**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 109-01-3 |1-Methylpiperazine | 98% | 203-639-5 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 10 21 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Flammable. Harmful in contact with skin. Irritating to eyes,
respiratory system and skin.Hygroscopic (absorbs moisture from the
air).Corrosive.
Potential Health Effects
Eye:
Causes eye irritation and possible burns.
Skin:
Causes skin burns. May be harmful if absorbed through the skin.
Ingestion:
Causes digestive tract irritation.
Inhalation:
Inhalation of vapor may cause respiratory tract irritation. Vapors
may cause dizziness or suffocation. Causes corrosive action on the
mucous membranes. Inhalation may produce burning sensation,
coughing, wheezing, laryngitis, shortness of breath, headache,
nausea, and vomiting.
Chronic:
Not available.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Discard
contaminated clothing in a manner which limits further exposure.
Remove contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air. Will
burn if involved in a fire. Use water spray to keep fire-exposed
containers cool. Containers may explode in the heat of a fire.
Flammable liquid and vapor. May be ignited by heat, sparks, and
flame.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. For large fires, use water spray, fog, or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers. Water may be ineffective. Do NOT use straight streams of
water.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation. A
vapor suppressing foam may be used to reduce vapors. Water spray may
reduce vapor but may not prevent ignition in closed spaces.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Use only in a well-ventilated area. Ground and bond containers when
transferring material. Use spark-proof tools and explosion proof
equipment. Avoid contact with eyes, skin, and clothing. Empty
containers retain product residue, (liquid and/or vapor), and can be
dangerous. Keep away from heat, sparks and flame. Avoid ingestion
and inhalation. Do not pressurize, cut, weld, braze, solder, drill,
grind, or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 109-01-3:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: Not available.
Odor: amine-like
pH: Not available.
Vapor Pressure: 122 hPa @20C
Viscosity: Not available.
Boiling Point: 138 deg C
Freezing/Melting Point: 65.5 deg F
Autoignition Temperature: Not available.
Flash Point: 42 deg C ( 107.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: miscible with water
Specific Gravity/Density: .9030g/cm3
Molecular Formula: C5H12N2
Molecular Weight: 100.16
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, strong
oxidants, moist air.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide, nitrogen.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 109-01-3: TM1225000
LD50/LC50:
CAS# 109-01-3: Draize test, rabbit, eye: 750 ug/24H Severe; Draize
test, rabbit, skin: 5 mg/24H Severe; Inhalation, mouse: LC50 = 2740
mg/m3/2H; Oral, mouse: LD50 = 1450 mg/kg; Oral, rat: LD50 = 2830
uL/kg; Skin, rabbit: LD50 = 1490 uL/kg.
Carcinogenicity:
1-Methylpiperazine -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: FLAMMABLE LIQUID, N.O.S.*
Hazard Class: 3
UN Number: 1993
Packing Group: III
IMO
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3.3
UN Number: 1993
Packing Group: III
RID/ADR
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3
UN Number: 1993
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 10 Flammable.
R 21 Harmful in contact with skin.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 24/25 Avoid contact with skin and eyes.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 33 Take precautionary measures against static
discharges.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
S 50A Do not mix with acids.
WGK (Water Danger/Protection)
CAS# 109-01-3: 1
Canada
CAS# 109-01-3 is listed on Canada's DSL List.
CAS# 109-01-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 109-01-3 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 8/28/1998 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
9-Hydrazinoacridine
| 3407-93-0 |
|
2,2,2-Trifluoroethylamine Hydrochloride 99%
| 373-88-6 |
|
1-Methyl-3,4-Dihydroisoquinoline Hydrochloride, 99+%
| 26210-39-9 |
|
Tri-o-acetyl-d-glucal, 99%
| 2873-29-2 |
|
2-Chlorophenyl isocyanate
| 3320-83-0 |
|
3,5-Dimethoxyphenol, 97% (GC)
| 500-99-2 |
|
N,N-Dimethylacetamide-d9, 99+ atom% d
| 16727-10-9 |
|
Resorcinol monoacetate, tech.
