**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 10101-97-0 |NICKEL(II) SULFATE HEXAHYDRATE | >98% | unlisted |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 22 40 43
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed. Possible risks of irreversible effects. May
cause sensitization by skin contact.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
Causes skin irritation. May cause severe irritation and possible
burns. May cause dermatitis.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea.
Inhalation:
Dust is irritating to the respiratory tract. Inhalation of vapor may
cause respiratory tract irritation.
Chronic:
Prolonged or repeated skin contact may cause sensitization
dermatitis and possible destruction and/or ulceration. May cause
respiratory tract cancer.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately. Do NOT allow victim to rub or keep eyes closed.
Skin:
Flush skin with plenty of soap and water for at least 15 minutes
while removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists. Wash clothing before reuse.
Ingestion:
Do NOT induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Remove from exposure to fresh air immediately. If not breathing,
give artificial respiration. If breathing is difficult, give oxygen.
Get medical aid. Do NOT use mouth-to-mouth resuscitation.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Water runoff can cause environmental damage. Dike
and collect water used to fight fire. During a fire, irritating and
highly toxic gases may be generated by thermal decomposition or
combustion. Vapors may be heavier than air. They can spread along
the ground and collect in low or confined areas.
Extinguishing Media:
Substance is noncombustible; use agent most appropriate to
extinguish surrounding fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Wash area with soap and water. Wear a self contained breathing
apparatus and appropriate Personal protection. (See Exposure
Controls, Personal Protection section). Avoid generating dusty
conditions. Carefully scoop up and place into appropriate disposal
container. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Minimize dust
generation and accumulation. Avoid contact with skin and eyes. Avoid
ingestion and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances. Keep away
from strong acids.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29CFR
1910.134 or European Standard EN 149. Always use a
NIOSH or European Standard EN 149 approved respirator
when necessary.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Appearance: blue-green
Odor: None reported
pH: 4.5 in solution.
Vapor Pressure: Negligible
Viscosity: Not available.
Boiling Point: 103 deg C
Freezing/Melting Point: 53 deg C
Autoignition Temperature: Noncombustible
Flash Point: Noncombustible
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: 280 C
Solubility in water: 625g/L @20C in water.
Specific Gravity/Density: 2.07 (water=1)
Molecular Formula: NiSO4.6H2O
Molecular Weight: 262.828
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Ignition sources, excess heat, strong acids.
Incompatibilities with Other Materials:
Strong acids, strong oxidizing agents.
Hazardous Decomposition Products:
Oxides of sulfur, irritating and toxic fumes and gases, nickel oxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 10101-97-0: QR9600000
LD50/LC50:
CAS# 10101-97-0: Oral, rat: LD50 = 264 mg/kg.
Carcinogenicity:
NICKEL(II) SULFATE HEXAHYDRATE -
ACGIH: A4 - Not Classifiable as a Human Carcinogen (listed as **
California: carcinogen; initial date 10/1/89 (listed as ** undefined *
NIOSH: occupational carcinogen (listed as ** undefined **)
NTP: Suspect carcinogen (listed as ** undefined **).
OSHA: Possible select carcinogen (listed as ** undefined **).
IARC: Group 2B carcinogen (listed as ** undefined **).
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Prawn (salt water) LC50=13.9ppm/48H Rainbow trout (fresh water)
TLm=160ppm/48H
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
R 40 Possible risks of irreversible effects.
R 43 May cause sensitization by skin contact.
Safety Phrases:
S 22 Do not breathe dust.
S 36/37 Wear suitable protective clothing and
gloves.
WGK (Water Danger/Protection)
CAS# 10101-97-0: 2
United Kingdom Occupational Exposure Limits
CAS# 10101-97-0: OES-United Kingdom, TWA (listed as ** undefined
**): 1 mg/m3 TWA
CAS# 10101-97-0: OES-United Kingdom, STEL (listed as ** undefined
**): 3 mg/m3 STEL
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 10101-97-0 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 10101-97-0: OEL-ARAB Republic of Egypt:TWA 0.1 mg(Ni)/m3
OEL-AUSTRALIA:TWA 1 mg(Ni)/m3
OEL-BELGIUM:TWA 1 mg(Ni)/m3 (insoluble compounds)
OEL-BELGIUM:TWA 1 mg(Ni)/m3
OEL-CZECHOSLOVAKIA:TWA 0.05 mg(Ni)/m3;STEL 0.25 mg(Ni)/m3
OEL-DENMARK:TWA 0.05 mg(Ni)/m3;Carcinogen
OEL-DENMARK:TWA 1 mg(Ni)/m3 (insoluble compounds)
OEL-FINLAND:TWA 0.1 mg(Ni)/m3;Carcinogen
OEL-FINLAND:TWA 0.1 mg(Ni)/m3;Skin;CAR (insoluble compounds)
OEL-FRANCE:TWA 1 mg(Ni)/m3
OEL-GERMANY;Carcinogen
OEL-HUNGARY:STEL 0.005 mg(Ni)/m3;CAR (insoluble compounds)
OEL-HUNGARY:STEL 0.005 mg(Ni)/m3;Carcinogen
OEL-JAPAN:TWA 1 mg(Ni)/m3;Carcinogen
OEL-THE NETHERLANDS:TWA 0.1 mg(Ni)/m3
OEL-THE NETHERLANDS:TWA 1 mg(Ni)/m3 (insoluble compounds)
OEL-THE PHILIPPINES:TWA 1 mg(Ni)/m3
OEL-RUSSIA:STEL 0.05 mg(Ni)/m3
OEL-SWEDEN:TWA 0.5 mg(Ni)/m3
OEL-SWITZERLAND:TWA 0.5 mg(Ni)/m3 (insoluble compounds)
OEL-SWITZERLAND:TWA 0.5 mg(Ni)/m3;Carcinogen JAN9
OEL-THAILAND:TWA 1 mg(Ni)/m3
OEL-UNITED KINGDOM:TWA 0.5 mg(Ni)/m3 (insoluble compounds)
OEL-UNITED KINGDOM:TWA 1 mg(Ni)/m3
OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV
OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
US FEDERAL
TSCA
CAS# 10101-97-0 is not on the TSCA Inventory. It is a hydrate and
exempt from TSCA Inventory requirements (40CFR720.3(u)(2)).
