W. R. GRACE
MATERIAL SAFETY DATA SHEET
Product Name: FlameSafe庐 900+ Series Firestop Compound
MSDS ID Number: Z-01572 MSDS Date: 11/05/2002
SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
FlameSafe庐 900+ Series Firestop Compound
Product Name:
Z-01572
MSDS Number:
Z-01553, Z-01528
Cancelled MSDS Number:
11/05/2002
MSDS Date:
Polyvinyl Acetate & Acrylic Latex Based Emulsion
Chemical Family Name:
Elastomeric Acrylic Firestop
Product Use:
Mixture-NA
Chemical Formula:
Mixture-NA
CAS # (Chemical Abstracts
Service Number):
Manufactured by:
W.R. Grace & Co.-Conn. Grace Canada, Inc.
62 Whittemore Avenue 294 Clements Road West
Cambridge, MA 02140 Ajax, Ontario L1S 3C6
In Case of Emergency Call:
In USA: (617) 876-1400 In Canada: (905) 683-8561
SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS
Ingredient CAS# Percent (max)
2-Propenoic acid, polymer.. 052640-81-0 25-50
Aluminum oxide 001344-28-1 10-25
Ethylene Glycol 000107-21-1 <1
Methenamine 000100-97-0 <1
Phenol, isopropylated, phosphate (3:1) 068937-41-7 1-10
Phenol-formaldehyde polymer 009003-35-4 1-10
Triphenyl phosphate 000115-86-6 1-10
Wollastonite (Ca(SiO3)) 013983-17-0 1-10
Zinc borate 001332-07-6 1-10
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W. R. GRACE
MATERIAL SAFETY DATA SHEET
Product Name: FlameSafe庐 900+ Series Firestop Compound
MSDS ID Number: Z-01572 MSDS Date: 11/05/2002
SECTION 3 - HAZARDS IDENTIFICATION
Emergency Overview:
Caution!
Causes mild to moderate eye irritation.
Causes respiratory tract irritation.
May be harmful if ingested.
Harmful if absorbed through skin.
May cause mutagenic effects.
May cause reproductive effects.
May cause teratogenic effects.
HMIS Rating:
Health: 2*
Flammability: 0
Reactivity: 0
Personal Protective Equipment: B (See Section 8)
Potential Health Effects:
Inhalation:
Causes respiratory tract irritation.
Prolonged inhalation may cause sensitization.
Effects include: Nausea, sneezing, coughing, tightness of chest and wheezing.
Hypersensitive individuals may experience allergic respiratory reaction.
Eye Contact:
Eye contact causes mild to moderate irritation.
Skin Contact:
Acute skin contact is not expected to cause irritation.
Hypersensitive individuals may develop an allergic reaction resulting in dermatitis, rash
or hives.
Skin Absorption:
Harmful if absorbed through the skin.
Ingestion:
Harmful if ingested.
Reproductive and developmental effects have been reported for certain ingredients.
Long-term repeated ingestion of small amounts of product may cause a decrease in red
blood cells or liver and kidney damage. Ethylene glycol has been shown to produce
teratogenic and developmental toxic effects in laboratory animals. Phenol-formaldehyde
polymer has tested positive as a mutagen.
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W. R. GRACE
MATERIAL SAFETY DATA SHEET
Product Name: FlameSafe庐 900+ Series Firestop Compound
MSDS ID Number: Z-01572 MSDS Date: 11/05/2002
SECTION 4 - FIRST AID MEASURES:
Skin Contact:
Wash with soap and water.
If discomfort or irritation persists, consult a physician.
Remove contaminated clothing and wash before reuse.
Eye Contact:
Flush eyes with water for at least 15 minutes while holding eyelids open.
Get immediate medical attention.
Ingestion:
Do not induce vomiting.
Never give anything by mouth to an unconscious person.
If discomfort or irritation persists, consult a physician.
Inhalation:
If symptoms develop, get fresh air. If symptoms persist, consult a physician.
If breathing has stopped, give artificial respiration then oxygen if needed.
