**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 100-11-8 |4-Nitrobenzyl bromide | 99.0 | 202-820-6 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 20/21/22
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed.The
toxicological properties of this material have not been fully
investigated.
Potential Health Effects
Eye:
No information regarding eye irritation and other potential effects
was found.
Skin:
No information regarding skin irritation and other potential effects
was found.
Ingestion:
The toxicological properties of this substance have not been fully
investigated.
Inhalation:
The toxicological properties of this substance have not been fully
investigated.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Immediately flush
eyes with plenty of water for at least 15 minutes, occasionally
lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Combustion generates toxic fumes.
Extinguishing Media:
Do NOT use water directly on fire. Use dry chemical or carbon
dioxide.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Sweep up or absorb material, then place into a suitable clean, dry,
closed container for disposal. Avoid generating dusty conditions.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Minimize dust generation and accumulation. Avoid contact with eyes,
skin, and clothing. Keep container tightly closed. Avoid ingestion
and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 100-11-8:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystals
Color: beige
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 98.00 - 100.00 deg C
Autoignition Temperature: Not available.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: 125 deg C
Solubility in water: insoluble
Specific Gravity/Density:
Molecular Formula: C7H6BrNO2
Molecular Weight: 216.03
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide, hydrogen bromide,
nitrogen.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 100-11-8: XS7967000
LD50/LC50:
Not available.
Carcinogenicity:
4-Nitrobenzyl bromide -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2811
Packing Group: II
IMO
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing Group: II
RID/ADR
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28 After contact with skin, wash immediately
with...
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 100-11-8: No information available.
Canada
CAS# 100-11-8 is listed on Canada's NDSL List.
CAS# 100-11-8 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 100-11-8 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 2/17/1998 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
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| ALL MSDS PAGES IN THIS GROUP
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Potassium hexacyanocobaltate(III), 95%
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Isatin, 98%
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| 10039-54-0 |
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Dysprosium Oxide, Reagent, 98% (Titr.)
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3,3-Dichloro-2-methoxytetrahydrofuran, 98%
| 0-00-1 |
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| 621-36-3 |
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| 853-39-4 |
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Decyl alcohol, 99%
| 112-30-1 |
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2-Ethylhexanoyl chloride, 98%
| 760-67-8 |
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| 3229-00-3 |
|
Nitrobenzo-18-Crown-6, 99+%
| 53408-96-1 |
|
Q-switch solution kit ii for neodymium lasers
| 21016-22-8 |
|
Alcian Blue, certified, 98% (UV-VIS)
| 33864-99-2 |
|
4-Cholesten-3-one, 99.5+%(tlc)
| 601-57-0 |
|
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| 7553-56-2 |
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| 1194-98-5 |
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| 10101-98-1 |
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| 594-19-4 |
|
Piperonyl alcohol, 98%
| 495-76-1 |
|
Iron
| 7439-89-6 |
|
Dithioloxalic Acid Dipotassium Salt, 99+% (Titr.)
| 20267-56-5 |
|
1-Naphthalenesulfonic acid, dihydrate, 94% (titr.)
| 85-47-2 |
|
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| 1309-37-1 |
|
Tricosane, 98% (gc)
| 638-67-5 |
|
L-(-)-Threitol, 98%
| 2319-57-5 |
|
1,8-Diiodooctane, 98+%, Stabilized Over Copper
| 24772-63-2 |
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Polyamide resin
| |
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Isoamyl alcohol
| 123-51-3 |
|
p-(Imidazol-1-yl)phenol, 97% (Titr.)
| 10041-02-8 |
|
Thymol, 99%
| 89-83-8 |
|
4-Hydroxybenzoic acid, p.a.
| 99-94-5 |
|
Cyclopropyl Phenyl Carbinol, 97%
| 1007-03-0 |
|
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| 92511-32-5 |
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| 0-01-1 |
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| 504-24-5 |
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| 18304-13-7 |
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| 118-74-1 |
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| 6627-88-9 |
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