**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 100-41-4 |Ethyl benzene | 5-10 | 202-849-4 |
|----------------|--------------------------------------|----------|-----------|
| 108-87-2 |Methylcyclohexane | 70-75 | 203-624-3 |
|----------------|--------------------------------------|----------|-----------|
| 4039-32-1 |Silanamine, 1,1,1-trimethyl-N-(trimeth| 20 | 223-725-6 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: F C N
Risk Phrases: 11 35 20 51/53 65 67
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable. Causes severe burns. Harmful by inhalation. Toxic
to aquatic organisms, may cause long-term adverse effects in the
aquatic environment. Harmful: may cause lung damage if swallowed.
Vapours may cause drowsiness and dizziness.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns.
Ingestion:
Causes gastrointestinal tract burns. May cause lung damage.
Inhalation:
Harmful if inhaled. Causes chemical burns to the respiratory tract.
Inhalation of vapors may cause drowsiness and dizziness.
Chronic:
Not available.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes.
Ingestion:
Do not induce vomiting. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Will burn if involved in a fire. Flammable liquid
and vapor. Vapors may form an explosive mixture with air.
Extinguishing Media:
Do NOT use carbon dioxide. DO NOT USE WATER OR FOAM. Smother with
dry sand, dry clay, dry ground limestone (CaCO3), or use approved
Class D extinguishers.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Remove all sources of ignition.
Use a spark-proof tool.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Use spark-proof tools and explosion proof equipment. Do not breathe
dust, vapor, mist, or gas. Do not get in eyes, on skin, or on
clothing. Handle under an inert atmosphere. Use only in a chemical
fume hood.
Storage:
Keep away from sources of ignition. Store in a cool, dry place.
Store in a tightly closed container. Flammables-area. Corrosives
area. Store under nitrogen.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local explosion-proof ventilation to keep airborne levels to
acceptable levels.
Exposure Limits
CAS# 100-41-4:
United Kingdom, WEL - TWA: 100 ppm TWA; 441 mg/m3 TWA
United Kingdom, WEL - STEL: 125 ppm STEL; 552 mg/m3 STEL
United States OSHA: 100 ppm TWA; 435 mg/m3 TWA
Belgium - TWA: 100 ppm VLE; 442 mg/m3 VLE
Belgium - STEL: 125 ppm VLE; 551 mg/m3 VLE
France - VME: 100 ppm VME; 435 mg/m3 VME
Germany: 100 ppm TWA; 440 mg/m3 TWA
Germany: Skin absorber
Japan: 50 ppm OEL; 217 mg/m3 OEL
Malaysia: 100 ppm TWA; 434 mg/m3 TWA
Netherlands: 50 ppm MAC; 215 mg/m3 MAC
Russia: 50 mg/m3 TWA
Spain: 100 ppm VLA-ED; 441 mg/m3 VLA-ED
Spain: 200 ppm VLA-EC; 884 mg/m3 VLA-EC
CAS# 108-87-2:
United States OSHA: 500 ppm TWA; 2000 mg/m3 TWA
Belgium - TWA: 400 ppm VLE; 1633 mg/m3 VLE
France - VME: 400 ppm VME; 1600 mg/m3 VME
Germany: 200 ppm TWA; 810 mg/m3 TWA
Japan: 400 ppm OEL; 1600 mg/m3 OEL
Malaysia: 400 ppm TWA; 1610 mg/m3 TWA
Netherlands: 400 ppm MAC; 1600 mg/m3 MAC
Russia: 50 mg/m3 TWA
Spain: 400 ppm VLA-ED; 1630 mg/m3 VLA-ED
CAS# 4039-32-1:
United Kingdom, WEL - TWA: (listed as silica, amorphous): 6 mg/m3
(inhalable dust); 2.4 mg/m3 TWA (respirable dust)
United Kingdom, WEL - STEL: (listed as silica, amorphous): 18 mg/
STEL (inhalable dust); 7.2 mg/m3 STEL (respirable dust)
Russia: (listed as silica, amorphous): 1 mg/m3 TWA
Personal Protective Equipment
Eyes:
Not available.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: light yellow
Odor: characteristic odor
pH: >7
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: hydrolysis
Specific Gravity/Density: 0.770
Molecular Formula: C6H18LiNSi2
Molecular Weight: 167.33
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Moisture sensitive.
Conditions to Avoid:
Incompatible materials, ignition sources, exposure to moist air or
water.
Incompatibilities with Other Materials:
Oxidizing materials, water, acids.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide, silicon dioxide,
lithium oxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 100-41-4: DA0700000
CAS# 108-87-2: GV6125000
CAS# 4039-32-1 unlisted.
LD50/LC50:
CAS# 100-41-4: Draize test, rabbit, eye: 500 mg Severe; Inhalation,
mouse: LC50 = 35500 mg/m3/2H; Inhalation, rat: LC50 = 55000
mg/m3/2H; Oral, rat: LD50 = 3500 mg/kg; Oral, rat: LD50 = 3500
mg/kg; Skin, rabbit: LD50 = 17800 uL/kg.
CAS# 108-87-2: Draize test, rabbit, eye: 100 uL/24H Mild; Draize
test, rabbit, skin: 500 uL/24H Mild; Inhalation, mouse: LC50 = 36900
mg/m3/2H; Inhalation, rabbit: LC50 = 15227 ppm/1H; Oral, mouse: LD50
= 1.2 gm/kg; Oral, rat: LD50 = >3200 mg/kg.
CAS# 4039-32-1.
Carcinogenicity:
Ethyl benzene -
ACGIH: A3 - Confirmed animal carcinogen with unknown relevance to
California: carcinogen, initial date 6/11/04
IARC: Group 2B carcinogen
Methylcyclohexane -
Not listed by ACGIH, IARC, or NTP.
Silanamine, 1,1,1-trimethyl-N-(trimethylsilyl)-, lithium sal -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE LIQUID, FLAMMABLE, N.O.S.*
Hazard Class: 8 (3)
UN Number: 2920
Packing Group: I
IMO
Shipping Name: CORROSIVE LIQUID, FLAMMABLE, N.O.S.
Hazard Class: 8 (3)
UN Number: 2920
Packing Group: I
RID/ADR
Shipping Name: FLAMMABLE LIQUID, CORROSIVE, N.O.S.
Hazard Class: 3 (8)
UN Number: 2924
Packing group: I
USA RQ: CAS# 100-41-4: 1000 lb final RQ; 454 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: F C N
Risk Phrases:
R 11 Highly flammable.
R 20 Harmful by inhalation.
R 35 Causes severe burns.
R 51/53 Toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
R 65 Harmful: may cause lung damage if swallowed.
R 67 Vapours may cause drowsiness and dizziness.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 29 Do not empty into drains.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
S 57 Use appropriate containment to avoid
environmental contamination.
WGK (Water Danger/Protection)
CAS# 100-41-4: 1
CAS# 108-87-2: 1
CAS# 4039-32-1: No information available.
Canada
CAS# 100-41-4 is listed on Canada's DSL List.
CAS# 108-87-2 is listed on Canada's DSL List.
CAS# 4039-32-1 is listed on Canada's NDSL List.
CAS# 100-41-4 is listed on Canada's Ingredient Disclosure List.
CAS# 108-87-2 is listed on Canada's Ingredient Disclosure List.
CAS# 4039-32-1 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 100-41-4 is listed on the TSCA inventory.
CAS# 108-87-2 is listed on the TSCA inventory.
CAS# 4039-32-1 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
MSDS Creation Date: 9/20/2004 Revision #0 Date: Original.
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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