**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 109-70-6 |1-Bromo-3-chloropropane, 99% | 99% | 203-697-1 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 20/22 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful by inhalation and if swallowed. Irritating to eyes,
respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. May be absorbed through the skin in harmful
amounts.
Ingestion:
Causes gastrointestinal irritation with nausea, vomiting and
diarrhea. May cause liver and kidney damage. May be harmful if
swallowed.
Inhalation:
Causes respiratory tract irritation.
Chronic:
May cause liver and kidney damage.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Immediately flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Wash hands before eating. Use with
adequate ventilation. Do not breathe dust, vapor, mist, or gas. Do
not get on skin or in eyes. Do not ingest or inhale.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate general or local explosion-proof ventilation to keep
airborne levels to acceptable levels.
Exposure Limits
CAS# 109-70-6:
Russia: 3 mg/m3 TWA
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: Clear
Odor: Sweet chloroform-like odor.
pH: Not available.
Vapor Pressure: 6.6 mbar @ 20 C
Viscosity: Not available.
Boiling Point: 144 - 145 deg C @ 760.00mm Hg
Freezing/Melting Point: -59 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: insoluble
Specific Gravity/Density: 1.5920g/cm3
Molecular Formula: C3H6BrCl
Molecular Weight: 157.44
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong bases, oxidizing agents, magnesium, zinc, aluminum.
Hazardous Decomposition Products:
Hydrogen chloride, phosgene, carbon monoxide, carbon dioxide,
hydrogen bromide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 109-70-6: TX4113000
LD50/LC50:
CAS# 109-70-6: Inhalation, rat: LC50 = 5668 mg/m3; Inhalation, rat:
LC50 = 6500 mg/m3/4H; Oral, mouse: LD50 = 1290 mg/kg; Oral, rat:
LD50 = 930 mg/kg.
Carcinogenicity:
1-Bromo-3-chloropropane, 99% -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
LC50 (24hr) goldfish:75 mg/l
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: 1-BROMO-3-CHLOROPROPANE
Hazard Class: 6.1
UN Number: 2688
Packing Group: III
IMO
Shipping Name: 1-BROMO-3-CHLOROPROPANE
Hazard Class: 6.1
UN Number: 2688
Packing Group: III
RID/ADR
Shipping Name: 1-BROMO-3-CHLOROPROPANE
Hazard Class: 6.1
UN Number: 2688
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/22 Harmful by inhalation and if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 109-70-6: 3
Canada
CAS# 109-70-6 is listed on Canada's DSL List.
CAS# 109-70-6 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 109-70-6 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
5-Hydroxy-n omega-methyltryptamine oxalate 99%
| 15558-50-6 |
|
Coumarin 6, Laser Grade, 98% (UV-Vis)
| 38215-36-0 |
|
Iodobenzene, 98%
| 591-50-4 |
|
Oxalyl bromide, 98%
| 15219-34-8 |
|
Borane-trimethylamine complex, 98% (titr.)
| 75-22-9 |
|
1,2,4-1H-Triazole, 99.5%
| 288-88-0 |
|
Benzoic acid ammonium salt, 99% (titr.)
| 1863-63-4 |
|
2-Methyl-Cyclopropane-Methanol (Mixture of Cis and Trans), 98%
| 6077-72-1 |
|
Dowex 1x8-50 Ion-Exchange Resin
| 69772-06-1 |
|
Poly (4-Vinylpyridinium Dichromate),Cross Linked with 2% DVB;2.2mmol
| 82246-45-5 |
|
Coumarin 334, Laser Grade, 99% (UV-Vis)
| 55804-67-6 |
|
Cinnamyl alcohol, 98%
| 104-54-1 |
|
Potassium trichloro(ethylene)platinate(ii) monohydrate
| 12012-50-9 |
|
3-Tert-Butyl Adipic Acid, 99%(GC)
| 10347-88-3 |
|
Vanadium(iv) oxide, 99.9%
| 12036-21-4 |
|
3-Aminobenzotrifluoride, 99+ %
| 98-16-8 |
|
4,4-Dimethyl-2-pentanol, 99%
| 6144-93-0 |
|
Benzyl levulinate, 96%(GC)
| 6939-75-9 |
|
2,3,5,6-Tetrafluorophenol, 97+%
| 769-39-1 |
|
1-Bromo-3-chloropropane, 99%
| 109-70-6 |
|
3-Mercapto-1,2-propanediol, 90 wt% aqueous solution
| 96-27-5 |
|
Acetylenedicarboxamide (pract)
| 543-21-5 |
|
4-Heptyloxyphenol, 99%
| 13037-86-0 |
|
1-Bromo-3-Fluoro-4-Iodobenzene, 99+%
| 105931-73-5 |
|
Benzyl phenyl sulfide, 99%
| 831-91-4 |
|
1,5-Pentamethylenetetrazole, 98%
| 54-95-5 |
|
Lepidine (4-methylquinoline), 99%
| 491-35-0 |
|
2-Methyl-1-tetralone, 99%
| 1590-08-5 |
|
3-Ethoxy-2-Cyclohexen-1-One, 99%
| 5323-87-5 |
|
Hydroquinone Bis(2-Hydroxyethyl)ether, 97% (GC)
| 104-38-1 |
|
(2S,3S)-3-Methylpyrrolidine-2-carboxylic acid, 97%
| 0-01-1 |
|
Cholesteryl 2-ethylhexanoate
| 41329-01-5 |
|
Thiobenzamide, 95%
| 2227-79-4 |
|
(S)-(+)-2-Phenylpropionic acid, 99%
| 7782-24-3 |
|
Lycopodium Powder
| 8023-70-9 |
|
Isopropylcyclohexane, 97%
| 696-29-7 |
|
2-Hydrazinobenzothiazole, 99% (Titr.)
| 615-21-4 |
|
n,n-Dimethyl-p-Toluidine, 99%
| 99-97-8 |
|
3-Iodo-4-Methylbenzoic Acid, 97%
| 82998-57-0 |
|
Europium (III) Sulfate Octahydrate, 99.99%
| 10031-55-7 |
|
4,4,5,5,6,6,6-Heptafluoro-1-(2-thienyl)- 1,3-hexanedione
| 559-94-4 |
|
4-Bromoresorcinol, 99%
| 6626-15-9 |
|
1-Octen-3-ol, 98%
| 3391-86-4 |
|
5-Bromo-2-chlorobenzotrifluoride,techn. 94 %
| 445-01-2 |
|
3-Chloropropionyl Chloride, 98%
| 625-36-5 |
|
Alpha, Alpha, Alpha-Trifluoro-P-Toluic Acid, 98%
| 455-24-3 |
|
2-Bromo-2-Phenylacetophenone
| 1484-50-0 |
|
Silicon, Powder, -325 Mesh, 99+%
| 7440-21-3 |
|
Ethylene oxide, 99+%
| 75-21-8 |
|
Atropine Sulfate Monohydrate, 98.5% (Dry Substance)
| 5908-99-6 |
|
|