH5600000
CAS Number: 103-09-3
OSHA PEL: NOT ESTABLISHED
ACGIH TLV: NOT ESTABLISHED
Other Recommended Limit: NONE RECOMMENDED
-------------------------------------
Proprietary: NO
Ingredient: DIBASIC ESTER
Ingredient Sequence Number: 05
Percent: 4.4
NIOSH (RTECS) Number: 1006080DE
OSHA PEL: NOT ESTABLISHED
ACGIH TLV: NOT ESTABLISHED
Other Recommended Limit: NONE RECOMMENDED
-------------------------------------
Proprietary: NO
Ingredient: CARBON DIOXIDE
Ingredient Sequence Number: 06
Percent: 2.9
NIOSH (RTECS) Number: FF6400000
CAS Number: 124-38-9
OSHA PEL: 5000 PPM
ACGIH TLV: 5000PPM/30000STEL;94
Other Recommended Limit: NONE RECOMMENDED
===========================================================================
Physical/Chemical Characteristics
===========================================================================
Appearance And Odor: LIGHT AMBER COLOR WITH A SLIGHT FRUITY ODOR.
Boiling Point: 378F,192C
Vapor Pressure (MM Hg/70 F): 0.04
Vapor Density (Air=1): 5.9
Specific Gravity: 0.86
Evaporation Rate And Ref: <0.03 (N-BUTYL ACETATE=1)
Solubility In Water: NIL
Percent Volatiles By Volume: 20.8
pH: N/A
Autoignition Temperature: N/A
===========================================================================
Fire and Explosion Hazard Data
===========================================================================
Flash Point: 201F,94C
Flash Point Method: PMCC
Lower Explosive Limit: N/A
Upper Explosive Limit: N/A
Extinguishing Media: CARBON DIOXIDE, FOAM, DRY CHEMICAL.
Special Fire Fighting Proc: USE NORMAL PROCEDURES FOR OIL. WATER AND FOAM
MAY CAUSE FROTHING. IF A LEAK OR SPILL HAS NOT IGNITED USE WATER SPRAY TO
DISPERSE VAPORS AND/OR COOL CONTAINERS.
Unusual Fire And Expl Hazrds: FIREFIGHTERS SHOUD WEAR NIOSH-APPROVED,
SELF-CONTAINED BREATHING APPARATUS TO AVOID EXPOSURE TO DECOMPOSITION
PRODUCTS. USE IN THE POSITIVE-PRESSURE MODE.
===========================================================================
Reactivity Data
===========================================================================
Stability: YES
http://hazard.com/msds/h/q244/q216.html 7/5/00
BREAK-FREE DIV OF SAN BAR -- BREAK-FREE CLP AEROSOL (NON-CHLORIN.. Page 3 of 5
Cond To Avoid (Stability): KEEP FROM OPEN FLAMES.
Materials To Avoid: STRONG OXIDIZERS.
Hazardous Decomp Products: OXIDES OF CARBON, ANTIMONY, SULFUR AND
NITROGEN.
Hazardous Poly Occur: NO
Conditions To Avoid (Poly): NOT APPLICABLE
===========================================================================
Health Hazard Data
===========================================================================
LD50-LC50 Mixture: LD50 >5G/KG, LOW LEVEL OF TOXICITY.
Route Of Entry - Inhalation: YES
Route Of Entry - Skin: YES
Route Of Entry - Ingestion: YES
Health Haz Acute And Chronic: SKIN- PROLONGED AND REPEATED CONTACT ON THE
SKIN COULD CAUSE IRRITATION AND POSSIBLE DERMATITIS. INHALATION-
RESPIRATORY IRRITATION AND DISCOMFORT MAY RESULT. EXCESSIVE INHALATION MAY
CAUSE CENTRAL NERVOUS SYSTEM EFFECTS. INGESTION- MAY CAUSE IRRITATION TO
DIGESTIVE TRACT. EYES- POSSIBLE TRANSIENT IRRITATION.
