**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 82246-45-5 |Poly (4-Vinylpyridinium Dichromate) | | unlisted |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN O
Risk Phrases: 40 8
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Limited evidence of a carcinogenic effect. Contact with combustible
material may cause fire.Cancer suspect agent.Light
sensitive.Possible risks of irreversible effects.
Potential Health Effects
Eye:
May cause eye irritation. May cause conjunctivitis. May cause
permanent corneal opacification.
Skin:
May cause severe irritation and possible burns.
Ingestion:
May cause cardiac disturbances. May cause burns to the
gastrointestinal tract. May cause central nervous system effects. May
cause nausea, vomiting, and diarrhea, possibly with blood.
Inhalation:
Inhalation of high concentrations may cause central nervous system
effects characterized by nausea, headache, dizziness, unconsciousness
and coma. May cause respiratory tract irritation. May cause cardiac
abnormalities. May cause acute pulmonary edema, asphyxia, chemical
pneumonitis, and upper airway obstruction caused by edema.
Chronic:
Effects may be delayed. Cancer suspect agent.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Strong oxidizer. Contact with other material may
cause fire. During a fire, irritating and highly toxic gases may be
generated by thermal decomposition or combustion. Use water with
caution and in flooding amounts. Some oxidizers may react explosively
with hydrocarbons(fuel). May accelerate burning if involved in a
fire. Containers may explode when heated. Runoff from fire control
or dilution water may cause pollution.
Extinguishing Media:
Contact professional fire-fighters immediately. For small fires, do
NOT use dry chemicals, carbon dioxide, halon or foams. USE WATER
ONLY. For large fires flood fire with water from a distance.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up, then place into a suitable container for
disposal. Remove all sources of ignition. Provide ventilation. Do not
use combustible materials such as paper towels to clean up spill.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Minimize dust generation and accumulation. Keep container tightly
closed. Avoid contact with clothing and other combustible materials.
Do not get on skin or in eyes. Avoid ingestion and inhalation. Store
protected from light.
Storage:
Keep away from heat, sparks, and flame. Do not store near
combustible materials. Store in a tightly closed container. Store in
a cool, dry, well-ventilated area away from incompatible substances.
Store protected from light.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 82246-45-5:
United Kingdom, WEL - TWA: (listed as chromium (vi) compounds): 0
mg/m3 TWA (as Cr)
United Kingdom, WEL - STEL: (listed as chromium (vi) compounds):
mg/m3 STEL (as Cr)
Belgium - TWA: (listed as chromium (vi) compounds (certain water
insoluble forms)): 0.01 mg/m3 VLE (as Cr)
France - VME: (listed as chromium (vi) compounds): 0.05 mg/m3 VME
Cr)
Germany: (listed as chromium (vi) compounds): 0.05 mg/m3 VME (as
Japan: (listed as chromium (vi) compounds): 0.05 mg/m3 OEL (as Cr
0.01 mg/m3 OEL (certain compounds, as Cr)
Spain: (listed as chromium (vi) compounds (certain water insolubl
forms)): 0.01 mg/m3 VLA-ED (as Cr)
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear a chemical apron. Wear appropriate protective
clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Powder
Color: dark brown
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: > 300 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula:
Molecular Weight:
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, light, ignition sources, dust generation,
combustible materials, reducing agents, strong oxidants.
Incompatibilities with Other Materials:
Reducing agents, alcohols, strong acids.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and
gases, carbon dioxide, nitrogen.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 82246-45-5 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Poly (4-Vinylpyridinium Dichromate) -
California: carcinogen, initial date 2/27/87 (listed as Chromium (VI)
NTP: Known carcinogen (listed as Chromium (VI) compounds).
IARC: Group 1 carcinogen (listed as Chromium (VI) compounds).
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: OXIDIZING SOLID, N.O.S.*
Hazard Class: 5.1
UN Number: 1479
Packing Group: III
IMO
Shipping Name: OXIDIZING SOLID, N.O.S.
Hazard Class: 5.1
UN Number: 1479
Packing Group: III
RID/ADR
Shipping Name: OXIDIZING SOLID, N.O.S.
Hazard Class: 5.1
UN Number: 1479
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN O
Risk Phrases:
R 40 Limited evidence of a carcinogenic effect.
R 8 Contact with combustible material may cause
fire.
