**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 769-39-1 |2,3,5,6-Tetrafluorophenol | 97+ | 212-209-6 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation. May cause chemical conjunctivitis and
corneal damage.
Skin:
Causes skin irritation. May cause cyanosis of the extremities.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea.
Inhalation:
Causes respiratory tract irritation. Aspiration may lead to
pulmonary edema. Can produce delayed pulmonary edema. Inhalation at
high concentrations may cause CNS depression and asphixiation.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Dusts at sufficient concentrations can form
explosive mixtures with air. During a fire, irritating and highly
toxic gases may be generated by thermal decomposition or combustion.
Use water spray to keep fire-exposed containers cool. Vapors may be
heavier than air. They can spread along the ground and collect in
low or confined areas. Containers may explode when heated.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Avoid runoff into storm sewers and ditches which lead to
waterways. Clean up spills immediately, observing precautions in the
Protective Equipment section. Remove all sources of ignition. Use a
spark-proof tool. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Avoid contact with eyes, skin, and clothing. Empty containers retain
product residue, (liquid and/or vapor), and can be dangerous. Keep
container tightly closed. Keep away from heat, sparks and flame.
Avoid ingestion and inhalation. Wash clothing before reuse. Do not
pressurize, cut, weld, braze, solder, drill, grind, or expose empty
containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 769-39-1:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: white
Odor: phenol-like
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 140 deg C @ 760.00mmHg
Freezing/Melting Point: 32.00 - 38.00 deg C
Autoignition Temperature: Not available.
Flash Point: 79 deg C ( 174.20 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C6H2F4O
Molecular Weight: 166.07
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat.
Incompatibilities with Other Materials:
Oxidizing agents
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide, fluoride fumes.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 769-39-1 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
2,3,5,6-Tetrafluorophenol -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2811
Packing Group: III
IMO
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing Group: III
RID/ADR
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 769-39-1: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 769-39-1 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 769-39-1 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #5 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
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|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
5-Hydroxy-n omega-methyltryptamine oxalate 99%
| 15558-50-6 |
|
Coumarin 6, Laser Grade, 98% (UV-Vis)
| 38215-36-0 |
|
Iodobenzene, 98%
| 591-50-4 |
|
Oxalyl bromide, 98%
| 15219-34-8 |
|
Borane-trimethylamine complex, 98% (titr.)
| 75-22-9 |
|
1,2,4-1H-Triazole, 99.5%
| 288-88-0 |
|
Benzoic acid ammonium salt, 99% (titr.)
| 1863-63-4 |
|
2-Methyl-Cyclopropane-Methanol (Mixture of Cis and Trans), 98%
| 6077-72-1 |
|
Dowex 1x8-50 Ion-Exchange Resin
| 69772-06-1 |
|
Poly (4-Vinylpyridinium Dichromate),Cross Linked with 2% DVB;2.2mmol
| 82246-45-5 |
|
Coumarin 334, Laser Grade, 99% (UV-Vis)
| 55804-67-6 |
|
Cinnamyl alcohol, 98%
| 104-54-1 |
|
Potassium trichloro(ethylene)platinate(ii) monohydrate
| 12012-50-9 |
|
3-Tert-Butyl Adipic Acid, 99%(GC)
| 10347-88-3 |
|
Vanadium(iv) oxide, 99.9%
| 12036-21-4 |
|
3-Aminobenzotrifluoride, 99+ %
| 98-16-8 |
|
4,4-Dimethyl-2-pentanol, 99%
| 6144-93-0 |
|
Benzyl levulinate, 96%(GC)
| 6939-75-9 |
|
2,3,5,6-Tetrafluorophenol, 97+%
| 769-39-1 |
|
1-Bromo-3-chloropropane, 99%
| 109-70-6 |
|
3-Mercapto-1,2-propanediol, 90 wt% aqueous solution
| 96-27-5 |
|
Acetylenedicarboxamide (pract)
| 543-21-5 |
|
4-Heptyloxyphenol, 99%
| 13037-86-0 |
|
1-Bromo-3-Fluoro-4-Iodobenzene, 99+%
| 105931-73-5 |
|
Benzyl phenyl sulfide, 99%
| 831-91-4 |
|
1,5-Pentamethylenetetrazole, 98%
| 54-95-5 |
|
Lepidine (4-methylquinoline), 99%
| 491-35-0 |
|
2-Methyl-1-tetralone, 99%
| 1590-08-5 |
|
3-Ethoxy-2-Cyclohexen-1-One, 99%
| 5323-87-5 |
|
Hydroquinone Bis(2-Hydroxyethyl)ether, 97% (GC)
| 104-38-1 |
|
(2S,3S)-3-Methylpyrrolidine-2-carboxylic acid, 97%
| 0-01-1 |
|
Cholesteryl 2-ethylhexanoate
| 41329-01-5 |
|
Thiobenzamide, 95%
| 2227-79-4 |
|
(S)-(+)-2-Phenylpropionic acid, 99%
| 7782-24-3 |
|
Lycopodium Powder
| 8023-70-9 |
|
Isopropylcyclohexane, 97%
| 696-29-7 |
|
2-Hydrazinobenzothiazole, 99% (Titr.)
| 615-21-4 |
|
n,n-Dimethyl-p-Toluidine, 99%
| 99-97-8 |
|
3-Iodo-4-Methylbenzoic Acid, 97%
| 82998-57-0 |
|
Europium (III) Sulfate Octahydrate, 99.99%
| 10031-55-7 |
|
4,4,5,5,6,6,6-Heptafluoro-1-(2-thienyl)- 1,3-hexanedione
| 559-94-4 |
|
4-Bromoresorcinol, 99%
| 6626-15-9 |
|
1-Octen-3-ol, 98%
| 3391-86-4 |
|
5-Bromo-2-chlorobenzotrifluoride,techn. 94 %
| 445-01-2 |
|
3-Chloropropionyl Chloride, 98%
| 625-36-5 |
|
Alpha, Alpha, Alpha-Trifluoro-P-Toluic Acid, 98%
| 455-24-3 |
|
2-Bromo-2-Phenylacetophenone
| 1484-50-0 |
|
Silicon, Powder, -325 Mesh, 99+%
| 7440-21-3 |
|
Ethylene oxide, 99+%
| 75-21-8 |
|
Atropine Sulfate Monohydrate, 98.5% (Dry Substance)
| 5908-99-6 |
|
|