**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 65201-77-6 |Tetrabutylammonium periodate | 99 | 265-614-5 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN O
Risk Phrases: 20/22 36/37/38 8
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful by inhalation and if swallowed. Irritating to eyes,
respiratory system and skin. Contact with combustible material may
cause fire.Light sensitive.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
Harmful if swallowed. May cause irritation of the digestive tract.
Inhalation:
Harmful if inhaled. Causes respiratory tract irritation.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Strong oxidizer. Contact with other material may
cause fire. During a fire, irritating and highly toxic gases may be
generated by thermal decomposition or combustion. Use water with
caution and in flooding amounts.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Contact professional
fire-fighters immediately. Use water spray, dry chemical, carbon
dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Avoid runoff into storm sewers and ditches which lead to waterways.
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up, then place into a suitable container for
disposal. Avoid generating dusty conditions. Remove all sources of
ignition. Provide ventilation. Do not use combustible materials such
as paper towels to clean up spill.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Minimize dust generation and accumulation. Avoid contact with eyes,
skin, and clothing. Keep container tightly closed. Avoid contact with
clothing and other combustible materials. Avoid ingestion and
inhalation. Store protected from light.
Storage:
Keep away from heat, sparks, and flame. Do not store near
combustible materials. Store in a tightly closed container. Store in
a cool, dry, well-ventilated area away from incompatible substances.
Store protected from light.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 65201-77-6:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystalline powder
Color: yellow
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Decomposes.
Freezing/Melting Point: 175 deg C (dec)
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: 175 deg C
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C16H36INO4
Molecular Weight: 433.37
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Light, ignition sources, dust generation.
Incompatibilities with Other Materials:
Reducing agents, combustible materials.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and
gases, carbon dioxide, nitrogen, hydrogen iodide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 65201-77-6 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Tetrabutylammonium periodate -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: OXIDIZING SOLID, N.O.S.*
Hazard Class: 5.1
UN Number: 1479
Packing Group: II
IMO
Shipping Name: OXIDIZING SOLID, N.O.S.
Hazard Class: 5.1
UN Number: 1479
Packing Group: II
RID/ADR
Shipping Name: OXIDIZING SOLID, N.O.S.
Hazard Class: 5.1
UN Number: 1479
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN O
Risk Phrases:
R 20/22 Harmful by inhalation and if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
R 8 Contact with combustible material may cause
fire.
Safety Phrases:
S 17 Keep away from combustible material.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 65201-77-6: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 65201-77-6 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 65201-77-6 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 2/22/1999 Revision #3 Date: 4/28/2005
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
alpha-Chloro-p-xylene, 99+%
| 104-82-5 |
|
Tetrabromo-O-Benzoquinone, 99%
| 2435-54-3 |
|
1,2-Diacetylbenzene, 99%
| 704-00-7 |
|
1-Chloromethyl-4-Fluoro-1,4-Diazoniabicycl o??2.2.2??Octane
| 0-00-1 |
|
(Carbethoxymethylene)-Triphenyl-Phosphorane, 98+% (HPLC)
| 1099-45-2 |
|
6-Methoxyquinoline, 98%
| 5263-87-6 |
|
Acrylonitrile, 99+% (inhibited with 35-45 ppm MEHQ)
| 107-13-1 |
|
Chloroacetic anhydride, 97% (titr.)
| 541-88-8 |
|
(R)-(-)-2-Aminobutane, 98%
| 13250-12-9 |
|
Cis-2-Hydroxymethyl-4-Cyclohexenyl-1-Amine, Hydrochloride, 98+%
| 98769-56-3 |
|
Kjeldahl tablets with selenium (Wieninger)
| 7757-82-6 |
|
Ammonium tungstate, 99.999%
| 11120-25-5 |
|
Alpha-(2,4-Dichlorophenyl)-1H-Imidazole-1-Ethanol, 98% (Titr.)
| 24155-42-8 |
|
4,4'-Difluorodiphenylmethane,99%
| 457-68-1 |
|
N,N'-o-Phenylenedimaleimide, 99%
| 13118-04-2 |
|
4-Acetylamino-2,2,6,6-tetramethylpiperidin -1-oxyl, 99%
| 14691-89-5 |
|
Tetrabutylammonium periodate
| 65201-77-6 |
|
Aniline hydrogen phthalate, 99%
| 50930-79-5 |
|
2-Methoxypropene, 92% stabilized with 0.5% Potassium Carbonate
| 116-11-0 |
|
3,4-Dimethoxycinnamic Acid, 99% Predominantly Trans Isomer
| 2316-26-9 |
|
Acenaphtho[1,2-b]quinoxaline
| |
|
o-Hydroxyphenethyl alcohol, 99%
| 7768-28-7 |
|
P-Tolualdehyde, 99+% (GC)
| 104-87-0 |
|
2-Ethylpiperidine, 95+% (GC)
| 1484-80-6 |
|
4',5,7- Trihydroxyflavanone, 97+%(tlc)
| 480-41-1 |
|
n-Acetyl-s-phenyl-l-cysteine
| 4775-80-8 |
|
13-cis-Retinoic acid, 99% (titr.)
| 4759-48-2 |
|
Inulin, from Dahlia tubers
| 9005-80-5 |
|
4-Chlorophenacyl Thiocyanate
| 19339-59-4 |
|
1-(4-Nitrophenyl)-2-Pyrrolidinone, 99+%(GC)
| 13691-26-4 |
|
2-Deoxy-D-Ribose, 99%
| 533-67-5 |
|
3-Fluoropyridine, 99%
| 372-47-4 |
|
2,3,5-Collidine, 99+%
| 695-98-7 |
|
Tetramethylammonium Hexafluorophosphate
| 558-32-7 |
|
Aminoacetaldehyde Dimethyl Acetal, 99%
| 22483-09-6 |
|
Geraniol, 99% (GC)
| 106-23-0 |
|
Malonamamidine hydrochloride, 99%
| 34570-17-7 |
|
4-Nitrophenethyl bromide, 98%
| 5339-26-4 |
|
d-Tyrosine, 98%
| 556-02-5 |
|
(3,3-Diisopropoxypropyl)triphenylphosphonium bromide, 90%
| 72931-54-5 |
|
Methyl 4-cyanobenzoate, 99+% (gc)
| 1129-35-7 |
|
1-Methyl-1-cyclopentene, 96%
| 693-89-0 |
|
Rosolic Acid
| 603-45-2 |
|
N,N'-Diphenylformamidine, 98%
| 622-15-1 |
|
DL-Homoserine, 99%
| 1927-25-9 |
|
2-Nitroso-1-Naphthol 95%
| 132-53-6 |
|
Indene, Tech., 90%
| 95-13-6 |
|
n-Acetyl-l-tryptophanamide
| 2382-79-8 |
|
Cyclohexanecarboxylic acid, 98+%
| 98-89-5 |
|
(2-Fluorophenyl)acetone, 99%
| 2836-82-0 |
|
|