MATERIAL SAFETY DATA SHEETS
MS 61318
For FUJIFILM Product Code: 61318
Description: CN-16S N4 STAB SUC 1.9L
Carton Identification Code: 850119
Covers 1 part:
Bottle Identification Code: 750119
Note: Material Safety Data Sheets must be kept on the premises where chemicals are stored and used.
They must be made readily available to all persons concerned with this chemistry. These may including
transport operators, store persons, workers, machine operators, retail / medical staff, store managers,
building owners and managers, emergency services, and government or industry inspectors.
AUSTRALIA: NEW ZEALAND:
Emergency Information: (02) 9466 2721 (09) 414 0400
FUJIFILM Australia Pty Ltd ABN 80 000 064 433
114 Old Pittwater Road
Brookvale, NSW 2100
Phone: (02) 9466 2600 Fax: (02) 9938 1975
Visit our website: http://www.fujifilm.com.au for the latest version of this MSDS.
Issue Date: April 2008
MATERIAL SAFETY DATA SHEET
Issued by: FUJIFILM Australia Pty Ltd Phone: (02) 9466 2600
FUJIFILM (NZ) Limited Phone: (09) 414 0400
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Product Name: CN-16S N4 SUC
This revision issued: April, 2008
Emergency Information: (02) 9466 2721 (Aust), (09) 414 0400 (NZ)
Page: 1 of 5
SECTION 1 - IDENTIFICATION OF CHEMICAL PRODUCT AND COMPANY
FUJIFILM Australia Pty Ltd ABN 80 000 064 433 FUJIFILM (NZ) Limited
114 Old Pittwater Rd Cnr William Pickering Dr & Bush Rd
Brookvale NSW 2100 Albany, Auckland
Phone: (02) 9466 2600 Fax: (02) 9938 1975 Phone (09) 414 0400
Emergency Information: (02) 9466 2721 (Aust), (09) 414 0400 (NZ) http://www.fujifilm.com.au/
Substance: Water solution of ingredients.
CN-16S N4 SUC
Trade Name:
Product Code: 850119 750119
Product Use: Photographic reagent.
Creation Date: March, 2006
Revision Date: April, 2008
Based on suppliers MSDS dated 26 April 2005
SECTION 2 - HAZARDS IDENTIFICATION
Statement of Hazardous Nature
This product is classified as: Hazardous according to the criteria of ASCC Australia.
Not a Dangerous Good according to the Australian Dangerous Goods (ADG) Code.
Risk Phrases: R36/38. Irritating to eyes and skin.
Safety Phrases: S24/25, S36/37. Avoid contact with skin and eyes. Wear suitable protective clothing and gloves.
SUSDP Classification: None allocated.
ADG Classification: None allocated. Not a Dangerous Good under the ADG Code.
UN Number: None allocated
Emergency Overview
Physical Description & colour: Pale yellow liquid.
Odour: No odour.
Major Health Hazards: irritating to eyes and skin.
Potential Health Effects
Inhalation
Short term exposure: Available data indicates that this product is not harmful. In addition product is unlikely to
cause any discomfort or irritation.
Long Term exposure: No data for health effects associated with long term inhalation.
Skin Contact:
Short term exposure: Available data indicates that this product is not harmful. It should present no hazards in
normal use. However product is a skin irritant. Symptoms may include itchiness and reddening of contacted skin.
Other symptoms may also become evident, but all should disappear once exposure has ceased.
Long Term exposure: No data for health effects associated with long term skin exposure.
Eye Contact:
Short term exposure: This product is an eye irritant. Symptoms may include stinging and reddening of eyes and
watering which may become copious. Other symptoms may also become evident. If exposure is brief, symptoms
should disappear once exposure has ceased. However, lengthy exposure or delayed treatment may cause permanent
damage.
Long Term exposure: No data for health effects associated with long term eye exposure.
Ingestion:
Short term exposure: Significant oral exposure is considered to be unlikely. This product is unlikely to cause any
irritation problems in the short or long term.
Long Term exposure: No data for health effects associated with long term ingestion.
