**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 7727-15-3 |Aluminum Bromide | 98+ | 231-779-7 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 22 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed. Causes burns.Corrosive.
Potential Health Effects
Eye:
Contact with eyes may cause severe irritation, and possible eye
burns. When substance becomes wet or comes in contact with moisture
of the mucous membranes, it will cause irritation. May cause
chemical conjunctivitis and corneal damage.
Skin:
Contact with skin causes irritation and possible burns, especially
if the skin is wet or moist. May cause skin rash (in milder cases),
and cold and clammy skin with cyanosis or pale color.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns. May cause perforation of the digestive
tract. May be harmful if swallowed. May cause systemic effects.
Aluminum may be readily absorbed from the gastrointestinal tract.
Inhalation:
May cause severe irritation of the respiratory tract with sore
throat, coughing, shortness of breath and delayed lung edema. Causes
chemical burns to the respiratory tract. Aspiration may lead to
pulmonary edema. May cause systemic effects.
Chronic:
Effects may be delayed. Chronic ingestion of aluminum oxide may
produce loss of appetite, hemolysis, renal deposition and bone
marrow damage
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
If water-reactive products are embedded in the skin, no water should
be applied. The embedded products should be covered with a light
oil.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Water
Reactive. Material will react with water and may release a flammable
and/or toxic gas. Use water spray to keep fire-exposed containers
cool. May ignite or explode on contact with steam or moist air.
Contact with metals may evolve flammable hydrogen gas. Containers
may explode when heated or if contaminated with water. Combustible
material; may burn but does not ignite readily.
Extinguishing Media:
Do NOT get water inside containers. Contact professional
fire-fighters immediately. Cool containers with flooding quantities
of water until well after fire is out. For small fires, use dry
chemical or carbon dioxide. For large fires, flood fire area with
large quantities of water, while knocking down vapors with water fog.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Avoid runoff into storm sewers and ditches which lead to waterways.
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up, then place into a suitable container for
disposal. Avoid generating dusty conditions. Remove all sources of
ignition. Provide ventilation. Do not expose spill to water.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Use only in a well-ventilated area. Do not allow water to get into
the container because of violent reaction. Minimize dust generation
and accumulation. Do not breathe dust, vapor, mist, or gas. Do not
get in eyes, on skin, or on clothing. Keep container tightly closed.
Do not ingest or inhale. Do not allow contact with water. Discard
contaminated shoes. Keep from contact with moist air and steam.
Storage:
Keep container closed when not in use. Keep away from water.
Corrosives area. Keep refrigerated. (Store below 4C/39F.) Store
protected from moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 7727-15-3:
United Kingdom, WEL - TWA: (listed as aluminum, soluble salts): 2
mg/m3 TWA
United Kingdom, WEL - STEL: (listed as aluminum, soluble salts):
mg/m3 STEL
Belgium - TWA: (listed as aluminum, soluble salts): 2 mg/m3 VLE (
Al)
France - VME: (listed as aluminum, soluble salts): 2 mg/m3 VME
Germany: (listed as aluminum, soluble salts): 2 mg/m3 VME
Malaysia: (listed as aluminum, soluble salts): 2 mg/m3 TWA (as Al
Spain: (listed as aluminum, soluble salts): 2 mg/m3 VLA-ED (as Al
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystals
Color: white to yellow
Odor: None reported.
pH: Not available.
Vapor Pressure: 1 mmHg @ 81 C
Viscosity: Not available.
Boiling Point: 265 deg C @ 760.00mmHg
Freezing/Melting Point: 97 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: reacts
Specific Gravity/Density: 3.2050g/cm3
Molecular Formula: AlBr3
Molecular Weight: 266.70
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures. Combines vigorously
or explosively with water.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat, exposure to
moist air or water.
Incompatibilities with Other Materials:
Moisture, acids, alcohols.
Hazardous Decomposition Products:
Hydrogen bromide, aluminum oxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 7727-15-3: BD0350000
LD50/LC50:
CAS# 7727-15-3: Oral, mouse: LD50 = 1623 mg/kg; Oral, rat: LD50 =
1598 mg/kg.
Carcinogenicity:
Aluminum Bromide -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
For more information, see "HANDBOOK OF ENVIRONMENTAL FATE AND
EXPOSURE DATA."
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: ALUMINIUM BROMIDE, ANHYDROUS
Hazard Class: 8
UN Number: 1725
Packing Group: II
IMO
Shipping Name: ALUMINIUM BROMIDE, ANHYDROUS
Hazard Class: 8
UN Number: 1725
Packing Group: II
RID/ADR
Shipping Name: ALUMINIUM BROMIDE, ANHYDROUS
Hazard Class: 8
UN Number: 1725
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 22 Harmful if swallowed.
R 34 Causes burns.
Safety Phrases:
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
WGK (Water Danger/Protection)
CAS# 7727-15-3: No information available.