Carcinogenicity - NTP: NO
Carcinogenicity - IARC: NO
Carcinogenicity - OSHA: NO
Explanation Carcinogenicity: NOT APPLICABLE
Signs/Symptoms Of Overexp: INHALATION- DIZZINESS, WEAKNESS, FATIGUE,
NAUSEA, HEADACHES AND POSSIBLE UNCONSCIOUSNESS WITH EXCESSIVE INHALATION.
SKIN- POSSIBLE SLIGHT TO MODERATE REDNESS MAY OCCUR WITH EXTENDED DAILY
EXPOSURE.
Med Cond Aggravated By Exp: PRE-EXISTING SKIN, EYE AND RESPIRATORY
DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO MATERIAL.
Emergency/First Aid Proc: EYES- FLUSH IMMEDIATELY WITH WATER FOR AT LEAST
15 MINUTES. SKIN- WASH WITH SOAP AND WATER, LAUNDER CONTAMINATED CLOTHING
BRFORE REUSE. INGESTION- DO NOT INDUCE VOMITING. IF CONSCIOUS, DRINK LARGE
QUANTITIES OF WATER AND SEEK IMMEDIATE MEDICAL ATTENTION. INHALATION- MOVE
TO FRESH AIR. CALL A PHYSICIAN IF ANESTHETIC OR NARCOTIC EFFECTS RESULT.
ASSIST WITH BREATHING SUPPORT MEASURES IF NEEDED.
===========================================================================
Precautions for Safe Handling and Use
===========================================================================
Steps If Matl Released/Spill: IF POORLY VENTILATED, USE RESPIRATORY
PROTECTION. FOLLOW ALL INDUSTRIAL PRACTICES FOR CLEANING SOLVENT/OIL
SPILLS. DIKE THE AREA TO CONFINE THE SPILL, SHUT OF IGNITION SOURCES AND
USE A GOOD ABSORBENT TO SOAK UP THE SPILL. STORE IN CLOSED CONTAINERS.
Neutralizing Agent: N/A
Waste Disposal Method: DISPOSE OF ALL WASTES IN ACCORDANCE WITH FEDERAL,
STATE AND LOCAL REGULATIONS. TREAT THIS TYPE OF WASTE AS WASTE OIL.
INCINERATION NORMALLY PREFERRED. NEVER DUMP INTO THE SEWER OR ON THE GROUND
OR INTO ANY NAVIGABLE WATERS, STREAMS, LAKES OR RIVERS.
Precautions-Handling/Storing: DO NOT STORE ABOVE 120F. DO NOT USE AROUND
OPEN FLAMES. MAINTAIN ADEQUATE VENTILATION. KEEP FROM CHILDREN. VAPORS CAN
COLLECT IN LOW AREAS.
Other Precautions: DO NOT ENTER THOSE AREAS WHERE LARGE QUANTITIES OF
VAPORS ARE SUSPECTED OF COLLECTING UNTIL EXCHANGING THE AIR OR USING
SPECIAL BREATHING APPARATUS.
===========================================================================
Control Measures
===========================================================================
Respiratory Protection: NOT REQUIRED IN NON-CONFINED AREAS OR WELL
VENTILATED AREAS. FOR EMERGENCIES OR FOR WORKING IN CONFINED AREAS WITH LOW
AIR EXCHANGE, FOLLOW OSHA STD. 29 CFR 1910.133.
Ventilation: GENERAL DILUTION OR LOCAL EXHAUST SUFFICIENT TO MAINTAIN
ADEQUATE AIR EXCHANGE TO AVOID VAPOR BUILD-UP.
Protective Gloves: POLYEHTYLENE, NEOPRENE OR PVC.
Eye Protection: COMPLY WITH OSHA STD. 29 CFR 1910.133
Other Protective Equipment: NOT REQUIRED.
