**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 112-27-6 |Triethylene glycol | 100 | 203-953-2 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: None Listed.
Risk Phrases: None Listed.
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Not available.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
Exposure may cause irritation characterized by redness, dryness, and
inflammation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. Possible aspiration hazard.
Inhalation:
Inhalation of a mist of this material may cause respiratory tract
irritation.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may be heavier than air. They can spread
along the ground and collect in low or confined areas.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation.
Storage:
Store in a cool, dry place. Keep containers tightly closed.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 112-27-6:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear to light yellow
Odor: mild odor
pH: Not available.
Vapor Pressure: < .001 mm Hg @2
Viscosity: 48 mPa s@20 C
Boiling Point: 285 deg C
Freezing/Melting Point: -7 deg C
Autoignition Temperature: 699.8 deg F ( 371.00 deg C)
Flash Point: 329 deg F ( 165.00 deg C)
Explosion Limits, lower: 0.9
Explosion Limits, upper: 9.2
Decomposition Temperature: Not available.
Solubility in water: Soluble in water
Specific Gravity/Density: 1.125
Molecular Formula: C6H14O4
Molecular Weight: 150.0956
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Sulfuric acid, isocyanates, perchloric acid, strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 112-27-6: YE4550000
LD50/LC50:
CAS# 112-27-6: Draize test, rabbit, eye: 500 mg Mild; Draize test,
rabbit, skin: 500 mg/24H Mild; Oral, mouse: LD50 = 20000 mg/kg; Oral,
rabbit: LD50 = 8400 mg/kg; Oral, rabbit: LD50 = 8400 mg/kg; Oral,
rat: LD50 = 17 gm/kg; Oral, rat: LD50 = 15000 mg/kg; Skin, rabbit:
LD50 = >20 mL/kg.
Carcinogenicity:
Triethylene glycol -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Fish: Fathead Minnow: LC50 = 70,200 mg/L; 96 Hr.; Flow-throughFish:
Bluegill/Sunfish: LC50 = 10,000 mg/L; 96 Hr.; Static
ConditionsBacteria: Phytobacterium phosphoreum: EC50 = 850 mg/L; 5
miuntes; Microtox test
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
WGK (Water Danger/Protection)
CAS# 112-27-6: 1
Canada
CAS# 112-27-6 is listed on Canada's DSL List.
CAS# 112-27-6 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 112-27-6 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 6/09/1999 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
3-Bromo-4-methylaniline, 97%
| 7745-91-7 |
|
2-Amino-3,5-Diiodobenzoic Acid, 98%
| 609-86-9 |
|
3-Chloro-2-methylpropene tech., 90%
| 563-47-3 |
|
4-Cyclohexylacetophenone, 98%
| 18594-05-3 |
|
2,4,6-Trihydroxybenzaldehyde, 97%
| 487-70-7 |
|
2-Dodecanone, 95%
| 6175-49-1 |
|
1-(4-Cyanophenyl)-piperazine hydrochloride
| 0-01-1 |
|
9-BBN crystalline dimer, 98%
| 21205-91-4 |
|
2,3-Pyridinedicarboxylic Anhydride,97%
| 699-98-9 |
|
N-tert-Butoxycarbonyl-L-Prolinol
| 69610-40-8 |
|
Toluene, P.A.
| 108-88-3 |
|
Tri-N-Butyl Phosphate
| 126-73-8 |
|
Tributylamine, P.A
| 102-82-9 |
|
Chloral hydrate, 98.5%
| 302-17-0 |
|
N-tert-Butoxycarbonyl-D-Prolinol
| 83435-58-9 |
|
3,5-Dimethyl-1-phenylpyrazole, 97%
| 1131-16-4 |
|
(4S)-4-Bromomethyl-2-Phenyl-1,3-Dioxane, 95%
| 201743-52-4 |
|
1,3,5-Trimethylpyrazole, 99%
| 1072-91-9 |
|
Trichloroethylene, reagent ACS, stabilized with 0.5% ethanol
| 64-17-5 |
|
Triethylene glycol, 99%
| 112-27-6 |
|
Triethylenetetramine, 95%
| 112-24-3 |
|
Hexyl Acetate, 99%
| 142-92-7 |
|
3,5-Diacetoxyacetophenone, 98+%
| 35086-59-0 |
|
2,4,5-Trihydroxybenzaldehyde
| 35094-87-2 |
|
Tetrahydroxy-1,4-quinone hydrate
| 123334-16-7 |
|
Trifluoroacetic acid, biochemical grade
| 76-05-1 |
|
Trifluoroacetic anhydride, 99+%
| 407-25-0 |
|
tert-Butanol-d10, 98%
| 53001-22-2 |
|
3-Methyl-2,4-pentanedione, mixture of tautomers, tech. 85%
| 815-57-6 |
|
1-(4-Methylphenyl)-2-methylpiperazine, 1:1 mixture of conformers, 97%
| 35947-11-6 |
|
Tris-(Hydroxymethyl)-Aminomethane, P.A.; Biochemical grade
| 77-86-1 |
|
Sodium phosphate, tribasic dodecahydrate, reagent ACS, powder
| 7601-54-9 |
|
Tungsten(vi) oxide 99+%
| 1314-35-8 |
|
Fluoranthene, 93%
| 206-44-0 |
|
4-Chloro-3-nitrobenzoyl chloride, 98%
| 38818-50-7 |
|
TMIO, 98%
| 0-01-1 |
|
4-Amino-2-chloro-6,7-dimethoxyquinazoline, 97%
| 23680-84-4 |
|
5-Chloro-3-pyridinol, 99%
| 74115-12-1 |
|
2-Chloro-5-chloromethylpyridine, tech. 90%
| 70258-18-3 |
|
7-Acetoxy-4-methylcoumarin, 98%
| 2747-05-9 |
|
3-Amino-2,5-dichlorobenzoic acid, 97%
| 133-90-4 |
|
6,11-Dihydrodibenzo[b,e]Thiepin-11-one, 97%
| 1531-77-7 |
|
Methylcyclopentane, 95%
| 96-37-7 |
|
3-Methylfuran, 98%
| 930-27-8 |
|
2-Amino-6-chloro-4-methoxypyrimidine, 98%
| 5734-64-5 |
|
Urea, 98%, Pearls
| 57-13-6 |
|
Vanillin, 99%
| 121-33-5 |
|
Vinyl acetate monomer, stabilized
| 108-05-4 |
|
N-Methylmaleimide
| 930-88-1 |
|
2-Acetyl-1-tetralone
| 17216-08-9 |
|
|