SECTION 5 - FIRE AND EXPLOSION HAZARD DATA
Flash Point: >200掳F/93掳C
Flash Point Method: Estimated
Lower Explosion Limit: Not Available
Upper Explosion Limit: Not Available
Auto-Ignition Temperature: Not Available
NFPA Rating:
Health: 1
Flammability: 0
Reactivity: 0
Extinguishing Media: Product will not support combustion. Use alcohol foam, Carbon
dioxide, dry chemical or water to treat surrounding fire.
Special Fire Fighting Procedures:
Wear self-contained breathing apparatus and complete personal protective equipment
when potential for exposure to vapors or products of combustion exist. Isolate area and
keep unnecessary people away.
Unusual Fire and Explosion Hazards:
During fire, oxides of nitrogen may be evolved.
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W. R. GRACE
MATERIAL SAFETY DATA SHEET
Product Name: FlameSafe庐 900+ Series Firestop Compound
MSDS ID Number: Z-01572 MSDS Date: 11/05/2002
SECTION 6 - ACCIDENTAL RELEASE MEASURES:
Spills/Leaks:
Use proper personal protective equipment. Do not flush to sewer or allow to enter
waterways. Keep unnecessary people away.
SECTION 7 - HANDLING AND STORAGE
Precautionary Measures:
Avoid contact with eyes, skin and clothing.
Do not take internally.
Practice good personal hygiene to avoid ingestion.
Use only with adequate ventilation.
Wash clothing before reuse.
FOR PROFESSIONAL USE ONLY. KEEP OUT OF CHILDREN'S REACH.
SECTION 8 - EXPOSURE CONTROLS AND PERSONAL PROTECTIVE
EQUIPMENT
EXPOSURE GUIDELINES (US)
Ingredient ACGIH TLV OSHA PEL Other
TWA STEL Ceiling TWA STEL Ceiling
2-Propenoic acid, polymer.. - - - - - - -
Aluminum oxide 10 mg/m3 TWA (as Al) - - total dust: 10 - - -
(The value is for total mg/m3 TWA;
dust containing no respirable
asbestos and < fraction: 5
mg/m3 TWA
Ammonia 25 ppm TWA 35 ppm - - 35 ppm - -
STEL STEL; 27
mg/m3
STEL
Ethylene Glycol - - C 100 - - - -
mg/m3
(aerosol)
Phenol, isopropylated, - - - - - - -
phosphate (3:1)
Phenol-formaldehyde - - - - - - -
polymer
Triphenyl phosphate 3 mg/m3 TWA - - 3 mg/m3 - - -
TWA
Wollastonite (Ca(SiO3)) - - - - - - -
Zinc borate - - - - - - -
*Contains formaldehyde below 0.1% threshold. Product is capable of releasing formaldehyde
under certain conditions. Exposure during typical application is expected to be insignificant.
Exposure to formaldehyde vapor is a potential concern if product is applied under confined space
conditions. Consult appropriate exposure guidelines for formaldehyde. (OSHA: 0.75 ppm-
TWA, 2.0 ppm - STEL, ACGIH 0.3 ppm Ceiling)
EXPOSURE GUIDELINES (CANADA)
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W. R. GRACE
MATERIAL SAFETY DATA SHEET
Product Name: FlameSafe庐 900+ Series Firestop Compound
MSDS ID Number: Z-01572 MSDS Date: 11/05/2002
Employers should consult local Provincial regulatory limits for exposure guidelines which may
vary locally.
Not generally required.
Engineering Controls:
Personal Protective Equipment:
Respiratory Protection: Respiratory protection is not normally required.
A NIOSH approved respirator for Formaldehyde vapor is required whenever exposures
exceed regulatory limits. For additional information, refer to US OSHA Regulations 29
CFR 1910.搂 134.
Skin Protection: Impervious (PVC, latex or nitrile) gloves should be worn anytime
direct contact is possible.
Eye Protection: Safety glasses or goggles should be worn.