Canada
CAS# 7727-15-3 is listed on Canada's DSL List.
CAS# 7727-15-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7727-15-3 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #6 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
9-Hydrazinoacridine
| 3407-93-0 |
|
2,2,2-Trifluoroethylamine Hydrochloride 99%
| 373-88-6 |
|
1-Methyl-3,4-Dihydroisoquinoline Hydrochloride, 99+%
| 26210-39-9 |
|
Tri-o-acetyl-d-glucal, 99%
| 2873-29-2 |
|
2-Chlorophenyl isocyanate
| 3320-83-0 |
|
3,5-Dimethoxyphenol, 97% (GC)
| 500-99-2 |
|
N,N-Dimethylacetamide-d9, 99+ atom% d
| 16727-10-9 |
|
Resorcinol monoacetate, tech.
| 102-29-4 |
|
1-Bromo-3,5-Dimethylbenzene, 98%
| 556-96-7 |
|
(S)-(+)-2-Methylbutyl p-[(p-methoxybenzylidene)amino]cinnamate, 98%
| 24140-30-5 |
|
Pseudopelletierine Hydrochloride, 98%
| 6164-62-1 |
|
P-Nitrophenol Sodium Salt, Dihydrate, 75% (UV-VIS)
| 824-78-2 |
|
Silver p-toluenesulfonate, 99+%
| 16836-95-6 |
|
22621-O-Dibutyryladenosine 3',5'-cyclic monophosphate sodium salt
| 16980-89-5 |
|
2',5'-Dimethylacetophenone, 99% (gc)
| 2142-73-6 |
|
Tri-n-butyltin chloride, tech., 90%
| 1461-22-9 |
|
1-Methylpiperazine, 99+% (gc)
| 109-01-3 |
|
3,5-Diiodo-4-hydroxybenzonitrile, 98%
| 1689-83-4 |
|
3,5-Dichlorosalicylic acid
| 320-72-9 |
|
Trans-2,4-Dichlorocinnamic Acid, 98%
| 1201-99-6 |
|
Beeswax, Bleached, White
| 8006-40-4 |
|
Ethyl bromopyruvate, 80-85%
| 70-23-5 |
|
3-Dimethylamino-2-Methylpropyl Chloride Hydrochloride, 98%
| 4261-67-0 |
|
2-Picoline-N-oxide, 98%
| 931-19-1 |
|
Bis(4-Bromophenyl) Ether
| 2050-47-7 |
|
Methyl 4-Bromobenzoate, 99% (GC)
| 619-42-1 |
|
Ethyl 2-Cyclohexanonecarboxylate, 98% (GC)
| 1655-07-8 |
|
4,4'-Dibromobiphenyl, 99%
| 92-86-4 |
|
Aluminum Bromide, Anhydrous, 98+%
| 7727-15-3 |
|
3,3'-Diaminobenzidine, 99%
| 91-95-2 |
|
2-Methoxyphenylacetone, 98%
| 5211-62-1 |
|
Beta-d-Ribofuranose 1,2,3,5-Tetraacetate
| 13035-61-5 |
|
N,N'-(2,3-Dinitro-1,4-phenylene) bisacetamide, 97%
| |
|
(+)-2-Methylbutyl-p-aminocinnamate, 98% (titr.)
| 62742-50-1 |
|
Trimethylsulfonium Iodide, 98%
| 2181-42-2 |
|
2,2-Dichlorotetradecanal, 90%
| 119450-45-2 |
|
2-Nitropropane, 96%
| 79-46-9 |
|
1-Acetylimidazole, 98%
| 2466-76-4 |
|
7-Ethoxycoumarin, 99.5%
| 31005-02-4 |
|
5-Bromo-2-iodotoluene, 98%
| |
|
3-Ethoxy-1-(4-Nitrophenyl)-2-Pyrazolin- 5-One, 98% (UV-Vis)
| 4105-90-2 |
|
S-(4-Nitrobenzyl)-6-Thioguanosine, 99%
| 13153-27-0 |
|
2,3,4-Tri-O-Acetyl-Beta-D-Xylopyranosyl Azide, 98%
| 53784-33-1 |
|
4-Bromo-2-Chlorophenol, 99%
| 3964-56-5 |
|
2,2,5,5-Tetramethyl-4-phenyl-3-imidazoline -3-oxide-1-oxyl, free
| 18796-03-7 |
|
Nitroethane, 98+%
| 79-24-3 |
|
3-Hydroxypyridine-N-oxide, 99%
| 6602-28-4 |
|
1,2-O-Cyclohexylidene-Alpha-D-Glucofuranose, 98%
| 16832-21-6 |
|
1-Methylheptylamine, 96% (gc)
| 693-16-3 |
|
1-(5-Chloro-2-Methylphenyl)Piperazine
| 76835-20-6 |
|
|