| 102-29-4 |
|
1-Bromo-3,5-Dimethylbenzene, 98%
| 556-96-7 |
|
(S)-(+)-2-Methylbutyl p-[(p-methoxybenzylidene)amino]cinnamate, 98%
| 24140-30-5 |
|
Pseudopelletierine Hydrochloride, 98%
| 6164-62-1 |
|
P-Nitrophenol Sodium Salt, Dihydrate, 75% (UV-VIS)
| 824-78-2 |
|
Silver p-toluenesulfonate, 99+%
| 16836-95-6 |
|
22621-O-Dibutyryladenosine 3',5'-cyclic monophosphate sodium salt
| 16980-89-5 |
|
2',5'-Dimethylacetophenone, 99% (gc)
| 2142-73-6 |
|
Tri-n-butyltin chloride, tech., 90%
| 1461-22-9 |
|
1-Methylpiperazine, 99+% (gc)
| 109-01-3 |
|
3,5-Diiodo-4-hydroxybenzonitrile, 98%
| 1689-83-4 |
|
3,5-Dichlorosalicylic acid
| 320-72-9 |
|
Trans-2,4-Dichlorocinnamic Acid, 98%
| 1201-99-6 |
|
Beeswax, Bleached, White
| 8006-40-4 |
|
Ethyl bromopyruvate, 80-85%
| 70-23-5 |
|
3-Dimethylamino-2-Methylpropyl Chloride Hydrochloride, 98%
| 4261-67-0 |
|
2-Picoline-N-oxide, 98%
| 931-19-1 |
|
Bis(4-Bromophenyl) Ether
| 2050-47-7 |
|
Methyl 4-Bromobenzoate, 99% (GC)
| 619-42-1 |
|
Ethyl 2-Cyclohexanonecarboxylate, 98% (GC)
| 1655-07-8 |
|
4,4'-Dibromobiphenyl, 99%
| 92-86-4 |
|
Aluminum Bromide, Anhydrous, 98+%
| 7727-15-3 |
|
3,3'-Diaminobenzidine, 99%
| 91-95-2 |
|
2-Methoxyphenylacetone, 98%
| 5211-62-1 |
|
Beta-d-Ribofuranose 1,2,3,5-Tetraacetate
| 13035-61-5 |
|
N,N'-(2,3-Dinitro-1,4-phenylene) bisacetamide, 97%
| |
|
(+)-2-Methylbutyl-p-aminocinnamate, 98% (titr.)
| 62742-50-1 |
|
Trimethylsulfonium Iodide, 98%
| 2181-42-2 |
|
2,2-Dichlorotetradecanal, 90%
| 119450-45-2 |
|
2-Nitropropane, 96%
| 79-46-9 |
|
1-Acetylimidazole, 98%
| 2466-76-4 |
|
7-Ethoxycoumarin, 99.5%
| 31005-02-4 |
|
5-Bromo-2-iodotoluene, 98%
| |
|
3-Ethoxy-1-(4-Nitrophenyl)-2-Pyrazolin- 5-One, 98% (UV-Vis)
| 4105-90-2 |
|
S-(4-Nitrobenzyl)-6-Thioguanosine, 99%
| 13153-27-0 |
|
2,3,4-Tri-O-Acetyl-Beta-D-Xylopyranosyl Azide, 98%
| 53784-33-1 |
|
4-Bromo-2-Chlorophenol, 99%
| 3964-56-5 |
|
2,2,5,5-Tetramethyl-4-phenyl-3-imidazoline -3-oxide-1-oxyl, free
| 18796-03-7 |
|
Nitroethane, 98+%
| 79-24-3 |
|
3-Hydroxypyridine-N-oxide, 99%
| 6602-28-4 |
|
1,2-O-Cyclohexylidene-Alpha-D-Glucofuranose, 98%
| 16832-21-6 |
|
1-Methylheptylamine, 96% (gc)
| 693-16-3 |
|
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| 76835-20-6 |
|
|