MATERIAL SAFETY DATA SHEET
Issued by: FUJIFILM Australia Pty Ltd Phone: (02) 9466 2600
FUJIFILM (NZ) Limited Phone: (09) 414 0400
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Product Name: CN-16S N4 SUC
This revision issued: April, 2008
Emergency Information: (02) 9466 2721 (Aust), (09) 414 0400 (NZ)
Page: 2 of 5
Carcinogen Status:
ASCC: No significant ingredient is classified as carcinogenic by ASCC.
NTP: No significant ingredient is classified as carcinogenic by NTP.
IARC: No significant ingredient is classified as carcinogenic by IARC.
SECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTS
TWA (mg/m3) STEL (mg/m3)
Ingredients CAS No Conc,%
3-Isothiazolone, 2-methyl- 2682-20-4 <1 not set not set
Ethoxylated alcohol 26183-52-8 <5 not set not set
Water 7732-18-5 to 100 not set not set
This is a commercial product whose exact ratio of components may vary slightly. Minor quantities of other non
hazardous ingredients are also possible.
The TWA exposure value is the average airborne concentration of a particular substance when calculated over a normal 8 hour working day for a 5
day working week. The STEL (Short Term Exposure Limit) is an exposure value that may be equalled (but should not be exceeded) for no longer
than 15 minutes and should not be repeated more than 4 times per day. There should be at least 60 minutes between successive exposures at the
STEL. The term "peak "is used when the TWA limit, because of the rapid action of the substance, should never be exceeded, even briefly.
SECTION 4 - FIRST AID MEASURES
General Information:
You should call The Poisons Information Centre if you feel that you may have been poisoned, burned or irritated by
this product. The number is 13 1126 from anywhere in Australia (0800 764 766 in New Zealand) and is available at all
times. Have this MSDS with you when you call.
Inhalation: First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor.
Skin Contact: Wash gently and thoroughly with warm water (use non-abrasive soap if necessary) for 10-20 minutes
or until product is removed. Under running water, remove contaminated clothing, shoes and leather goods (e.g.
watchbands and belts) and completely decontaminate them before reuse or discard. If irritation persists, repeat
flushing and seek medical attention.
Eye Contact: Immediately flush the contaminated eye(s) with lukewarm, gently flowing water for 20 minutes or until
the product is removed, while holding the eyelid(s) open. Take care not to rinse contaminated water into the
unaffected eye or onto the face. Obtain medical attention immediately. Take special care if exposed person is wearing
contact lenses.
Ingestion: If product is swallowed or gets in mouth, do NOT induce vomiting; wash mouth with water and give some
water to drink. If symptoms develop, or if in doubt contact a Poisons Information Centre or a doctor.
SECTION 5 - FIRE FIGHTING MEASURES
Fire and Explosion Hazards: There is no risk of an explosion from this product under normal circumstances if it is
involved in a fire.
Only small quantities of decomposition products are expected from this products at temperatures normally achieved in
a fire. This will only occur after heating to dryness.
Fire decomposition products from this product are likely to be irritating if inhaled.
Extinguishing Media: Not Combustible. Use extinguishing media suited to burning materials.
Fire Fighting: If a significant quantity of this product is involved in a fire, call the fire brigade.
Flash point: Does not burn.
Does not burn.
Upper Flammability Limit:
Lower Flammability Limit: Does not burn.
Autoignition temperature: Not applicable - does not burn.
Flammability Class: Does not burn.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
Accidental release: This product is sold in small packages, and the accidental release from one of these is not
usually a cause for concern. For minor spills, clean up, rinsing to sewer and put empty container in garbage. Although
no special protective clothing is normally necessary because of occasional minor contact with this product, it is good
MATERIAL SAFETY DATA SHEET
Issued by: FUJIFILM Australia Pty Ltd Phone: (02) 9466 2600
FUJIFILM (NZ) Limited Phone: (09) 414 0400
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Product Name: CN-16S N4 SUC
This revision issued: April, 2008
Emergency Information: (02) 9466 2721 (Aust), (09) 414 0400 (NZ)
Page: 3 of 5
practice to wear impermeable gloves when handling chemical products. In the event of a major spill, prevent spillage
from entering drains or water courses and call emergency services.
SECTION 7 - HANDLING AND STORAGE
Handling: Keep exposure to this product to a minimum, and minimise the quantities kept in work areas. Check
Section 8 of this MSDS for details of personal protective measures, and make sure that those measures are followed.
