**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 111-76-2 |2-Butoxyethanol | 6 | 203-905-0 |
|----------------|--------------------------------------|----------|-----------|
| 6834-92-0 |Sodium metasilicate | 6 | 229-912-9 |
|----------------|--------------------------------------|----------|-----------|
| 7732-18-5 |Water | 82 | 231-791-2 |
|----------------|--------------------------------------|----------|-----------|
| 68439-57-6 |Sodium C14-16-alkane hydroxy & alkene | 3 | 270-407-8 |
| |sufonates | | |
|----------------|--------------------------------------|----------|-----------|
| 127087-87-0 |4-Nonylphenol, branched, ethoxylated | 3 | unlisted |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: C
Risk Phrases: 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes burns.Corrosive.
Potential Health Effects
Eye:
Causes eye burns. May cause chemical conjunctivitis and corneal
damage.
Skin:
Not available.
Ingestion:
Causes gastrointestinal tract burns. May cause central nervous
system effects. May cause systemic effects.
Inhalation:
Causes chemical burns to the respiratory tract. Aspiration may lead
to pulmonary edema. May cause systemic effects. Central nervous
system effects, which appear to predominate in acute cases are
characterized by abnormal fatigue, memory difficulties and dizziness.
Chronic:
Prolonged or repeated skin contact may cause defatting and
dermatitis. Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Contact
with metals may evolve flammable hydrogen gas. Containers may explode
when heated. Runoff from fire control or dilution water may cause
pollution.
Extinguishing Media:
Use extinguishing media most appropriate for the surrounding fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation. Do
not get in eyes, on skin, or on clothing. Keep container tightly
closed. Discard contaminated shoes. Avoid breathing vapor or mist.
Storage:
Store in a cool, dry place. Keep container closed when not in use.
Corrosives area. Keep away from acids.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 111-76-2:
United Kingdom, WEL - TWA: 25 ppm TWA
United Kingdom, WEL - STEL: 50 ppm STEL
United States OSHA: 50 ppm TWA; 240 mg/m3 TWA
Belgium - TWA: 20 ppm VLE; 98 mg/m3 VLE
Belgium - STEL: 50 ppm VLE; 246 mg/m3 VLE
France - VME: 25 ppm VME; 120 mg/m3 VME
Germany: 20 ppm TWA; 98 mg/m3 TWA
Germany: Skin absorber
Malaysia: 20 ppm TWA; 96.7 mg/m3 TWA
Netherlands: 50 ppm STEL; 246 mg/m3 STEL
Netherlands: 20 ppm MAC; 100 mg/m3 MAC
Russia: 5 mg/m3 TWA
Spain: 20 ppm VLA-ED; 98 mg/m3 VLA-ED
Spain: 50 ppm VLA-EC; 245 mg/m3 VLA-EC
CAS# 6834-92-0:
CAS# 7732-18-5:
CAS# 68439-57-6:
CAS# 127087-87-0:
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear red
Odor: aromatic odor
pH: 12.3 @ use dilution
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: > 212 deg F
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Soluble.
Specific Gravity/Density: 1.07
Molecular Formula: Not applicable.
Molecular Weight: Not available.
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Extreme temperatures.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong reducing agents.
Hazardous Decomposition Products:
Carbon monoxide, oxides of sulfur, irritating and toxic fumes and
gases, carbon dioxide, hydrogen sulfide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 111-76-2: KJ8575000
CAS# 6834-92-0: VV9275000
CAS# 7732-18-5: ZC0110000
CAS# 68439-57-6 unlisted.
CAS# 127087-87-0: RB2451000 TR1581962
LD50/LC50:
CAS# 111-76-2: Dermal, guinea pig: LD50 = 230 uL/kg; Draize test,
rabbit, eye: 100 mg Severe; Draize test, rabbit, eye: 100 mg/24H
Moderate; Inhalation, mouse: LC50 = 700 ppm/7H; Inhalation, mouse:
LC50 = 3380 mg/m3/7H; Inhalation, rat: LC50 = 450 ppm/4H;
Inhalation, rat: LC50 = 2900 mg/m3/7H; Oral, mouse: LD50 = 1230
mg/kg; Oral, mouse: LD50 = 1167 mg/kg; Oral, rabbit: LD50 = 300
mg/kg; Oral, rabbit: LD50 = 320 mg/kg; Oral, rat: LD50 = 470 mg/kg;
Oral, rat: LD50 = 917 mg/kg; Skin, rabbit: LD50 = 220 mg/kg.
CAS# 6834-92-0: Draize test, rabbit, skin: 250 mg/24H Severe; Oral,
mouse: LD50 = 770 mg/kg; Oral, rat: LD50 = 1153 mg/kg.
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
CAS# 68439-57-6.
CAS# 127087-87-0.
Carcinogenicity:
2-Butoxyethanol -
ACGIH: A3 - Confirmed animal carcinogen with unknown relevance to
Sodium metasilicate -
Not listed by ACGIH, IARC, or NTP.
Water -
Not listed by ACGIH, IARC, or NTP.
Sodium C14-16-alkane hydroxy & alkene sufonates -
Not listed by ACGIH, IARC, or NTP.
4-Nonylphenol, branched, ethoxylated -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
The high pH of this material makes it harmful to aquatic life.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
No information available.
IMO
No information available.
RID/ADR
No information available.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
WGK (Water Danger/Protection)
CAS# 111-76-2: 1
CAS# 6834-92-0: 1
CAS# 7732-18-5: No information available.
CAS# 68439-57-6: No information available.
CAS# 127087-87-0: 2
Canada
CAS# 111-76-2 is listed on Canada's DSL List.
CAS# 6834-92-0 is listed on Canada's DSL List.
CAS# 7732-18-5 is listed on Canada's DSL List.
CAS# 68439-57-6 is listed on Canada's DSL List.
CAS# 127087-87-0 is listed on Canada's DSL List.
CAS# 111-76-2 is listed on Canada's Ingredient Disclosure List.
CAS# 6834-92-0 is listed on Canada's Ingredient Disclosure List.
CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List.
CAS# 68439-57-6 is not listed on Canada's Ingredient Disclosure List.
CAS# 127087-87-0 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 111-76-2 is listed on the TSCA inventory.
CAS# 6834-92-0 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.
CAS# 68439-57-6 is listed on the TSCA inventory.
CAS# 127087-87-0 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
MSDS Creation Date: 12/01/1997 Revision #6 Date: 10/05/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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