**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 1313-99-1 |NICKEL(II) OXIDE | 97 | 215-215-7 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T
Risk Phrases: 43 49 53
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
May cause sensitization by skin contact. May cause cancer by
inhalation. May cause long-term adverse effects in the aquatic
environment.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. May cause skin sensitization, an allergic
reaction, which becomes evident upon re-exposure to this material.
May cause dermatitis.
Ingestion:
Causes gastrointestinal irritation with nausea, vomiting and
diarrhea.
Inhalation:
Causes respiratory tract irritation. May cause allergic respiratory
reaction.
Chronic:
Repeated inhalation is associated with nasal and nasopharyngeal
cancer.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
Antidote:
The use of a metal chelator should be determined only by qualified
medical personnel.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Substance is noncombustible; use agent most appropriate to
extinguish surrounding fire. Use water spray, dry chemical, carbon
dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Wash hands before eating. Minimize
dust generation and accumulation. Avoid contact with eyes, skin, and
clothing. Wash clothing before reuse. Do not breathe dust. Use only
with adequate ventilation.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use process enclosure, local exhaust ventilation, or other
engineering controls to control airborne levels.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
Wear a NIOSH/MSHA or European Standard EN 149
approved full-facepiece airline respirator in the
positive pressure mode with emergency escape
provisions. Follow the OSHA respirator regulations
found in 29 CFR 1910.134 or European Standard EN 149.
Always use a NIOSH or European Standard EN 149
approved respirator when necessary.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: khaki
Odor: odorless
pH: Not available.
Vapor Pressure: Not applicable.
Viscosity: Not applicable.
Boiling Point: Not available.
Freezing/Melting Point: 1684 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: insoluble in water.
Specific Gravity/Density: 4.8-6.8
Molecular Formula: NiO
Molecular Weight: 74.6894
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Dust generation.
Incompatibilities with Other Materials:
Fluorine, hydrogen sulfide, barium oxide and air.
Hazardous Decomposition Products:
Irritating and toxic gases, nickel oxide, nickel, metallic oxides.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 1313-99-1: QR8400000 QR8430000
LD50/LC50:
Not available.
Carcinogenicity:
NICKEL(II) OXIDE -
California: carcinogen, initial date 10/1/89
NTP: Known carcinogen (listed as Nickel compounds).
IARC: Group 1 carcinogen (listed as Nickel compounds).
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 49 May cause cancer by inhalation.
R 43 May cause sensitization by skin contact.
R 53 May cause long-term adverse effects in the
aquatic environment.
Safety Phrases:
S 53 Avoid exposure - obtain special instructions
before use.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 1313-99-1: 3
United Kingdom Occupational Exposure Limits
United Kingdom Maximum Exposure Limits
CAS# 1313-99-1: MEL-United Kingdom, TWA (listed as ** undefined
**): 0.1 mg/m3 TWA (as Ni)
Canada
CAS# 1313-99-1 is listed on Canada's DSL List.
CAS# 1313-99-1 is listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 1313-99-1: OEL-ARAB Republic of Egypt:TWA 0.1 mg(Ni)/m3
OEL-AUSTRALIA:TWA 1 mg(Ni)/m3
OEL-BELGIUM:TWA 1 mg(Ni)/m3 (insoluble compounds)
OEL-BELGIUM:TWA 1 mg(Ni)/m3
OEL-CZECHOSLOVAKIA:TWA 0.05 mg(Ni)/m3;STEL 0.25 mg(Ni)/m3
OEL-DENMARK:TWA 0.05 mg(Ni)/m3;Carcinogen
OEL-DENMARK:TWA 1 mg(Ni)/m3 (insoluble compounds)
OEL-FINLAND:TWA 0.1 mg(Ni)/m3;Carcinogen
OEL-FINLAND:TWA 0.1 mg(Ni)/m3;Skin;CAR (insoluble compounds)
OEL-FRANCE:TWA 1 mg(Ni)/m3
OEL-GERMANY;Carcinogen
OEL-HUNGARY:STEL 0.005 mg(Ni)/m3;CAR (insoluble compounds)
OEL-HUNGARY:STEL 0.005 mg(Ni)/m3;Carcinogen
OEL-JAPAN:TWA 1 mg(Ni)/m3;Carcinogen
OEL-THE NETHERLANDS:TWA 0.1 mg(Ni)/m3
OEL-THE NETHERLANDS:TWA 1 mg(Ni)/m3 (insoluble compounds)
OEL-THE PHILIPPINES:TWA 1 mg(Ni)/m3
OEL-RUSSIA:STEL 0.05 mg(Ni)/m3
OEL-SWEDEN:TWA 0.1 mg/m3;Carcinogen
OEL-SWEDEN:TWA 0.5 mg(Ni)/m3
OEL-SWITZERLAND:TWA 0.5 mg(Ni)/m3 (insoluble compounds)
OEL-SWITZERLAND:TWA 0.5 mg(Ni)/m3;Carcinogen JAN9
OEL-SWITZERLAND:TWA 0.5 mg/m3;Carcinogen
OEL-THAILAND:TWA 1 mg(Ni)/m3
OEL-UNITED KINGDOM:TWA 0.5 mg(Ni)/m3 (insoluble compounds)
OEL-UNITED KINGDOM:TWA 1 mg(Ni)/m3
OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV
OEL IN NEW ZEALAND, SIN
US FEDERAL
TSCA
CAS# 1313-99-1 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 2/23/1998 Revision #2 Date: 8/02/2002
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
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