The measures detailed below under "Storage" should be followed during handling in order to minimise risks to
persons using the product in the workplace. Also, avoid contact or contamination of product with incompatible
materials listed in Section 10.
Storage: Make sure that the product does not come into contact with substances listed under "Incompatibilities" in
Section 10. Some liquid preparations settle or separate on standing and may require stirring before use. Check
packaging - there may be further storage instructions on the label.
SECTION 8 - EXPOSURE CONTROLS AND PERSONAL PROTECTION
The following Australian Standards will provide general advice regarding safety clothing and equipment:
Respiratory equipment: AS/NZS 1715, Protective Gloves: AS 2161, Industrial Clothing: AS2919, Industrial Eye
Protection: AS1336 and AS/NZS 1337, Occupational Protective Footwear: AS/NZS2210.
TWA (mg/m3) STEL (mg/m3)
Exposure Limits
Exposure limits have not been established by ASCC for any of the significant ingredients in this product.
No special equipment is usually needed when occasionally handling small quantities. The following instructions are
for bulk handling or where regular exposure in an occupational setting occurs without proper containment systems.
Ventilation: No special ventilation requirements are normally necessary for this product. However make sure that
the work environment remains clean and that vapours and mists are minimised.
Eye Protection: Protective glasses or goggles should be worn when this product is being used. Failure to protect
your eyes may cause them harm. Emergency eye wash facilities are also recommended in an area close to where
this product is being used.
Skin Protection: Prevent skin contact by wearing impervious gloves, clothes and, preferably, apron. Make sure that
all skin areas are covered. See below for suitable material types.
Protective Material Types: We suggest that protective clothing be made from the following materials: Neoprene.
Respirator: Usually, no respirator is necessary when using this product. However, if you have any doubts consult
the Australian Standard mentioned above.
Eyebaths or eyewash stations and safety deluge showers should be provided near to where this product is being
used.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES:
Physical Description & colour: Pale yellow liquid.
Odour: No odour.
Boiling Point: Approximately 100掳 at 100kPa.
C
Freezing/Melting Point: Approximately 0掳 C.
Volatiles: Water component.
Vapour Pressure: 2.37 kPa at 20掳 (water vapour pressure).
C
Vapour Density: No data.
Specific Gravity: 1.01 approx
Water Solubility: Completely soluble in water.
pH: 8.3 at 25掳C
Volatility: No data.
Odour Threshold: No data.
Evaporation Rate: No data.
Coeff Oil/water distribution: No data
Autoignition temp: Not applicable - does not burn.
SECTION 10 - STABILITY AND REACTIVITY
Reactivity: This product is unlikely to react or decompose under normal storage conditions. However, if you have
any doubts, contact the supplier for advice on shelf life properties.
MATERIAL SAFETY DATA SHEET
Issued by: FUJIFILM Australia Pty Ltd Phone: (02) 9466 2600
FUJIFILM (NZ) Limited Phone: (09) 414 0400
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Product Name: CN-16S N4 SUC
This revision issued: April, 2008
Emergency Information: (02) 9466 2721 (Aust), (09) 414 0400 (NZ)
Page: 4 of 5
Conditions to Avoid: None known.
Incompatibilities: No particular Incompatibilities.
Fire Decomposition: Only small quantities of decomposition products are expected from this products at
temperatures normally achieved in a fire. This will only occur after heating to dryness. Carbon dioxide, and if
combustion is incomplete, carbon monoxide and smoke. Nitrogen and its compounds, and under some
circumstances, oxides of nitrogen. Occasionally hydrogen cyanide gas. Oxides of sulfur (sulfur dioxide is a respiratory
hazard) and other sulfur compounds. Most will have a foul odour. Water. Carbon monoxide poisoning produces
headache, weakness, nausea, dizziness, confusion, dimness of vision, disturbance of judgment, and
unconsciousness followed by coma and death. Hydrogen cyanide poisoning signs and symptoms are weakness,
dizziness, headache, nausea, vomiting, coma, convulsions, and death. Death results from respiratory arrest.
Hydrogen cyanide gas acts very rapidly; symptoms and death can both occur quickly.
Polymerisation: This product will not undergo polymerisation reactions.
