MATERIAL SAFETY DATA SHEET
800-533-6623
Emergency Phone: HAZARD RATING
1 4=EXTREME
Toxicity
800-533-6623
Information Phone:
1 3=HIGH
Fire
973-690-5808
Fax Number:
0 2=MODERATE
Reactivity
N/A 1=SLIGHT
Special
0=INSIGNIFICANT
PRODUCT IDENTIFICATION
GRAVEX铮? GR 3-30 US
Product Name:
Cation/Anion exchange resins (Hydrogen/Hydroxide forms)
Ionic Form:
MS-GR330US
MSDS Code:
1/21/03
Effective Date:
1. COMPONENT INFORMATION
No. CAS No. AMT.(%)
1) Sulfonated copolymer of styrene and 069011-20-7 10-30
divinylbenzene in the hydrogen form.
2) Trimethylamine functionalized, 069011-18-3 10-30
chloromethylated copolymer of styrene and
divinylbenzene in the hydroxide form.
3) Water 007732-18-5 40-70
2. PHYSICAL DATA
Not applicable
MELTING POINT:
Not applicable
BOILING POINT:
VAPOR PRESSURE (mm Hg): 17mm Hg @20掳C/68掳F
Not applicable
VAPOR DENSITY (Air=1):
Insoluble
SOLUBILITY IN WATER:
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72 LOCKWOOD STREET, NEWARK, NEW JERSEY 07105
Graver Technologies Product: GRAVEX GR 3-30 US
MSDS Code: MS-GR330US
Date: 1/21/03
2. PHYSICAL DATA (continued)
1.1 - 1.4
SPECIFIC GRAVITY (water=1):
< 1 Water
EVAPORATION RATE (Butyl acetate=1):
50-65% Water
PERCENT VOLATILITY:
White to dark amber solid (beads).
APPEARANCE:
Slight amine odor
ODOR:
3. EXPOSURE LIMIT INFORMATION
OSHA ACGIH
COMPONENT NO. TWA STEL TLV STEL
1 None None None None
2 None None None None
3 None None None None
4. FIRE AND EXPLOSION HAZARD DATA
FLASH POINT: Not Applicable
METHOD USED: Not Applicable
AUTO-IGNITION TEMPERATURE: 500掳C/932掳F. Product is not combustible until
moisture is removed, then resin starts to burn in flame at 230掳C/446掳F.
LOWER EXPLOSIVE LIMIT: Not Applicable
UPPER EXPLOSIVE LIMIT: Not Applicable
FIRE FIGHTING EQUIPMENT: Wear positive pressure self-contained breathing
apparatus.
EXTINGUISHING AGENTS: Use the following extinguishing media when fighting
fires involving this material: 1) carbon dioxide 2) dry chemical 3) water spray
5. REACTIVITY DATA
STABILITY: Stable under normal handling and storage conditions.
(see incompatibility statement).
Page 2 of 6
Graver Technologies Product: GRAVEX GR 3-30 US
MSDS Code: MS-GR330US
Date: 1/21/03
5. REACTIVITY DATA (continued)
INCOMPATIBILITY: (SPECIFIC MATERIALS TO AVOID) WARNING:
Oxidizing agents such as nitric acid attack organic ion exchange resin under
certain conditions and could result in a slightly degraded resin up to an explosive
reaction. Before using strong oxidizing agents, consult sources knowledgeable in
handling such materials.
HAZARDOUS DECOMPOSITION PRODUCTS: Thermal decomposition may yield
the following: Alkylbenzenes, vinylbenzenes, naphthalene, benzaldehydes,
phenol, sulfur oxides, organic sulfates, organic amines, carbon dioxide,
hydrochloric acid, carbon monoxide, nitrogen oxides, ammonia, chlorine,
methyl chloride, water
HAZARDOUS POLYMERIZATION: Product will not undergo polymerization.
6. ENVIRONMENTAL AND DISPOSAL INFORMATION
ACTION TO TAKE FOR SPILLS/LEAKS: Sweep up. Caution: May be slippery.
DISPOSAL METHOD: DO NOT DUMP INTO ANY SEWERS, ON THE GROUND OR
INTO ANY BODY OF WATER. Bury resin in licensed landfill, or burn in approved
incinerator according to local, state, and federal regulations. For resin
contaminated with hazardous material, dispose of mixture as hazardous material
according to local, state, and federal regulations. Waste characterizations and
compliance with applicable laws are the responsibility solely of the waste
generator. GRAVER TECHNOLOGIES, INC. HAS NO CONTROL OVER THE
MANAGEMENT PRACTICES OR MANUFACTURING PROCESSES OF PARTIES
HANDLING OR USING THIS MATERIAL.
7. HEALTH HAZARD DATA
EYE: May cause severe eye irritation. May cause moderate corneal injury. Effects are
likely to heal. Flush with water for a minimum of 15 minutes. Consult a physician if
irritation persists.
SKIN CONTACT: Prolonged or repeated exposure may cause skin irritation. If irritation
occurs, wash affected area with water. Consult a physician if irritation persists.
SKIN ABSORPTION: Skin absorption is unlikely due to physical properties.