Safety Phrases:
S 17 Keep away from combustible material.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
WGK (Water Danger/Protection)
CAS# 82246-45-5: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 82246-45-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 82246-45-5 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #6 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
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5-Hydroxy-n omega-methyltryptamine oxalate 99%
| 15558-50-6 |
|
Coumarin 6, Laser Grade, 98% (UV-Vis)
| 38215-36-0 |
|
Iodobenzene, 98%
| 591-50-4 |
|
Oxalyl bromide, 98%
| 15219-34-8 |
|
Borane-trimethylamine complex, 98% (titr.)
| 75-22-9 |
|
1,2,4-1H-Triazole, 99.5%
| 288-88-0 |
|
Benzoic acid ammonium salt, 99% (titr.)
| 1863-63-4 |
|
2-Methyl-Cyclopropane-Methanol (Mixture of Cis and Trans), 98%
| 6077-72-1 |
|
Dowex 1x8-50 Ion-Exchange Resin
| 69772-06-1 |
|
Poly (4-Vinylpyridinium Dichromate),Cross Linked with 2% DVB;2.2mmol
| 82246-45-5 |
|
Coumarin 334, Laser Grade, 99% (UV-Vis)
| 55804-67-6 |
|
Cinnamyl alcohol, 98%
| 104-54-1 |
|
Potassium trichloro(ethylene)platinate(ii) monohydrate
| 12012-50-9 |
|
3-Tert-Butyl Adipic Acid, 99%(GC)
| 10347-88-3 |
|
Vanadium(iv) oxide, 99.9%
| 12036-21-4 |
|
3-Aminobenzotrifluoride, 99+ %
| 98-16-8 |
|
4,4-Dimethyl-2-pentanol, 99%
| 6144-93-0 |
|
Benzyl levulinate, 96%(GC)
| 6939-75-9 |
|
2,3,5,6-Tetrafluorophenol, 97+%
| 769-39-1 |
|
1-Bromo-3-chloropropane, 99%
| 109-70-6 |
|
3-Mercapto-1,2-propanediol, 90 wt% aqueous solution
| 96-27-5 |
|
Acetylenedicarboxamide (pract)
| 543-21-5 |
|
4-Heptyloxyphenol, 99%
| 13037-86-0 |
|
1-Bromo-3-Fluoro-4-Iodobenzene, 99+%
| 105931-73-5 |
|
Benzyl phenyl sulfide, 99%
| 831-91-4 |
|
1,5-Pentamethylenetetrazole, 98%
| 54-95-5 |
|
Lepidine (4-methylquinoline), 99%
| 491-35-0 |
|
2-Methyl-1-tetralone, 99%
| 1590-08-5 |
|
3-Ethoxy-2-Cyclohexen-1-One, 99%
| 5323-87-5 |
|
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| 104-38-1 |
|
(2S,3S)-3-Methylpyrrolidine-2-carboxylic acid, 97%
| 0-01-1 |
|
Cholesteryl 2-ethylhexanoate
| 41329-01-5 |
|
Thiobenzamide, 95%
| 2227-79-4 |
|
(S)-(+)-2-Phenylpropionic acid, 99%
| 7782-24-3 |
|
Lycopodium Powder
| 8023-70-9 |
|
Isopropylcyclohexane, 97%
| 696-29-7 |
|
2-Hydrazinobenzothiazole, 99% (Titr.)
| 615-21-4 |
|
n,n-Dimethyl-p-Toluidine, 99%
| 99-97-8 |
|
3-Iodo-4-Methylbenzoic Acid, 97%
| 82998-57-0 |
|
Europium (III) Sulfate Octahydrate, 99.99%
| 10031-55-7 |
|
4,4,5,5,6,6,6-Heptafluoro-1-(2-thienyl)- 1,3-hexanedione
| 559-94-4 |
|
4-Bromoresorcinol, 99%
| 6626-15-9 |
|
1-Octen-3-ol, 98%
| 3391-86-4 |
|
5-Bromo-2-chlorobenzotrifluoride,techn. 94 %
| 445-01-2 |
|
3-Chloropropionyl Chloride, 98%
| 625-36-5 |
|
Alpha, Alpha, Alpha-Trifluoro-P-Toluic Acid, 98%
| 455-24-3 |
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2-Bromo-2-Phenylacetophenone
| 1484-50-0 |
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Silicon, Powder, -325 Mesh, 99+%
| 7440-21-3 |
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Ethylene oxide, 99+%
| 75-21-8 |
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| 5908-99-6 |
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