Work Hygienic Practices: DO NOT SMOKE, EAT OR DRINK WHILE USING THE
http://hazard.com/msds/h/q244/q216.html 7/5/00
BREAK-FREE DIV OF SAN BAR -- BREAK-FREE CLP AEROSOL (NON-CHLORIN.. Page 4 of 5
PRODUCT. WASH HANDS WITH SOAP & WATER BEFORE SMOKING, EATING OR USING
TOILET.
Suppl. Safety & Health Data: NONE
===========================================================================
Transportation Data
===========================================================================
Trans Data Review Date: 94066
DOT PSN Code: AGD
DOT Proper Shipping Name: AEROSOLS, NON-FLAMMABLE,
DOT Class: 2.2
DOT ID Number: UN1950
DOT Label: NONFLAMMABLE GAS
IMO PSN Code: AKD
IMO Proper Shipping Name: AEROSOLS o
IMO Regulations Page Number: 2102
IMO UN Number: 1950
IMO UN Class: 2(T)
IMO Subsidiary Risk Label: T
IATA PSN Code: ANB
IATA UN ID Number: 1950
IATA Proper Shipping Name: AEROSOLS, 20, *
IATA UN Class: 2.2
IATA Label: NON-FLAMMABLE GAS
AFI PSN Code: ANB
AFI Prop. Shipping Name: AEROSOLS, NON-FLAMMABLE, N.O.S.
AFI Class: 2.2
AFI ID Number: UN1950
AFI Basic Pac Ref: 6-6
N.O.S. Shipping Name: POLYALPHAOLEFIN OIL
Additional Trans Data: NONE
===========================================================================
Disposal Data
===========================================================================
===========================================================================
Label Data
===========================================================================
Label Required: YES
Technical Review Date: 07MAR94
Label Status: F
Common Name: BREAK-FREE CLP AEROSOL (NON-CHLORINATED FORMULA)
Chronic Hazard: NO
Signal Word: CAUTION!
Acute Health Hazard-Slight: X
Contact Hazard-Slight: X
Fire Hazard-Slight: X
Reactivity Hazard-None: X
Special Hazard Precautions: SKIN- COULD CAUSE IRRITATION AND POSSIBLE
DERMATITIS. INHALATION- RESPIRATORY IRRITATION AND DISCOMFORT. EXCESSIVE
INHALATION MAY CAUSE CNS EFFECTS. INGESTION- MAY CAUSE IRRITATION. EYES-
POSSIBLE TRANSIENT IRRITATION. DO NOT STORE ABOVE 120F. FIRST AID: EYES-
FLUSH IMMEDIATELY WITH WATER FOR AT LEAST 15 MINUTES. SKIN- WASH WITH SOAP
AND WATER, LAUNDER CONTAMINATED CLOTHING BRFORE REUSE. INGESTION- DO NOT
INDUCE VOMITING. IF CONSCIOUS, DRINK LARGE QUANTITIES OF WATER AND SEEK
IMMEDIATE MEDICAL ATTENTION. INHALATION- MOVE TO FRESH AIR. CALL A
PHYSICIAN IF ANESTHETIC OR NARCOTIC EFFECTS RESULT. ASSIST WITH BREATHING
SUPPORT MEASURES IF NEEDED.
Protect Eye: Y
Protect Skin: Y
Protect Respiratory: Y
Label Name: BREAK-FREE DIV OF SAN/BAR CORP
Label Street: 1035 S LINWOOD AVE
Label P.O. Box: 25020
Label City: SANTA ANA
Label State: CA
http://hazard.com/msds/h/q244/q216.html 7/5/00
BREAK-FREE DIV OF SAN BAR -- BREAK-FREE CLP AEROSOL (NON-CHLORIN.. Page 5 of 5
Label Zip Code: 92799-5020
Label Country: US
Label Emergency Number: 800-424-9300(CHEMTREC)/202-483-7616
http://hazard.com/msds/h/q244/q216.html 7/5/00
|