Work/Hygienic Practices: Use good personal hygiene practices.
Use good personal hygiene practices. Wash thoroughly after handling. Prevent direct skin
contact.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Solid
Physical State:
Red mastic. Mild latex odor.
Appearance/Odor:
Odor Threshold: (ppm)
Not Available
pH:
Unknown
Vapor Pressure: (Mm Hg)
Greater than 1
Vapor Density: (Air = 1)
Appreciable
Solubility In Water:
Not Available
Specific Gravity: (Water = 1)
1
Evaporation Rate: (Butyl Acetate = 1)
>212掳F/100掳C
Boiling Point:
Unknown
Viscosity:
Not Applicable
Bulk Density: (Pounds/Cubic Foot)(Pcf)
5.4 g/l
% Volatiles (gr/L): (70掳F) (21掳C)
SECTION 10 - STABILITY AND REACTIVITY
Stable
Chemical Stability:
None known for this product.
Conditions To Avoid:
Will not polymerize.
Hazardous Polymerization:
Carbon dioxide, Carbon monoxide and Low molecular
Hazardous Decomposition
weight hydrocarbons.
Products:
SECTION 11 - TOXICOLOGICAL INFORMATION
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W. R. GRACE
MATERIAL SAFETY DATA SHEET
Product Name: FlameSafe庐 900+ Series Firestop Compound
MSDS ID Number: Z-01572 MSDS Date: 11/05/2002
Ingredient(No data unless listed.) CAS Number LD50 and LC50
Triphenyl phosphate 000115-86-6 Oral LD50 Rat : 3500 mg/kg;
Oral LD50 Mouse : 1320 mg/kg;
Carcinogenicity:
IARC IARC IARC NTP NTP OSHA
Ingredient Group 1 Group 2A Group 2B Known Suspect
No No No No No No
2-Propenoic acid, polymer..
No No No No No No
Aluminum oxide
No No No No No No
Phenol, isopropylated, phosphate (3:1)
No No No No No No
Phenol-formaldehyde polymer
No No No No No No
Triphenyl phosphate
No No No No No No
Wollastonite (Ca(SiO3))
No No No No No No
Zinc borate
*Contains formaldehyde below 0.1% threshold. Product is capable of releasing formaldehyde
under certain conditions. Exposures during typical applications are expected to be insignificant.
Exposure to formaldehyde vapor is a potential concern if product is applied under confined space
conditions. NTP: Suspect Carcinogen. IARC: Group 2A. OSHA: Potential.
Phenol-formaldehyde polymer in this product has tested
Mutagenicity:
positive as a mutagen.
Ethylene glycol contained in this product has been shown
Teratogenicity:
to produce teratogenic effects in laboratory animals.
Reproductive effects have been reported for Phenol-
Reproductive Toxicity:
formaldehyde polymer.
SECTION 12 - ECOLOGICAL INFORMATION
No data available for product.
Environmental Fate:
No data available for product.
Ecotoxicity:
SECTION 13 - DISPOSAL CONSIDERATIONS
Consult all regulations (federal, state, provincial,
Waste Disposal Procedures:
local) or a qualified waste disposal firm when
characterizing waste for disposal. According to
EPA (40 CFR 搂 261), waste of this product is not
defined as hazardous. Dispose of waste in
accordance with all applicable regulations.
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W. R. GRACE
MATERIAL SAFETY DATA SHEET
Product Name: FlameSafe庐 900+ Series Firestop Compound
MSDS ID Number: Z-01572 MSDS Date: 11/05/2002
SECTION 14 - TRANSPORTATION INFORMATION
Not Applicable
Proper Shipping Name:
Not Applicable
UN/NA Number:
Nonhazardous
Domestic Hazard Class:
Compound, Fireproofing or Retardants, Flame.
