**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 13963-58-1 |Potassium hexacyanocobaltate(III) | 95 | 237-742-1 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T
Risk Phrases: 22 32 33
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed. Contact with acids liberates very toxic gas.
Danger of cumulative effects.Light sensitive.Cancer suspect agent.The
toxicological properties of this material have not been fully
investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. Harmful if absorbed through the skin.
Ingestion:
Harmful if swallowed. May cause irritation of the digestive tract.
Inhalation:
May cause respiratory tract irritation. Harmful if inhaled.
Chronic:
Experimental carcinogen.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry
chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Avoid generating dusty conditions. Provide
ventilation. Cover with dry earth, dry sand, or other non-combustible
material followed with plastic sheet to minimize spreading and
contact with water. Stop leak only if you can do so without risk.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Minimize dust generation and
accumulation. Do not get in eyes, on skin, or on clothing. Keep
container tightly closed. Do not ingest or inhale. Store protected
from light. Use only in a chemical fume hood. Wash clothing before
reuse.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances. Store
protected from light.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Exposure Limits
CAS# 13963-58-1:
United Kingdom, WEL - TWA: (listed as cobalt compounds): 0.1 mg/m
TWA (as Co)
United Kingdom, WEL - STEL: (listed as cobalt compounds): 0.3 mg/
STEL (as Co)
Japan: (listed as cobalt compounds): 0.05 mg/m3 OEL (as Co)
Malaysia: (listed as cobalt, inorganic compounds): 0.02 mg/m3 TWA
Co)
Spain: (listed as cobalt, inorganic compounds): 0.02 mg/m3 VLA-ED
Co)
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystals
Color: Moist, Light-Yellow Crystals
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Freely Soluble.
Specific Gravity/Density: 1.8780g/cm3
Molecular Formula: C6CoK3N6
Molecular Weight: 332.34
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Contact with acid liberates gas. Sensitive to light.
Conditions to Avoid:
Incompatible materials, light, strong oxidants.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids.
Hazardous Decomposition Products:
Hydrogen cyanide, nitrogen oxides, carbon monoxide, carbon dioxide,
nitrogen.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 13963-58-1: GF9470000
LD50/LC50:
CAS# 13963-58-1: Oral, mouse: LD50 = 1529 mg/kg.
The toxicity of this product was partially based upon the hazards
associated with cobalt
Carcinogenicity:
Potassium hexacyanocobaltate(III) -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CYANIDES, INORGANIC, SOLID, N.O.S.*
Hazard Class: 6.1
UN Number: 1588
Packing Group: II
IMO
Shipping Name: CYANIDES, INORGANIC, SOLID, N.O.S.
Hazard Class: 6.1
UN Number: 1588
Packing Group: II
RID/ADR
Shipping Name: CYANIDES, INORGANIC, SOLID, N.O.S.
Hazard Class: 6.1
UN Number: 1588
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 22 Harmful if swallowed.
R 32 Contact with acids liberates very toxic gas.
R 33 Danger of cumulative effects.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 13963-58-1: No information available.
Canada
CAS# 13963-58-1 is listed on Canada's NDSL List.
CAS# 13963-58-1 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 13963-58-1 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 12/05/1998 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Zinc copper couple
| 53801-63-1 |
|
Hydroquinone
| 123-31-9 |
|
Mordant yellow 10
| 6054-99-5 |
|
Potassium hexacyanocobaltate(III), 95%
| 13963-58-1 |
|
Isatin, 98%
| 91-56-5 |
|
Hydroxylamine Sulfate
| 10039-54-0 |
|
Hydroxylamine hydrochloride, Reagent ACS, 96+% (Titr.)
| 5470-11-1 |
|
Hypophosphorous acid, 30 - 50% in water
| 6303-21-5 |
|
4-(4-Nitrobenzyl)pyridine, 98%
| 1083-48-3 |
|
Dysprosium Oxide, Reagent, 98% (Titr.)
| 1308-87-8 |
|
3,3-Dichloro-2-methoxytetrahydrofuran, 98%
| 0-00-1 |
|
m-Tolylacetic acid, 97% (gc)
| 621-36-3 |
|
DL-Homocysteic acid , 98%
| 504-33-6 |
|
5-Chlorovaleronitrile, 97%
| 6280-87-1 |
|
N,N-Dimethylaniline
| 121-69-7 |
|
Decafluorobenzophenone, 98%
| 853-39-4 |
|
Decyl alcohol, 99%
| 112-30-1 |
|
2-Ethylhexanoyl chloride, 98%
| 760-67-8 |
|
Pentaerythrityl tetrabromide, 98%
| 3229-00-3 |
|
Nitrobenzo-18-Crown-6, 99+%
| 53408-96-1 |
|
Q-switch solution kit ii for neodymium lasers
| 21016-22-8 |
|
Alcian Blue, certified, 98% (UV-VIS)
| 33864-99-2 |
|
4-Cholesten-3-one, 99.5+%(tlc)
| 601-57-0 |
|
Iodine
| 7553-56-2 |
|
Iodine Solution Wij's
| 64-19-7 |
|
4-Nitrobenzyl bromide, 99%
| 100-11-8 |
|
N-Isopropylcyclohexylamine, 99%
| 1194-98-5 |
|
Nickel(II) sulfate heptahydrate, for nickel plating, DIN 50970
| 10101-98-1 |
|
Tert.-butyllithium, 1.5m solution in pentane
| 594-19-4 |
|
Piperonyl alcohol, 98%
| 495-76-1 |
|
Iron
| 7439-89-6 |
|
Dithioloxalic Acid Dipotassium Salt, 99+% (Titr.)
| 20267-56-5 |
|
1-Naphthalenesulfonic acid, dihydrate, 94% (titr.)
| 85-47-2 |
|
Iron (III) Oxide Anhydrous
| 1309-37-1 |
|
Tricosane, 98% (gc)
| 638-67-5 |
|
L-(-)-Threitol, 98%
| 2319-57-5 |
|
1,8-Diiodooctane, 98+%, Stabilized Over Copper
| 24772-63-2 |
|
Polyamide resin
| |
|
Isoamyl alcohol
| 123-51-3 |
|
p-(Imidazol-1-yl)phenol, 97% (Titr.)
| 10041-02-8 |
|
Thymol, 99%
| 89-83-8 |
|
4-Hydroxybenzoic acid, p.a.
| 99-94-5 |
|
Cyclopropyl Phenyl Carbinol, 97%
| 1007-03-0 |
|
3-Exo-Aminobicyclo??2.2.1??Hept-5-ene-2-Exo-Carboxylic Acid, 98%
| 92511-32-5 |
|
(2R,3R)-1-Carboxy-4-Chloro-2,3-Dihydroxy-Cyclohexa-4,6-Diene, 95%
| 0-01-1 |
|
4-Aminopyridine
| 504-24-5 |
|
Cyanoethyl sucrose
| 18304-13-7 |
|
2-Amino-6-chloropurine, 99+%
| 10310-21-1 |
|
Hexachlorobenzene, 99%
| 118-74-1 |
|
4-Allyl-2,6-Dimethoxyphenol, Tech., 90+ %
| 6627-88-9 |
|
|