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MSDS 
:
 Nickel(II) Nitrate Hexahydrate 99%
CAS 
:
 13478-00-7
SYNONYMS 
:
 Nickelous Nitrate Hexahydrate; Nitric Acid Nickel (II) Salt     Hexahydrate.
**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****

+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 13478-00-7 |NICKEL(II) NITRATE, HEXAHYDRATE | 99 | unlisted |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN O
Risk Phrases: 20/22 8

**** SECTION 3 - HAZARDS IDENTIFICATION ****

EMERGENCY OVERVIEW
Harmful by inhalation and if swallowed. Contact with combustible
material may cause fire.Oxidizer.

Potential Health Effects
Eye:
May cause eye irritation. May cause conjunctivitis.
Skin:
Causes skin irritation. May cause severe irritation and possible
burns. May cause dermatitis.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May cause liver and kidney damage.
Inhalation:
Dust is irritating to the respiratory tract. Inhalation of vapor may
cause respiratory tract irritation. May cause methemoglobinemia,
cyanosis, convulsions, tachycardia, dyspnea (labored breathing), and
death.
Chronic:
Prolonged inhalation may cause respiratory tract inflammation and
lung damage. Prolonged or repeated skin contact may cause
sensitization dermatitis and possible destruction and/or ulceration.
May cause respiratory tract cancer.

**** SECTION 4 - FIRST AID MEASURES ****

Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Flush skin with plenty of soap and water for at least 15 minutes
while removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Remove from exposure to fresh air immediately. If not breathing,
give artificial respiration. If breathing is difficult, give oxygen.
Get medical aid.
Notes to Physician:

**** SECTION 5 - FIRE FIGHTING MEASURES ****

General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Substance is
nonflammable. Oxidizer. Greatly increases the burning rate of
combustible materials. Vapors may be heavier than air. They can
spread along the ground and collect in low or confined areas.
Containers may explode if exposed to fire.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Substance is
noncombustible; use agent most appropriate to extinguish surrounding
fire. For large fires flood fire with water from a distance. Do NOT
use dry chemicals, CO2, Halon or foams.

**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****

General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Avoid runoff into storm sewers and ditches which lead to waterways.
Clean up spills immediately, observing precautions in the Protective
Equipment section. Wear a self contained breathing apparatus and
appropriate Personal protection. (See Exposure Controls, Personal
Protection section). Avoid generating dusty conditions. Remove all
sources of ignition. Carefully scoop up and place into appropriate
disposal container. Provide ventilation.

**** SECTION 7 - HANDLING and STORAGE ****

Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use only in a well-ventilated area. Minimize dust
generation and accumulation. Avoid contact with skin and eyes. Avoid
ingestion and inhalation. Wash clothing before reuse.
Storage:
Do not store near combustible materials. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances. Keep away from reducing agents.

**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****

Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Personal Protective Equipment

Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29CFR
1910.134 or European Standard EN 149. Always use a
NIOSH or European Standard EN 149 approved respirator
when necessary.

**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****

Physical State: Solid
Appearance: emerald green
Odor: odorless
pH: 4.0 (aqueous sol.)
Vapor Pressure: Negligible
Viscosity: Not available.
Boiling Point: 137 deg C
Freezing/Melting Point: 57 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: 200 C
Solubility in water: 238.5g/100cc water @ 20C.
Specific Gravity/Density: 2.05
Molecular Formula: Ni(NO3)26H2O
Molecular Weight: 290.8

**** SECTION 10 - STABILITY AND REACTIVITY ****

Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, combustible materials, flammable materials.
Incompatibilities with Other Materials:
Alkyl esters, aluminum, hydroxylamine, phosphinates, phosphorus,
strong reducing agents, strong acids, sulfur, tin (II) chloride.
Hazardous Decomposition Products:
Nitrogen oxides, irritating and toxic fumes and gases, nitrogen,
nickel oxide.
Hazardous Polymerization: Has not been reported.

**** SECTION 11 - TOXICOLOGICAL INFORMATION ****

RTECS#:
CAS# 13478-00-7: QR7300000
LD50/LC50:
CAS# 13478-00-7: Oral, rat: LD50 = 1620 mg/kg.
Carcinogenicity:
NICKEL(II) NITRATE, HEXAHYDRATE -
ACGIH: A5 - Not Suspected as a Human Carcinogen (listed as ** und
California: carcinogen; initial date 10/1/89 (listed as ** undefined *
NIOSH: occupational carcinogen (listed as ** undefined **)
NTP: Suspect carcinogen (listed as ** undefined **).
OSHA: Possible select carcinogen (listed as ** undefined **).
IARC: Group 2B carcinogen (listed as ** undefined **).
See actual entry in RTECS for complete information.