SECTION 11 - TOXICOLOGICAL INFORMATION
Local Effects:
Target Organs: skin, eyes
Classification of Hazardous Ingredients
Ingredient Risk Phrases
No ingredient mentioned in the List of Designated Hazardous Substances is present in this product at hazardous
concentrations.
SECTION 12 - ECOLOGICAL INFORMATION
Insufficient data to be sure of status.
SECTION 13 - DISPOSAL CONSIDERATIONS
Disposal: There are many pieces of legislation covering waste disposal and they differ in each state and territory, so
each user must refer to laws operating in their area. In some areas, certain wastes must be tracked. The Hierarchy of
Controls seems to be common - the user should investigate: Reduce, Reuse, and Recycle and only if all else fails
should disposal be considered. Note that properties of a product may change in use, so that the following suggestions
may not always be appropriate. The following may help you in properly addressing this matter for this product. This
product may be recycled if unused, or if it has not been contaminated so as to make it unsuitable for its intended use.
If it has been contaminated, it may be possible to separate the contamination in some way. Only if neither of these
options is suitable, consider landfill.
SECTION 14 - TRANSPORT INFORMATION
ADG Code: This product is not classified as a Dangerous Good. No special transport conditions are necessary
unless required by other regulations.
SECTION 15 - REGULATORY INFORMATION
AICS: All of the significant ingredients in this formulation are compliant with NICNAS regulations.
SECTION 16 - OTHER INFORMATION
This MSDS contains only safety-related information. For other data see product literature.
A more recent version of this MSDS might be found at http://www.fujifilm.com.au/
Acronyms:
th
ADG Code Australian Code for the Transport of Dangerous Goods by Road and Rail (7 edition)
AICS Australian Inventory of Chemical Substances
Office of the Australian Safety and Compensation Council
ASCC
CAS number Chemical Abstracts Service Registry Number
Hazchem Code Emergency action code of numbers and letters that provide information to emergency
services especially firefighters
MATERIAL SAFETY DATA SHEET
Issued by: FUJIFILM Australia Pty Ltd Phone: (02) 9466 2600
FUJIFILM (NZ) Limited Phone: (09) 414 0400
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Product Name: CN-16S N4 SUC
This revision issued: April, 2008
Emergency Information: (02) 9466 2721 (Aust), (09) 414 0400 (NZ)
Page: 5 of 5
IARC International Agency for Research on Cancer
NOS Not otherwise specified
National Toxicology Program (USA)
NTP
R-Phrase Risk Phrase
SUSDP Standard for the Uniform Scheduling of Drugs & Poisons
UN Number United Nations Number
THIS MSDS SUMMARISES OUR BEST KNOWLEDGE OF THE HEALTH AND SAFETY HAZARD INFORMATION OF THE PRODUCT AND
HOW TO SAFELY HANDLE AND USE THE PRODUCT IN THE WORKPLACE. EACH USER MUST REVIEW THIS MSDS IN THE CONTEXT OF
HOW THE PRODUCT WILL BE HANDLED AND USED IN THE WORKPLACE.
IF CLARIFICATION OR FURTHER INFORMATION IS NEEDED TO ENSURE THAT AN APPROPRIATE RISK ASSESSMENT CAN BE MADE,
THE USER SHOULD CONTACT THIS COMPANY SO WE CAN ATTEMPT TO OBTAIN ADDITIONAL INFORMATION FROM OUR SUPPLIERS
OUR RESPONSIBILITY FOR PRODUCTS SOLD IS SUBJECT TO OUR STANDARD TERMS AND CONDITIONS, A COPY OF WHICH IS SENT
TO OUR CUSTOMERS AND IS ALSO AVAILABLE ON REQUEST.
Please read all labels carefully before using product.
This MSDS is prepared in accord with the ASCC document 鈥淣ational Code of Practice for the Preparation
of Material Safety Data Sheets鈥? 2nd Edition [NOHSC:2011(2003)]
Copyright 漏 Kilford & Kilford Pty Ltd, April, 2008.
http://www.kilford.com.au/ Phone (02) 9251 4532
MATERIAL SAFETY DATA SHEET
Issued by: FUJIFILM Australia Pty Ltd Phone: (02) 9466 2600
FUJIFILM (NZ) Limited Phone: (09) 414 0400
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
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