**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 104-87-0 |p-Tolualdehyde | 99 | 203-246-9 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 22
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed.Lachrymator (substance which increases the flow
of tears).
Potential Health Effects
Eye:
May cause eye irritation and possible burns. Lachrymator
(substance which increases the flow of tears).
Skin:
May cause skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May be harmful if swallowed.
Inhalation:
Causes respiratory tract irritation with possible burns. May cause
irritation of the mucous membranes.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid immediately. Flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Combustible liquid.
Vapors may be heavier than air. They can spread along the ground and
collect in low or confined areas. Containers may explode when heated.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use only in a well-ventilated area. Avoid contact
with eyes, skin, and clothing. Empty containers retain product
residue, (liquid and/or vapor), and can be dangerous. Keep container
tightly closed. Keep away from heat, sparks and flame. Avoid
ingestion and inhalation. Do not pressurize, cut, weld, braze,
solder, drill, grind, or expose empty containers to heat, sparks or
open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Keep container closed when not in use. Store in a tightly
closed container. Store in a cool, dry, well-ventilated area away
from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low. Use
process enclosure, local exhaust ventilation, or other engineering
controls to control airborne levels.
Exposure Limits
CAS# 104-87-0:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
Wear a NIOSH/MSHA or European Standard EN 149
approved full-facepiece airline respirator in the
positive pressure mode with emergency escape
provisions. Follow the OSHA respirator regulations
found in 29 CFR 1910.134 or European Standard EN 149.
Use a NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: floral-like
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 204 deg C
Freezing/Melting Point: -6 deg C
Autoignition Temperature: 435 deg C ( 815.00 deg F)
Flash Point: 80 deg C ( 176.00 deg F)
Explosion Limits, lower: N/A
Explosion Limits, upper: N/A
Decomposition Temperature:
Solubility in water: Slightly soluble.
Specific Gravity/Density: 1.0200g/cm3
Molecular Formula: C8H8O
Molecular Weight: 120.15
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, strong
oxidants.
Incompatibilities with Other Materials:
Oxidizing agents
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 104-87-0: CU7034500
LD50/LC50:
CAS# 104-87-0: Draize test, rabbit, eye: 100 mg Moderate; Draize
test, rabbit, skin: 500 mg Moderate; Oral, mouse: LD50 = 3200 mg/kg;
Oral, rat: LD50 = 1600 mg/kg; Skin, rat: LD50 = 2500 mg/kg.
Oral, rat:
Carcinogenicity:
p-Tolualdehyde -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 104-87-0: 1
Canada
CAS# 104-87-0 is listed on Canada's DSL List.
CAS# 104-87-0 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 104-87-0 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 5/11/1998 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
alpha-Chloro-p-xylene, 99+%
| 104-82-5 |
|
Tetrabromo-O-Benzoquinone, 99%
| 2435-54-3 |
|
1,2-Diacetylbenzene, 99%
| 704-00-7 |
|
1-Chloromethyl-4-Fluoro-1,4-Diazoniabicycl o??2.2.2??Octane
| 0-00-1 |
|
(Carbethoxymethylene)-Triphenyl-Phosphorane, 98+% (HPLC)
| 1099-45-2 |
|
6-Methoxyquinoline, 98%
| 5263-87-6 |
|
Acrylonitrile, 99+% (inhibited with 35-45 ppm MEHQ)
| 107-13-1 |
|
Chloroacetic anhydride, 97% (titr.)
| 541-88-8 |
|
(R)-(-)-2-Aminobutane, 98%
| 13250-12-9 |
|
Cis-2-Hydroxymethyl-4-Cyclohexenyl-1-Amine, Hydrochloride, 98+%
| 98769-56-3 |
|
Kjeldahl tablets with selenium (Wieninger)
| 7757-82-6 |
|
Ammonium tungstate, 99.999%
| 11120-25-5 |
|
Alpha-(2,4-Dichlorophenyl)-1H-Imidazole-1-Ethanol, 98% (Titr.)
| 24155-42-8 |
|
4,4'-Difluorodiphenylmethane,99%
| 457-68-1 |
|
N,N'-o-Phenylenedimaleimide, 99%
| 13118-04-2 |
|
4-Acetylamino-2,2,6,6-tetramethylpiperidin -1-oxyl, 99%
| 14691-89-5 |
|
Tetrabutylammonium periodate
| 65201-77-6 |
|
Aniline hydrogen phthalate, 99%
| 50930-79-5 |
|
2-Methoxypropene, 92% stabilized with 0.5% Potassium Carbonate
| 116-11-0 |
|
3,4-Dimethoxycinnamic Acid, 99% Predominantly Trans Isomer
| 2316-26-9 |
|
Acenaphtho[1,2-b]quinoxaline
| |
|
o-Hydroxyphenethyl alcohol, 99%
| 7768-28-7 |
|
P-Tolualdehyde, 99+% (GC)
| 104-87-0 |
|
2-Ethylpiperidine, 95+% (GC)
| 1484-80-6 |
|
4',5,7- Trihydroxyflavanone, 97+%(tlc)
| 480-41-1 |
|
n-Acetyl-s-phenyl-l-cysteine
| 4775-80-8 |
|
13-cis-Retinoic acid, 99% (titr.)
| 4759-48-2 |
|
Inulin, from Dahlia tubers
| 9005-80-5 |
|
4-Chlorophenacyl Thiocyanate
| 19339-59-4 |
|
1-(4-Nitrophenyl)-2-Pyrrolidinone, 99+%(GC)
| 13691-26-4 |
|
2-Deoxy-D-Ribose, 99%
| 533-67-5 |
|
3-Fluoropyridine, 99%
| 372-47-4 |
|
2,3,5-Collidine, 99+%
| 695-98-7 |
|
Tetramethylammonium Hexafluorophosphate
| 558-32-7 |
|
Aminoacetaldehyde Dimethyl Acetal, 99%
| 22483-09-6 |
|
Geraniol, 99% (GC)
| 106-23-0 |
|
Malonamamidine hydrochloride, 99%
| 34570-17-7 |
|
4-Nitrophenethyl bromide, 98%
| 5339-26-4 |
|
d-Tyrosine, 98%
| 556-02-5 |
|
(3,3-Diisopropoxypropyl)triphenylphosphonium bromide, 90%
| 72931-54-5 |
|
Methyl 4-cyanobenzoate, 99+% (gc)
| 1129-35-7 |
|
1-Methyl-1-cyclopentene, 96%
| 693-89-0 |
|
Rosolic Acid
| 603-45-2 |
|
N,N'-Diphenylformamidine, 98%
| 622-15-1 |
|
DL-Homoserine, 99%
| 1927-25-9 |
|
2-Nitroso-1-Naphthol 95%
| 132-53-6 |
|
Indene, Tech., 90%
| 95-13-6 |
|
n-Acetyl-l-tryptophanamide
| 2382-79-8 |
|
Cyclohexanecarboxylic acid, 98+%
| 98-89-5 |
|
(2-Fluorophenyl)acetone, 99%
| 2836-82-0 |
|
|