Surface Freight Classification:
Not Applicable
Label/Placard Required:
SECTION 15 - REGULATORY INFORMATION
REGULATORY CHEMICAL LISTS:
CERCLA (Comprehensive Response Compensation and Liability Act):
(None present unless listed below)
Chemical Name CAS # Wt % CERCLA RQ
Zinc borate 001332-07-6 4 final RQ = 1000 pounds
(454 kg)
SARA Title III (Superfund Amendments and Reauthorization Act)
SARA Section 312/Tier I & II Hazard Categories:
Health Immediate (acute) Yes
Health Delayed (chronic) Yes
Flammable No
Reactive No
Pressure No
302 Reportable Ingredients (Identification Threshold 1%.):
Chemical Name CAS # Wt % SARA 302
TPQ
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W. R. GRACE
MATERIAL SAFETY DATA SHEET
Product Name: FlameSafe庐 900+ Series Firestop Compound
MSDS ID Number: Z-01572 MSDS Date: 11/05/2002
313 Reportable Ingredients (Chemicals present below reporting threshold are exempt):
Chemical Name CAS # Wt %
Acetaldehyde 000075-07-0 .0023075
Acrylamide 000079-06-1 .0013845
Acrylonitrile 000107-13-1 .0004615
Aluminum oxide 001344-28-1 15.41
Ammonia 007664-41-7 .129
Chlorothalonil 001897-45-6 .0404
Ethyl acrylate 000140-88-5 .003692
Ethylene Glycol 000107-21-1 .15
Formaldehyde 000050-00-0 .02789005
Glycol ethers RR-00067-9 .002
Methyl alcohol 000067-56-1 .002
Zinc Compounds RR-00578-7 4.0
National Volatile Organic Compound Emission Standards For Architectural Coatings:
Volatile Organic Content: (gr/L) 5.4 g/l
D2 B
WHMIS Classification(s):
This product has been classified in accordance with the hazard criteria of the Controlled Products
Regulations (CPR). This MSDS contains all the information required by the CPR.
State Regulatory Information:
WARNING! This product contains substances known
California Proposition 65:
to the state of California to cause cancer, birth defects or
other reproductive harm.
Massachusetts Hazardous Substance List(Identification threshold 0.001%(1ppm)):
Chemical Name CAS # Wt %
Acetaldehyde 000075-07-0 .0023075
Acrylamide 000079-06-1 .0013845
Acrylonitrile 000107-13-1 .0004615
Ammonia 007664-41-7 .129
Chlorothalonil 001897-45-6 .0404
Ethyl acrylate 000140-88-5 .003692
Formaldehyde 000050-00-0 .02789005
New Jersey Hazardous Substance List(Identification threshold (0.1%)):
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W. R. GRACE
MATERIAL SAFETY DATA SHEET
Product Name: FlameSafe庐 900+ Series Firestop Compound
MSDS ID Number: Z-01572 MSDS Date: 11/05/2002
Chemical Name CAS # Wt %
Aluminum oxide 001344-28-1 15.41
Ammonia 007664-41-7 .129
Ethylene Glycol 000107-21-1 .15
Pennsylvania Hazardous Substance List(Identification threshold 0.01%):
Chemical Name CAS # Wt %
Formaldehyde 000050-00-0 .02789005
CHEMICAL INVENTORY STATUS:
All chemicals in this product are listed or exempt from listing in the following countries:
US CANADA EUROPE AUSTRALIA JAPAN KOREA PHILIPPINES
TSCA DSL NDSL EINECS/ELINCS AICS ENCS ECL PICCS
Yes Not Yes Not Not Not Not Not
Determined Determined Determined Determined Determined Determined
SECTION 16 - OTHER INFORMATION
Non-Hazardous Ingredient Disclosure:
Chemical Name CAS Number
Water 007732-18-5
EH&S Department
Prepared by:
EH&S Department
Approved by:
11/05/2002
Approved Date:
Disclaimer:
"The data included herein are presented in accordance with various environment, health and
safety regulations. It is the responsibility of a recipient of the data to remain currently informed
on chemical hazard information, to design and update its own program and to comply with all
national, federal, state and local laws and regulations applicable to safety, occupational health,
right-to-know and environmental protection."
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