**** SECTION 12 - ECOLOGICAL INFORMATION ****

Other
No information available.

**** SECTION 13 - DISPOSAL CONSIDERATIONS ****

Dispose of in a manner consistent with federal, state, and local regulations.

**** SECTION 14 - TRANSPORT INFORMATION ****

IATA
Shipping Name: NICKEL NITRATE
Hazard Class: 5.1
UN Number: 2725
Packing Group: III
IMO
Shipping Name: NICKEL NITRATE
Hazard Class: 5.1
UN Number: 2725
Packing Group: III
RID/ADR
Shipping Name: NICKEL NITRATE
Dangerous Goods Code: 5.1(22C)
UN Number: 2725

**** SECTION 15 - REGULATORY INFORMATION ****

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN O
Risk Phrases:
R 20/22 Harmful by inhalation and if swallowed.
R 8 Contact with combustible material may cause
fire.
Safety Phrases:
S 17 Keep away from combustible material.
S 24/25 Avoid contact with skin and eyes.
S 36/37 Wear suitable protective clothing and
gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 13478-00-7: No information available.
United Kingdom Occupational Exposure Limits
CAS# 13478-00-7: OES-United Kingdom, TWA (listed as ** undefined
**): 1 mg/m3 TWA
CAS# 13478-00-7: OES-United Kingdom, STEL (listed as ** undefined
**): 3 mg/m3 STEL
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 13478-00-7 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 13478-00-7: OEL-ARAB Republic of Egypt:TWA 0.1 mg(Ni)/m3
OEL-AUSTRALIA:TWA 1 mg(Ni)/m3
OEL-BELGIUM:TWA 1 mg(Ni)/m3 (insoluble compounds)
OEL-BELGIUM:TWA 1 mg(Ni)/m3
OEL-CZECHOSLOVAKIA:TWA 0.05 mg(Ni)/m3;STEL 0.25 mg(Ni)/m3
OEL-DENMARK:TWA 0.05 mg(Ni)/m3;Carcinogen
OEL-DENMARK:TWA 1 mg(Ni)/m3 (insoluble compounds)
OEL-FINLAND:TWA 0.1 mg(Ni)/m3;Carcinogen
OEL-FINLAND:TWA 0.1 mg(Ni)/m3;Skin;CAR (insoluble compounds)
OEL-FRANCE:TWA 1 mg(Ni)/m3
OEL-GERMANY;Carcinogen
OEL-HUNGARY:STEL 0.005 mg(Ni)/m3;CAR (insoluble compounds)
OEL-HUNGARY:STEL 0.005 mg(Ni)/m3;Carcinogen
OEL-JAPAN:TWA 1 mg(Ni)/m3;Carcinogen
OEL-THE NETHERLANDS:TWA 0.1 mg(Ni)/m3
OEL-THE NETHERLANDS:TWA 1 mg(Ni)/m3 (insoluble compounds)
OEL-THE PHILIPPINES:TWA 1 mg(Ni)/m3
OEL-RUSSIA:STEL 0.05 mg(Ni)/m3
OEL-SWEDEN:TWA 0.5 mg(Ni)/m3
OEL-SWITZERLAND:TWA 0.5 mg(Ni)/m3 (insoluble compounds)
OEL-SWITZERLAND:TWA 0.5 mg(Ni)/m3;Carcinogen JAN9
OEL-THAILAND:TWA 1 mg(Ni)/m3
OEL-UNITED KINGDOM:TWA 0.5 mg(Ni)/m3 (insoluble compounds)
OEL-UNITED KINGDOM:TWA 1 mg(Ni)/m3
OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV
OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
US FEDERAL
TSCA
CAS# 13478-00-7 is not on the TSCA Inventory. It is a hydrate and
exempt from TSCA Inventory requirements (40CFR720.3(u)(2)).

**** SECTION 16 - ADDITIONAL INFORMATION ****

MSDS Creation Date: 8/06/1998 Revision #1 Date: 8/02/2000

The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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