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 8/07/1998 Revision #1 Date: 8/02/2000
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
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| ALL MSDS PAGES IN THIS GROUP
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| 62637-92-7 |
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Nalidixic acid, 99.5%
| 389-08-2 |
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(R)-(+)-N-Allyl-1-phenylethylamine hydrochloride
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Divinyltetramethyldisiloxane, 97%
| 2627-95-4 |
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Tetraethyl orthosilicate, 95%
| 78-10-4 |
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1,2-Epoxyhexane, 97%
| 1436-34-6 |
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(N-Acetyl)-(2R)-bornane-10,2-sultam
| 141993-16-0 |
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Naphthalene, scintillation grade, 99+%
| 91-20-3 |
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Nickel Spheres, p.a., 6 to 16mm
| 7440-02-0 |
|
(1R,2R)-N,N'-Di-p-toluenesulfonyl-1,2-diphenyl-1,2-ethylenediamine
| 121758-19-8 |
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Nickel Acetate Tetrahydrate, Reagent (Crystals), 99% (Titr.)
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| 170709-41-8 |
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| 132836-66-9 |
|
(N-Crotonyl)-(4S)-isopropyl-2-oxazolidinone
| 90719-30-5 |
|
(N-Crotonyl)-(4S)-benzyl-2-oxazolidinone
| 0-01-1 |
|
(S)-PHENYL SUPERQUAT, 98%
| 0-01-1 |
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(R)-PHENYL SUPERQUAT, 98%
| 0-01-1 |
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Forskolin
| 66575-29-9 |
|
Fumonisin B2
| 0-01-1 |
|
Genistein (synthetic), 99%
| 446-72-0 |
|
Nickel (II) Chloride Hexahydrate, 97%
| 7791-20-0 |
|
H-7.dihydrochloride
| 108930-17-2 |
|
Nickel(II) Nitrate Hexahydrate 99%
| 13478-00-7 |
|
H-8, dihydrochloride
| 113276-94-1 |
|
P-Phenylenediacrylic Acid, 97%
| 16323-43-6 |
|
Nickel Monoxide, Peagent (Powder), 97% (titr.)
| 1313-99-1 |
|
N-(2-Hydroxyethyl)ethylenediaminetriacetic acid, trisodium salt
| 0-00-1 |
|
Ammonium Bicarbonate
| 1066-33-7 |
|
H-89.dihydrochloride
| 127243-85-0 |
|
K-252a
| 97161-97-2 |
|
2-N-Butylaminoethanethiol
| 5842-00-2 |
|
KN-62
| 127191-97-3 |
|
KN-93
| 0-01-1 |
|
Lavendustin A
| 125697-92-9 |
|
Leupeptin (synthetic)
| 24365-46-6 |
|
Nickel Sulfate Hexahydrate, Reagent ACS (Crystals)
| 10101-97-0 |
|
Methyl caffeate
| 3843-74-1 |
|
Ammonium Bifluoride
| 1341-49-7 |
|
Okadaic acid (high purity)
| 78111-17-8 |
|
Okadaic acid ammonium salt (high purity)
| 155716-06-6 |
|
Okadaic acid potassium salt (high purity )
| 155751-72-7 |
|
Okadaic acid sodium salt (high purity)
| 78111-17-8 |
|
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| 101622-51-9 |
|
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| 33069-62-4 |
|
Pentoxifylline
| 6493-05-6 |
|
Phorbol 12-myristate 13-acetate, 99%
| 16561-29-8 |
|
Piceatannol
| 10083-24-6 |
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Resiniferatoxin (high purity)
| 57444-62-9 |
|
|