INGESTION: Single dose oral LD50 has not been determined. Single dose oral toxicity
is believed to be low. No hazards anticipated from ingestion incidental to industrial
exposure. If swallowed, call a physician.
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Graver Technologies Product: GRAVEX GR 3-30 US
MSDS Code: MS-GR330US
Date: 1/21/03
7. HEALTH HAZARD DATA (continued)
INHALATION: Vapors are unlikely due to physical properties.
SYSTEM & OTHER EFFECTS: No specific data available, however, repeated
exposures are not anticipated to cause any significant adverse effects.
8. PERSONAL PROTECTION MEASURES
EXPOSURE GUIDELINES: None established.
VENTILATION: Good general ventilation should be sufficient.
RESPIRATORY PROTECTION: A respiratory protection program meeting
OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever
workplace conditions warrant a respirator鈥檚 use. None required under normal
operating conditions.
EYE PROTECTION: Use safety glasses ANSI Z87.1 or approved equivalent.
SKIN & HAND PROTECTION: Avoid skin contact. When using this substance, use
skin protection (clean body-covering clothing). Cotton, latex, rubber or canvas
gloves for the hands.
OTHER PROTECTIVE EQUIPMENT: Facilities storing or utilizing this material should
be equipped with an eyewash facility.
9. STORAGE AND HANDLING INFORMATION
STORAGE CONDITIONS: The minimum recommended storage temperature for this
material is 3掳C/38掳F. The maximum recommended storage temperature for this
material is 60掳C/140掳F. Avoid repeated freezing; beads may fracture.
Page 4 of 6
Graver Technologies Product: GRAVEX GR 3-30 US
MSDS Code: MS-GR330US
Date: 1/21/03
9. STORAGE AND HANDLING INFORMATION (continued)
HANDLING PROCEDURES: The maximum recommended operating temperature for
this material is 60掳C/140掳F. NOTE: This product as supplied is a whole bead ion
exchange resin and may produce slight eye irritation. However, the ground form of
this resin should be treated as a severe eye irritant. Worker exposure to ground
resins can be controlled with local exhaust ventilation at the point of dust
generation, or the use of suitable personal protective equipment (dust/mist air-
purifying respirator and safety goggles). Properly designed equipment is vital if
these ion exchange resins are to be used in conjunction with strong oxidizing
agents such as nitric acid to prevent a rapid build up of pressure and possible
explosion. Consult a source knowledgeable in the handling of these materials
before proceeding. Do not pack column with dry ion exchange resins. Dry
beads expand when wetted; this expansion can cause glass columns to shatter.
10. REGULATORY INFORMATION
WORKPLACE CLASSIFICATIONS: This product is considered non-hazardous under
OSHA Hazard Communication Standard (29CFR 1910.1200).
This product is not a 鈥楥ontrolled Product鈥? under the Canadian Workplace
Hazardous Materials Information System (WHMIS).
TRANSPORTATION CLASSIFICATIONS: US DOT Hazard Class - Non-regulated
EMERGENCY PLANNING & COMMUNITY RIGHT-TO-KNOW (SARA TITLE 3):
Section 311/312 Categorizations (40CFR 370) This product is not a hazardous
chemical under 29CFR 1910.1200, and therefore is not covered by Title III of
SARA.
Section 313 Information (40CFR 372) This product does not contain a chemical
which is listed in Section 313 above de minimis concentrations.
Page 5 of 6
Graver Technologies Product: GRAVEX GR 3-30 US
MSDS Code: MS-GR330US
Date: 1/21/03
EMERGENCY PLANNING & COMMUNITY RIGHT-TO-KNOW (SARA TITLE 3):
CERCLA Information (40CFR 302.4) Releases of this material to air, land, or
water are not reportable to the National Response Center under the
Comprehensive Environmental Response, Compensation, and Liability Act
(CERCLA) or to state and local emergency planning committee under the
Superfund Amendments and Reauthorization Act (SARA Title III Section 304).
RCRA Information When a decision is made to discard this material as
supplied, it does not meet RCRA鈥檚 characteristic definition of ignitability,
corrosivity, or reactivity, and is not listed in 40CFR 261.33. The toxicity
characteristic (TC), however, has not been evaluated by the Toxicity Characteristic
Leaching Procedure (TCLP).
Chemical Control Law Status All components of this product are listed or are
excluded from listing on the U.S. Toxic Substance Control Act (TSCA) Chemical
Substance Inventory.
GRAVEX铮? is a trademark of Graver Technologies
Abbreviations:
ACGIH - American Conference of Governmental Industrial Hygienists
OSHA - Occupational Safety and Health Administration
TLV - Threshold limit Value
TWA - Time Weighted Average
STEL - Short Term Exposure Limit
The above information contained herein relates to the specific material identified. Graver Technologies
believes that such information is accurate and reliable as of the date of this material safety data sheet,
but no representation, guarantee or warranty, express or implied, is made as to the accuracy, reliability,
or completeness of the information. Graver Technologies urges persons receiving this information to
make their own determination as to the information鈥檚 suitability and completeness for their particular
application. Consult Graver Technologies for further information.
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