**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 33864-99-2 |Alcian blue | 98 | 251-705-7 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: None Listed.
Risk Phrases: None Listed.
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully
investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological
properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties
of this substance have not been fully investigated.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Dusts at sufficient concentrations can form
explosive mixtures with air. During a fire, irritating and highly
toxic gases may be generated by thermal decomposition or combustion.
Use water spray to keep fire-exposed containers cool.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry
chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up or absorb material, then place into a
suitable clean, dry, closed container for disposal. Avoid generating
dusty conditions. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Minimize dust
generation and accumulation. Avoid contact with eyes, skin, and
clothing. Keep container tightly closed. Avoid ingestion and
inhalation.
Storage:
Store in a tightly closed container. Keep from contact with
oxidizing materials. Store in a cool, dry, well-ventilated area away
from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 33864-99-2:
United Kingdom, WEL - TWA: (listed as copper): 0.2 mg/m3 TWA (fum
1 mg/m3 TWA (dust and mist)
United Kingdom, WEL - STEL: (listed as copper): 0.6 mg/m3 STEL
(fume); 2 mg/m3 STEL (dust and mist)
United States OSHA: 0.1 mg/m3 TWA (fume); 1 mg/m3 TWA (dusts and
mists) (listed under Copper).
Belgium - TWA: (listed as copper): 0.2 mg/m3 VLE (fume); 1 mg/m3
(dust and mist)
France - VME: (listed as copper): 0.2 mg/m3 VME (fume); 1 mg/m3 V
(dust, as Cu)
France - VLE: (listed as copper): 2 mg/m3 VLE (dust, as Cu)
Germany: (listed as copper): 0.2 mg/m3 VME (fume); 1 mg/m3 VME (d
as Cu)
Malaysia: (listed as copper): 0.2 mg/m3 TWA (fume, as Cu); 1 mg/m
TWA (dust and mist, as Cu)
Netherlands: (listed as copper): 0.2 mg/m3 MAC (smoke); 1 mg/m3 M
(dust)
Russia: (listed as copper): 1 mg/m3 TWA (dust)
Russia: (listed as copper): 0.5 mg/m3 STEL (dust)
Spain: (listed as copper): 0.2 mg/m3 VLA-ED (fume); 1 mg/m3 VLA-E
(dust and mist, as Cu)
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: Not available.
Odor: none reported
pH: Not available.
Vapor Pressure: Negligible.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 148 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: moderately soluble
Specific Gravity/Density:
Molecular Formula: C56H68Cl4CuN16S4
Molecular Weight: 1298.88
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, oxides of nitrogen, oxides of
sulfur, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 33864-99-2 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Alcian blue -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
WGK (Water Danger/Protection)
CAS# 33864-99-2: No information available.
Canada
CAS# 33864-99-2 is listed on Canada's DSL List.
CAS# 33864-99-2 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 33864-99-2 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 7/13/1999 Revision #3 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
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Zinc copper couple
| 53801-63-1 |
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Hydroquinone
| 123-31-9 |
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Mordant yellow 10
| 6054-99-5 |
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Potassium hexacyanocobaltate(III), 95%
| 13963-58-1 |
|
Isatin, 98%
| 91-56-5 |
|
Hydroxylamine Sulfate
| 10039-54-0 |
|
Hydroxylamine hydrochloride, Reagent ACS, 96+% (Titr.)
| 5470-11-1 |
|
Hypophosphorous acid, 30 - 50% in water
| 6303-21-5 |
|
4-(4-Nitrobenzyl)pyridine, 98%
| 1083-48-3 |
|
Dysprosium Oxide, Reagent, 98% (Titr.)
| 1308-87-8 |
|
3,3-Dichloro-2-methoxytetrahydrofuran, 98%
| 0-00-1 |
|
m-Tolylacetic acid, 97% (gc)
| 621-36-3 |
|
DL-Homocysteic acid , 98%
| 504-33-6 |
|
5-Chlorovaleronitrile, 97%
| 6280-87-1 |
|
N,N-Dimethylaniline
| 121-69-7 |
|
Decafluorobenzophenone, 98%
| 853-39-4 |
|
Decyl alcohol, 99%
| 112-30-1 |
|
2-Ethylhexanoyl chloride, 98%
| 760-67-8 |
|
Pentaerythrityl tetrabromide, 98%
| 3229-00-3 |
|
Nitrobenzo-18-Crown-6, 99+%
| 53408-96-1 |
|
Q-switch solution kit ii for neodymium lasers
| 21016-22-8 |
|
Alcian Blue, certified, 98% (UV-VIS)
| 33864-99-2 |
|
4-Cholesten-3-one, 99.5+%(tlc)
| 601-57-0 |
|
Iodine
| 7553-56-2 |
|
Iodine Solution Wij's
| 64-19-7 |
|
4-Nitrobenzyl bromide, 99%
| 100-11-8 |
|
N-Isopropylcyclohexylamine, 99%
| 1194-98-5 |
|
Nickel(II) sulfate heptahydrate, for nickel plating, DIN 50970
| 10101-98-1 |
|
Tert.-butyllithium, 1.5m solution in pentane
| 594-19-4 |
|
Piperonyl alcohol, 98%
| 495-76-1 |
|
Iron
| 7439-89-6 |
|
Dithioloxalic Acid Dipotassium Salt, 99+% (Titr.)
| 20267-56-5 |
|
1-Naphthalenesulfonic acid, dihydrate, 94% (titr.)
| 85-47-2 |
|
Iron (III) Oxide Anhydrous
| 1309-37-1 |
|
Tricosane, 98% (gc)
| 638-67-5 |
|
L-(-)-Threitol, 98%
| 2319-57-5 |
|
1,8-Diiodooctane, 98+%, Stabilized Over Copper
| 24772-63-2 |
|
Polyamide resin
| |
|
Isoamyl alcohol
| 123-51-3 |
|
p-(Imidazol-1-yl)phenol, 97% (Titr.)
| 10041-02-8 |
|
Thymol, 99%
| 89-83-8 |
|
4-Hydroxybenzoic acid, p.a.
| 99-94-5 |
|
Cyclopropyl Phenyl Carbinol, 97%
| 1007-03-0 |
|
3-Exo-Aminobicyclo??2.2.1??Hept-5-ene-2-Exo-Carboxylic Acid, 98%
| 92511-32-5 |
|
(2R,3R)-1-Carboxy-4-Chloro-2,3-Dihydroxy-Cyclohexa-4,6-Diene, 95%
| 0-01-1 |
|
4-Aminopyridine
| 504-24-5 |
|
Cyanoethyl sucrose
| 18304-13-7 |
|
2-Amino-6-chloropurine, 99+%
| 10310-21-1 |
|
Hexachlorobenzene, 99%
| 118-74-1 |
|
4-Allyl-2,6-Dimethoxyphenol, Tech., 90+ %
| 6627-88-9 |
|
|